Engineering Commons^™

Pyrolysis Based Biorefineries For The Production Of Fermentable Substrates, Luis Carlos Luque-Moreno

Electronic Thesis and Dissertation Repository

Fast pyrolysis is rapid thermal conversion process capable of transforming multiple feedstocks into various energy carriers, specifically pyrolysis oil, bio gas, and bio char. The oil phase is of high value due to its complex mixtures of organic molecules, along with large number of anhydrous carbohydrates, which can be easily transformed into glucose via acid hydrolysis. These carbohydrates can be either biocatalyzed into fuels and chemicals by microorganisms or converted after further treatment steps. However quantities of these carbohydrates in the oil are a function of feedstock composition and process parameters. The research presented in this thesis focuses on producing …

Novel Carbon-Supported Transition Metal Phosphide Catalysts For Hydrodeoxygenation Of Fast Pyrolysis Oil, Cheng Guo

Electronic Thesis and Dissertation Repository

Catalytic hydrodeoxygenation (HDO) is considered to be the most promising route to upgrade pyrolysis oil to liquid transportation fuels. The objective of this research was to explore inexpensive supported metal oxides/metal phosphide catalysts for the upgrading of pyrolysis oil into advanced drop-in hydrocarbon liquid fuels by HDO.

The first stage of this thesis project investigates a series of molybdenum oxides/phosphide catalysts on different supports that were prepared in-house, such as Al₂O₃, activated carbon (AC), MgAl₂O₄ and Mg₆Al₂(CO₃)(OH)₁₆. The HDO activity of these catalysts were investigated …