Engineering Commons^™

The Anodic Behavior Of Zinc In Aqueous Salt Solutions, Yun-Chung Sun

Doctoral Dissertations

"The increasing demand for protective metals as coatings and non-corrosive alloys has caused extensive research on the fundamental behavior of metals in corrosive media. The problem of controlling the destructive process of metallic corrosion still exists and becomes urgent in this space age. The desirablity of metals such as beryllium, magnesium, and zinc in air frame and space structural units, because of their high strength to weight ratio, has been responsible for the considerable progress in their technology in recent years.

The basic mechanism of the anodic dissolution of metals such as zinc, cadmium, and magnesium in salt solution is …

Aeration Studies In Submerged Fermentations Using A Steam-Sterilizable Dissolved Oxygen Sensor Of Improved Design, Carl J. Wallace

Doctoral Dissertations

"Large-scale submerged fermentations have been important for many years for the production of antibiotics, vitamins, enzymes, etc.; however, aeration studies have been severely restricted in these processes because of the unavailability of adequate oxygen sensing equipment.

A steam-sterilizable oxygen sensor of improved design was developed out of an investigation of several potential sensors. This rapidly responding galvanic probe made use of a lead anode, a silver cathode, an acetate buffer as the electrolyte, and a one mil Teflon® membrane as the diffusion barrier. Its sensitivity was approximately 40 µamps and full response required approximately 5 minutes.

Use was made of …

A Study Of The Anodic Oxidation Of Acetylene On Gold Electrodes, Jo Lisle Reed

Doctoral Dissertations

"The object of this investigation was to establish a mechanism for the anodic oxidation of acetylene on gold electrodes in aqueous solutions. It is known that anodic oxidation of organic compounds on gold electrodes produces a large number of organic intermediates and end products. Therefore, it appeared worthwhile to establish a mechanism that could provide a better understanding of the fuel cell electrode kinetics and possibly lead to new methods of organic syntheses"--Introduction, page 2.

Turbulence Measurements In Polymer Solutions Using Hot-Film Anemometry, Gary Kent Patterson

Doctoral Dissertations

"Hot-film anemometry was used to study the detailed structure of turbulence (intensities, energy spectra, and auto-correlations) in Newtonian solvents, non-drag reducing polymer solutions, and drag reducing polymer solutions. This was done in two smooth wall tubes with diameters of 1.0 inch and 2.0 inches. A probe traversing mechanism was used for measurements at radial positions from the center to as near the wall as possible for both the film probes (r/a=0.85 in the 2-inch tube) and the impact tubes (r/ a=0.98). The impact tubes were used to measure velocities for film probe calibration.

The solvents used in this investigation were …

The Anodic Dissolution Of Cadmium In Aqueous Solutions, San-Cheng Lai

Doctoral Dissertations

"The purpose of this investigation was to study the effect of cadmium ions on the anodic dissolution of cadmium in salt solutions of ·constant ionic strength. The concentration of the cadmium ions was varied from 0.001 to 1 N and the current density ranged from 0.001 to 0.1 amp•cm^-2. The temperature was controlled at 25°C.

....A mathematical model was postulated expressing the anodic dissolution rate as the sum of electrochemical, local corrosion, and disintegration rates."--Abstract, page iii.