Engineering Commons^™

Self-Sustaining Smouldering Combustion Of Granular Activated Carbon Contaminated With Per- And Polyfluoroalkyl Substances – Fluorine Mass Balance And Enhanced Methods Of Mineralization, Brian Gerald Harrison

Electronic Thesis and Dissertation Repository

Per- and polyfluoroalkyl substances (PFAS) are a large group of anthropogenic compounds. Long-term use has led to widespread environmental contamination, and PFAS source zones will require cleanup.

Self-sustaining Treatment for Active Remediation (STAR) is a thermal treatment technology that employs smouldering combustion as a method of soil treatment. Smouldering can be self-sustaining and is thus more energy-efficient. Previous research applying STAR to PFAS-contaminated soil and granular activated carbon (GAC) showed promise, as PFAS were removed from soil.

This study clarified the potential of STAR as a treatment option for PFAS. This study is unique in how thoroughly it characterized the …

Carbon Injection To Support In-Situ Smouldering Remediation, Gillian Wilton

Electronic Thesis and Dissertation Repository

Per- and polyfluoroalkyl substances (PFAS) are a group of anthropogenic contaminants that are growing increasing concern due to their associated negative health affects. The properties of PFAS result in their persistence and stability which present challenges for remediation. Activated carbon is currently the most widely used method for PFAS treatment since carbon microparticle injection can be used for in-situ treatment; however, this method does not result in PFAS destruction. Thermal treatment is a promising post-treatment method that can be used with activated carbon as long as sufficient PFAS-destroying temperatures are achieved (> 900°C). A promising in-situ thermal treatment technology is …

Hydrogen-Rich Syngas Derived From Smouldering Biomass And Hydrocarbon Wastes, Joshua K. Brown

Electronic Thesis and Dissertation Repository

In the face of climate change, the world is looking to new fuel sources to meet the surging global energy demand. Hydrogen has been proposed as a promising energy vector being both a net-zero carbon emitter and having one of the highest gravimetric energy densities of known fuels. Production of hydrogen, however, is difficult with many of the technologies which exist today failing to be economically feasible or environmentally sustainable. Smouldering has recently been developed as a cost effective and energy efficient technology for destruction of organic wastes. The unique reaction zones created within a smouldering system have the potential …