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Li2b12h12·7nh3: A New Ammine Complex For Ammonia Storage Or Indirect Hydrogen Storage, Zhenguo Huang, Judith C. Gallucci, Xuenian Chen, Teshome B. Yisgedu, Hima Kumar Lingam, Sheldon G. Shore, Ji-Cheng Zhao
Li2b12h12·7nh3: A New Ammine Complex For Ammonia Storage Or Indirect Hydrogen Storage, Zhenguo Huang, Judith C. Gallucci, Xuenian Chen, Teshome B. Yisgedu, Hima Kumar Lingam, Sheldon G. Shore, Ji-Cheng Zhao
Australian Institute for Innovative Materials - Papers
A new ammine complex, Li2B12H12$7NH3, that can reversibly release all the NH3 at below 200oC and reabsorb NH3 at room temperature and 0.5 bar was synthesized and investigated for reversible ammonia storage or indirect hydrogen storage.
InterMolecular DiHydrogen- And Hydrogen-Bonding InterActions In DiAmmonium Closo-DecaHydroDecaBorate Sesquihydrate, Teshome B. Yisgedu, Xuenian Chen, Hima Kumar Lingam, Zhenguo Huang, Edward A. Meyers, Sheldon G. Shore, Ji-Cheng Zhao
InterMolecular DiHydrogen- And Hydrogen-Bonding InterActions In DiAmmonium Closo-DecaHydroDecaBorate Sesquihydrate, Teshome B. Yisgedu, Xuenian Chen, Hima Kumar Lingam, Zhenguo Huang, Edward A. Meyers, Sheldon G. Shore, Ji-Cheng Zhao
Australian Institute for Innovative Materials - Papers
The asymmetric unit of the title salt, 2NH4+_B10H102__1.5H2O or (NH4)2B10H10_1.5H2O, (I), contains two B10H102_ anions, four NH4+ cations and three water molecules. (I) was converted to the anhydrous compound (NH4)2B10H10, (II), by heating to 343 K and its X-ray powder pattern was obtained. The extended structure of (I) shows two types of hydrogen-bonding interactions (N-H_ _ _O and O-H_ _ _O) and two types of dihydrogen-bonding interactions (N- H_ _ _H-B and O-H_ _ _H-B). The N-H_ _ _H-B dihydrogen bonding forms a two-dimensional sheet structure, and hydrogen bonding (N-H_ _ _O and O-H_ _ _O) and O- H_ _ …