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Beyond Nickel-Based Superalloys II

2016

Microstructure

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Full-Text Articles in Engineering

Microstructural Analysis And High Temperature Creep Of Mo-9si-8b Alloys With Al And Ge Additions, Peter Kellner, Rainer Völkl, Uwe Glatzel Jul 2016

Microstructural Analysis And High Temperature Creep Of Mo-9si-8b Alloys With Al And Ge Additions, Peter Kellner, Rainer Völkl, Uwe Glatzel

Beyond Nickel-Based Superalloys II

Refractory metals and their alloys show potential for high temperature applications, due to the increased melting point and creep resistance. Spark plasma sintering technology as well as argon arc melting is used to prepare quaternary and quinternary Mo-9Si-8B-xAl-yGe (x is 0 or 2; y is 0 or 2) samples. Compositions are stated in at.%. All the compositions consist of a Mo solid solution (α-Mo) and two intermetallic phases: Mo3Si (A15) and Mo5SiB2 (T2). On the one hand, no zirconium is added to the alloys to avoid evaporation of MoO3 due to the …


Mo-9si-8b Alloys With Additons Of Zr – Microstructure And Creep Properties, Uwe Glatzel, Christian Hochmuth, Rainer Völkl Jul 2016

Mo-9si-8b Alloys With Additons Of Zr – Microstructure And Creep Properties, Uwe Glatzel, Christian Hochmuth, Rainer Völkl

Beyond Nickel-Based Superalloys II

Three phase Mo-9Si-8B (at.%) alloys are a prominent example for a potential new high temperature structural material. Due to their high melting point and excellent creep resistance. In this study the effect of Zr addition (0…4 at.%) on the microstructure and creep properties of Mo-9Si-8B (at.%) alloys is investigated. Two powder metallurgical processes, hot isostatic pressing (HIP) and spark plasma sintering (SPS), are used to prepare specimens. The resulting microstructures are examined using SEM and TEM analysis. SPS alloys exhibit smaller grain sizes and fewer oxides compared to the HIP alloys, because of the oxygen availability during HIP. The more …


Microstructure And Creep Resistance Of Ti-Rich Mo + Mo5si3 + Mo5sib2 Alloys, Daniel Schliephake, Martin Heilmaier Jul 2016

Microstructure And Creep Resistance Of Ti-Rich Mo + Mo5si3 + Mo5sib2 Alloys, Daniel Schliephake, Martin Heilmaier

Beyond Nickel-Based Superalloys II

New materials are necessary to increase efficiency of power generation and aircraft engines by higher combustion temperatures. Recently, it was found that alloying with high amounts of Ti replaces Mo3Si by Mo5Si3 and stabilizes the phase field Mo + Mo5Si3 + Mo5SiB2, which could be beneficial for higher oxidation resistance, since Mo5Si3 is more oxidation resistant than Mo3Si. Additional, Ti-rich Mo-Si-B alloys show an increased creep resistance compared to Ti-free Mo-Si-B alloys and a significant reduction in the alloy density. However, using the …