Engineering Commons^™

Materials And Interfaces For Electrocatalytic Hydrogen Production And Utilization., Alexander Jiya Gupta

Electronic Theses and Dissertations

Mass industrialization over the last few centuries has created a global economy which is dependent upon fossil fuels to satisfy an exponentially increasing demand for energy. Aside from the possible depletion of this finite resource, the combustion of fossil fuels releases greenhouse gases into the atmosphere which cause the global temperature to rise – a phenomenon which has already begun to create geologic and geopolitical instability and shows no signs of abatement. One proposed method to rid humanity of its dependence on fossil fuels is to use green hydrogen as an energy carrier. In this scheme, excess electricity from a …

Design Of A 300cm2 Pemfc Stack With Force And Cfd Simulation To Optimize Flow Channels, Gasket Design, And Clamping Forces., Robert M. Ench

Electronic Theses and Dissertations

Proton exchange membrane fuel cells are important to the future of green energy as hydrogen can be made with green technologies and store energy for later use. Fuel cells can efficiently convert the hydrogen to electricity as needed. This study uses Solidworks simulation to make design improvements to the fuel cell before the prototype build stage of testing; this saves money and time by reducing the prototype builds needed.

In this study, a multi-channel serpentine design with two outlets versus a single outlet is evaluated using CFD to investigate pressure drop. Lower pressure drops are desirable as less energy input …

Synthesis, Characterization, And Evaluation Of Metal Complexes With Cancer Selective Anti-Proliferative Effects And Hydrogen Evolution Catalytic Properties., Nicholas Vishnosky

Electronic Theses and Dissertations

Bis-thiosemicarbazones (BTSC) and their metal chelates have properties that are useful in several different scientific fields. These systems have already received attention in major fields of biology and engineering. Hydrogen evolution reaction (HER) catalysts need to be cheap and operate under minimal overpotentials with a long lifetime. The treatment of cancer requires, novel agents that have potent cytotoxic activity against cancer cells while displaying minimal side effects. In this dissertation the modular synthesis of these bis-thiosemicarbazone systems is utilized to regulate the redox chemistry for employment in the desired sector of chemistry. The ligand and metal chelates synthesized were characterized …

Computational Fluid Dynamics Simulation Of United Launch Alliance Delta Iv Hydrogen Plume Mitigation Strategies, Stephen Guimond

Electronic Theses and Dissertations

During the launch sequence of the United Launch Alliance Delta IV launch vehicle, large amounts of pure hydrogen are introduced into the launch table and ignited by Radial-Outward-Firing-Igniters (ROFIs). This ignition results in a significant flame, or plume, that rises upwards out of the launch table due to buoyancy. The presence of the plume causes increased and unwanted heat loads on the surface of the vehicle. A proposed solution is to add a series of fans and structures to the existing launch table configuration that are designed to inject ambient air in the immediate vicinity of the launch vehicle's nozzles …

Surface Acoustic Wave (Saw) Cryogenic Liquid And Hydrogen Gas Sensors, Brian Fisher

Electronic Theses and Dissertations

This research was born from NASA Kennedy Space Center’s (KSC) need for passive, wireless and individually distinguishable cryogenic liquid and H2 gas sensors in various facilities. The risks of catastrophic accidents, associated with the storage and use of cryogenic fluids may be minimized by constant monitoring. Accidents involving the release of H2 gas or LH2 were responsible for 81% of total accidents in the aerospace industry. These problems may be mitigated by the implementation of a passive (or low-power), wireless, gas detection system, which continuously monitors multiple nodes and reports temperature and H2 gas presence. Passive, wireless, cryogenic liquid level …

Solar Driven Photoelectrochemical Water Splitting For Hydrogen Generation Using Multiple Bandgap Tandem Of Cigs2 Pv Cells And Thin Film Photocatalyst, Anant Jahagirdar

Electronic Theses and Dissertations

The main objective of this research was to develop efficient CuIn1-xGaxS2 (CIGS2)/CdS thin film solar cells for photoelectrochemical (PEC) water splitting to produce very pure hydrogen and oxygen. Efficiencies obtained using CIGS2 have been lower than those achieved using CuInSe2 and CuIn1-xGaxSe2. The basic limitation in the efficiencies is attributed to lower open circuit voltages with respect to the bandgap of the material. Presently, the main mechanism used to increase the open circuit voltage of these copper chalcopyrites (CuInSe2 and CuInS2) is the addition of gallium. However, addition of gallium has its own challenges. This research was intended to (i) …

Effects Of Transport Properties And Flame Unsteadiness On Nitrogen Oxides Emissions From Laminar Hydrogen Jet Diffusion Flames, Doyoub Park

Electronic Theses and Dissertations

Experimental studies on the coupled effects of transport properties and unsteady fluid dynamics have been conducted on laminar, acoustically forced, hydrogen jet diffusion flames diluted by argon and helium. The primary purpose of this research is to determine how the fuel Lewis number and the flow unsteadiness play a combined role in maximum flame temperature and affect NOx emission from jet diffusion flame. The fuel Lewis number is varied by increasing/decreasing the mole fraction of diluents in the fuel stream. Therefore, maximum flame temperatures and then NOx emission levels were expected to differ for Ar- and He-diluted flames. In an …