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Materials Science and Engineering

Chalcogenide

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Nanoparticles In Solution-Derived Chalcogenide Glass Films, Spencer Novak May 2012

Nanoparticles In Solution-Derived Chalcogenide Glass Films, Spencer Novak

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The results in this thesis are from our efforts to modify the optical properties of solution-derived chalcogenide glass films by the incorporation of nanomaterials. First, the composition Ge23Sb7S70 was selected as the appropriate glass matrix for testing because solution-derived films of this composition have been well-studied in our group. Additionally, this composition was found to be less sensitive to certain processing parameters than As2S3, another well-studied, candidate chalcogenide glass composition, making Ge23Sb7S70 more suitable for the addition of nanomaterials. Optimization of film process parameters was performed to obtain high-quality films appropriate for doping with nanomaterials. This consisted of determining the …


Characterization And Optimization Of Solution-Derived Chalcogenide Glass Thin Films, Jacklyn Wilkinson May 2012

Characterization And Optimization Of Solution-Derived Chalcogenide Glass Thin Films, Jacklyn Wilkinson

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Chalcogenide glasses have many unique properties that allow them to be used in a variety of optical applications. Infrared transparency allows them to be used in sensors for molecules that have 'fingerprints' in the 2-25 μm range. By producing amorphous thin films of these materials, they can be incorporated into chemical sensors as planar waveguides and resonators. The goal of this work was to fabricate and characterize solution-derived chalcogenide thin films for use in chemical sensors with a source wavelength between 3-3.5 μm.
The structural and optical properties of the parent bulk glass were characterized and used as reference for …