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Full-Text Articles in Engineering
Iron Phosphate Glass For The Immobilization Of Dehalogenated Salt Waste, Matthew Aaron Page
Iron Phosphate Glass For The Immobilization Of Dehalogenated Salt Waste, Matthew Aaron Page
All Theses
Electrochemical reprocessing can be used to recycle presently stored nuclear fuel and consists of dissolving that used fuel in molten salt and the waste produced from these processes is a small amount of a high-level salt waste. Vitrification has been selected as the primary means of safely disposing high and low level radioactive waste. This is due to glass’ ability to incorporate many elements within its matrix, and it is chemically durable with the addition of network formers and other glass forming chemicals. With over 90,000 tonnes of nuclear waste in the United States, the avoidance of additional steps required …
Optimization Of Processing Parameters For As2se3 Glass For Low Loss, High Strength Fibers, Baptiste Giroire
Optimization Of Processing Parameters For As2se3 Glass For Low Loss, High Strength Fibers, Baptiste Giroire
All Theses
Chalcogenide glasses have been widely studied due to their extraordinary transparency in the infrared (IR) region from 0.5 to 20 μm. This transparency combined with excellent thermo-mechanical properties, makes them ideal candidate for infrared optics including IR fiber optic applications. However, such non-oxide glasses generally exhibit low mechanical strength, as compared to their oxide counterpart, which are based on covalently bonded metal-oxygen species. In addition to mechanical robustness, low optical loss (hence low impurity content) is required for most IR optical materials, including the one in this study, amorphous arsenic tri-selenide, As2Se3. In this effort, As2Se3 glass was investigated and …
Nanoparticles In Solution-Derived Chalcogenide Glass Films, Spencer Novak
Nanoparticles In Solution-Derived Chalcogenide Glass Films, Spencer Novak
All Theses
The results in this thesis are from our efforts to modify the optical properties of solution-derived chalcogenide glass films by the incorporation of nanomaterials. First, the composition Ge23Sb7S70 was selected as the appropriate glass matrix for testing because solution-derived films of this composition have been well-studied in our group. Additionally, this composition was found to be less sensitive to certain processing parameters than As2S3, another well-studied, candidate chalcogenide glass composition, making Ge23Sb7S70 more suitable for the addition of nanomaterials. Optimization of film process parameters was performed to obtain high-quality films appropriate for doping with nanomaterials. This consisted of determining the …
Characterization And Optimization Of Solution-Derived Chalcogenide Glass Thin Films, Jacklyn Wilkinson
Characterization And Optimization Of Solution-Derived Chalcogenide Glass Thin Films, Jacklyn Wilkinson
All Theses
Chalcogenide glasses have many unique properties that allow them to be used in a variety of optical applications. Infrared transparency allows them to be used in sensors for molecules that have 'fingerprints' in the 2-25 μm range. By producing amorphous thin films of these materials, they can be incorporated into chemical sensors as planar waveguides and resonators. The goal of this work was to fabricate and characterize solution-derived chalcogenide thin films for use in chemical sensors with a source wavelength between 3-3.5 μm.
The structural and optical properties of the parent bulk glass were characterized and used as reference for …
Stress Relaxation Of Glass Using A Parallel Plate Viscometer, Guy-Marie Vallet
Stress Relaxation Of Glass Using A Parallel Plate Viscometer, Guy-Marie Vallet
All Theses
Currently, grinding and polishing is the traditional method for manufacturing optical glass lenses. However, for a few years now, precision glass molding has gained importance for its flexibility in manufacturing aspheric lenses. With this new method, glass viscoelasticity and more specifically stress relaxation are important phenomena in the glass transition region to control the molding process and to predict the final lens shape.
The goal of this research is to extract stress relaxation parameters in shear of Pyrex¨ glass by using a Parallel Plate Viscometer (PPV). The PPV machine was originally created to measure the viscosity of glass solid cylinders …