Engineering Commons^™

Inherently Porous Atomically Thin Membranes For Gas Separation, Harpreet Atwal

Electronic Thesis and Dissertation Repository

Membranes made from atomically thin materials promise hundreds of times higher production rates than conventional polymer membranes for separation applications. Graphene is impermeable to gases but becomes selectively permeable once pores are introduced into it but creating trillions of nanopores over large areas is difficult. By instead choosing an inherently porous two-dimensional material with naturally identical pores repeated at high density, we may circumvent this challenge. In this work, we explore the potential of two candidate materials, 2D polyphenylene and graphdiyne. We synthesize cyclohexane-m-phenylene, a monomer of 2D polyphenylene. We then develop an atomic force microscopy technique for measuring the …

Convection In Corrugated Slots, Seyed Arman Abtahi

Electronic Thesis and Dissertation Repository

This thesis consists of two parts. The first part deals with the development of proper methodology, i.e. a spectrally accurate algorithm suitable for analysis of convection problems in corrugated slots. The second part is devoted to the study of natural convection in corrugated slots.

The algorithm uses the immersed boundary conditions (IBC) concept to deal with the irregular form of the solution domain associated with the presence of corrugated plates. The field equations are discretized on a regular domain surrounding the flow domain using Fourier expansions in the horizontal direction and Chebyshev expansions in the vertical direction. The boundary conditions …