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Electronic Thesis and Dissertation Repository

2013

Adsorption

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Full-Text Articles in Engineering

Carbon-Nzvi Nanocomposites For Dechlorination Of Halogenated Hydrocarbons, Jing Cheng Oct 2013

Carbon-Nzvi Nanocomposites For Dechlorination Of Halogenated Hydrocarbons, Jing Cheng

Electronic Thesis and Dissertation Repository

A family of hybrid nanocarbon/nanoiron composites has been developed with the aim to carry out simultaneous adsorption and dechlorination of chlorinated hydrocarbons from aqueous solutions. Several methodologies for the synthesis of these materials are evaluated in terms of their adsorption capacities and dechlorination activities. Detailed spectroscopic and microscopy studies indicate that the adsorption ability of the carbonaceous support is greatly improved after acid oxidization, attributed to the formation of oxygenated functional groups on their surfaces. When iron nanoparticles are incorporated on the composites, the materials show a much higher trichloroethylene (TCE) removal efficiency compared to bare metallic nanoiron particles or …


Application Of Mixed Iron Oxides In Subsurface Remediation Technologies, Saidur Rahman Chowdhury May 2013

Application Of Mixed Iron Oxides In Subsurface Remediation Technologies, Saidur Rahman Chowdhury

Electronic Thesis and Dissertation Repository

Heavy metal contamination of soil and groundwater has been a concern in water supply and public health in many countries where the water supply system draws primarily from groundwater. In the present study, mixed maghemite-magnetite nanoparticles have been used as adsorbents for Cr(VI), As and Cd(II) removal. From the study, it is apparent that the removal of Cr(VI ), Cd(II) and As(V) by mixed iron oxide nanoparticles depends on pH, temperature, contact time, solid/liquid ratio and initial concentration of heavy metals. The results showed that Cr(VI) adsorption on mixed maghemite-magnetite was dependent on solution pH between 3 and 6. Theoretical …