Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 7 of 7
Full-Text Articles in Engineering
Computational Modeling Of Percolation Conduction And Diffusion Of Heterogeneous Materials, Jian Qiu
Computational Modeling Of Percolation Conduction And Diffusion Of Heterogeneous Materials, Jian Qiu
Electronic Theses and Dissertations
Heterogeneous materials provide a unique combination of desirable mechanical, thermal or electrical properties. This dissertation presents several micro-structure modeling approaches to predict the effective properties of heterogeneous materials and demonstrates its certain application toward two highly heterogeneous, unconventional structural composite materials (carbon fiber reinforced composite materials and graphene nanoplatelets composite). By using the efficient computational algorithm based on the FEA, a randomly oriented disk-shaped particles system are generated. A new element partition scheme based on the vector operations and geometry of inclusion has been implemented to mesh the intersected disks. The computed equivalent conductivity is expressed as a power-law function …
Interdiffusion And Impurity Diffusion In Magnesium Solid Solutions, Catherine Kammerer
Interdiffusion And Impurity Diffusion In Magnesium Solid Solutions, Catherine Kammerer
Electronic Theses and Dissertations
Magnesium, being lightweight, offers potential to be developed into extensive structural applications. The transportation segment has particular interest in Mg and Mg alloy for applications where reduced vehicle weight is proportional to increased fuel efficiency. Aluminum and zinc are two of the most common alloying elements in commercial Mg alloys. They improve the physical properties of Mg through solid solution strengthening and precipitation hardening. Diffusion plays a key role in the kinetics of and microstructural development during solidification and heat treatment. However, there is limited diffusion data available for Mg and Mg alloys. In particular, because Al is monoisotopic, tracer …
Interdiffusion Reaction Between Uranium-Zirconium And Iron, Young Joo Park
Interdiffusion Reaction Between Uranium-Zirconium And Iron, Young Joo Park
Electronic Theses and Dissertations
U-Zr metallic fuels cladded in Fe-alloys are being considered for application in an advanced Sodium-Cooled Fast Reactor (SFR) that can recycle the U-Zr fuels and minimize the long-lived actinide waste. To understand the complex fuel-cladding chemical interaction of the U-Zr metallic fuel with Fe-alloys, a systematic multicomponent diffusion study was carried out using solid-to-solid diffusion couples. The U-10 wt.% Zr vs. pure Fe diffusion couples were assembled and annealed at temperatures, 630, 650 and 680°C for 96 hours. Development of microstructure, phase constituents, and compositions developed during the thermal anneals were examined by scanning electron microscopy, transmission electron microscopy and …
Diffusion And Reaction In Selected Uranium Alloy System, Ke Huang
Diffusion And Reaction In Selected Uranium Alloy System, Ke Huang
Electronic Theses and Dissertations
U-Mo metallic fuels with Al alloys as the matrix/cladding are being developed as low enriched uranium fuels under the Reduced Enrichment for Research and Test Reactor (RERTR) program. Significant interactions have been observed to occur between the U-Mo fuel and the Al alloy during fuel processing and irradiation. U-Zr metallic fuels with stainless steel claddings have been developed for the generation IV sodium fast reactor (SFR). The fuel cladding chemical interaction (FCCI) induced by the interdiffusion of components was also observed. These interactions induce deleterious effects on the fuel system, such as thinning of the cladding layer, formation of phases …
Laser Enhanced Doping For Silicon Carbide White Light Emitting Diodes, Sachin Bet
Laser Enhanced Doping For Silicon Carbide White Light Emitting Diodes, Sachin Bet
Electronic Theses and Dissertations
This work establishes a solid foundation for the use of indirect band gap semiconductors for light emitting application and presents the work on development of white light emitting diodes (LEDs) in silicon carbide (SiC). Novel laser doping has been utilized to fabricate white light emitting diodes in 6H-SiC (n-type N) and 4H-SiC (p-type Al) wafers. The emission of different colors to ultimately generate white light is tailored on the basis of donor acceptor pair (DAP) recombination mechanism for luminescence. A Q-switched Nd:YAG pulse laser (1064 nm wavelength) was used to carry out the doping experiments. The p and n regions …
Interdiffusion Analysis For Nicocraly And Nial Vs. Various Superalloys, Emmanuel Perez
Interdiffusion Analysis For Nicocraly And Nial Vs. Various Superalloys, Emmanuel Perez
Electronic Theses and Dissertations
Hot section components in gas turbines can be NiCoCrAlY-coated to provide the component with an Al reservoir that maintains a protective oxide layer on its surface. Over the service life of the component, the coatings degrade by composition and phase changes due to oxidation/hot-corrosion, and multicomponent interdiffusion from and into the superalloy substrate. In this study, the rate of Al interdiffusion into selected Ni-base superalloys using various diffusion couples of two-phase NiCoCrAlY (beta + gamma) and single beta-phase NiAl with the selected alloys is measured. The diffusion couples were examined with an emphasis on the composition-dependence of Al interdiffusion. Microstructural …
Phenomenology And Experimental Observations In High Temperature Ternary Interdiffusion, Abby Lee Elliott
Phenomenology And Experimental Observations In High Temperature Ternary Interdiffusion, Abby Lee Elliott
Electronic Theses and Dissertations
A new method to extract composition dependent ternary interdiffusion coefficients from a single diffusion couple experiment is presented. The calculations involve direct determination of interdiffusion fluxes from experimental concentration profiles and local integration and differentiation of Onsager's formalism. This new technique was applied to concentration profiles obtained from selected semi-infinite, single-phase diffusion couple experiments in the Cu-Ni-Zn, Fe-Ni-Al, and Ni-Cr-Al systems. These couples exhibit features such as uphill diffusion and zero flux planes. The interdiffusion coefficients from the new technique along with coefficients reported from other methods are graphed as functions of composition. The coefficients calculated from the new technique …