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Development Of Novel Nanomaterials For Lithium Sulfur Batteries, Xia Li
Development Of Novel Nanomaterials For Lithium Sulfur Batteries, Xia Li
Electronic Thesis and Dissertation Repository
Lithium-sulfur batteries are considered as the most promising next generation high-energy batteries. Compared with other kinds of battery, Li-S batteries have ultra-high theoretical energy density, which is a good candidate for electric vehicles and hybrid electric vehicles in future. However, there are still many challenges to be addressed in Li-S batteries. Design of electrodes, selection of electrolytes, and battery assemble have direct effects on the safety, cost and electrochemical performance of Li-S batteries. Therefore, it is greatly important to develop novel electrodes to achieve high-energy for Li-S batteries. This thesis mainly focuses on the design of sulfur cathode of Li-S …
Surface Modification Of Electrode Materials For Lithium-Ion Batteries, Biwei Xiao
Surface Modification Of Electrode Materials For Lithium-Ion Batteries, Biwei Xiao
Electronic Thesis and Dissertation Repository
The development of lithium-ion batteries (LIBs) has been hampered by the intrinsic limitations of the electrode materials. High-performance LIBs demand electrode materials with fast lithium/electron diffusion rate, stable surface chemistry and high specific capacity. Surface modification by atomic layer deposition (ALD) is an essential method to optimize the performance of the electrode materials. The research in this thesis aims at achieving high-performance LIBs via surface modification and understanding the mechanisms via synchrotron radiation.
Firstly, by applying ALD FePO4 on LiNi0.5Mn1.5O4 (LNMO), we successfully alleviated the electrolyte decomposition under high voltage by using the electrochemically …