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Full-Text Articles in Engineering
Synthesis, Characterization, Spectroscopic, And Mesomorphic Studies Of New Schiff Base Ligands And Titanium, Cobalt, Nickel And Copper Metal Centers, Raj K. Gurung
Chemistry & Biochemistry Theses & Dissertations
Transition metal complexes with Schiff base ligands offer a wide application in the field of development of catalysis and material. The straightforward synthesis allowed the structural modification and helped to optimize in various application of such complexes. Titanium-containing complexes have been reported to be important for their catalytic and material applications through the coordination of a tetradentate Schiff base ligand, viz. N, N’-ethylene bis(salicylideneiminate) dianion (salen). Studies reporting the characterization of achiral titanium(IV) salen complexes are scarce due to their intricate nature. Such complexes would be comparatively less expensive and easier to prepare synthetically and thus could represent an …
Lignin: A Likely Precursor Of A Significant Fraction Of Humic Substances Via Oxidative Transformations, Seyyedhadi Khatami
Lignin: A Likely Precursor Of A Significant Fraction Of Humic Substances Via Oxidative Transformations, Seyyedhadi Khatami
Chemistry & Biochemistry Theses & Dissertations
Lignin is a major component of decaying terrestrial vegetation in soils and has been arguably reported to contribute substantially to the formation of soil carbon humus, and natural dissolved organic matter (DOM). To better understand the process by which this humification occurs, lignin and lignin-derived monomers were subjected to both biotic and abiotic oxidation processes. Two well-known oxidative transformation strategies were employed. The first involved the fungal degradation of brown-rot degraded wood subjected to a white-rot fungus (Phanerochaete chrysosporium) whose enzymes are particularly effective in lignin degradation via enzymatic oxidation. This enzymatic attack was monitored by ultrahigh resolution …