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Virginia Commonwealth University

Theses/Dissertations

2023

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Articles 1 - 19 of 19

Full-Text Articles in Engineering

Improving The Flexibility And Robustness Of Machine Tending Mobile Robots, Richard Ethan Hollingsworth Jan 2023

Improving The Flexibility And Robustness Of Machine Tending Mobile Robots, Richard Ethan Hollingsworth

Theses and Dissertations

While traditional manufacturing production cells consist of a fixed base robot repetitively performing tasks, the Industry 5.0 flexible manufacturing cell (FMC) aims to bring Autonomous Industrial Mobile Manipulators (AIMMs) to the factory floor. Composed of a wheeled base and a robot arm, these collaborative robots (cobots) operate alongside people while autonomously performing tasks at different workstations. AIMMs have been tested in real production systems, but the development of the control algorithms necessary for automating a robot that is a combination of two cobots remains an open challenge before the large scale adoption of this technology occurs in industry. Currently popular …


Pms And Gas Pollutants Removal By Electret Filter Media And Metal-Organic Frameworks (Mofs), Yu Zhang Jan 2023

Pms And Gas Pollutants Removal By Electret Filter Media And Metal-Organic Frameworks (Mofs), Yu Zhang

Theses and Dissertations

Indoor air quality (IAQ) has been becoming a major concern worldwide because statistical data showed that the indoor concentrations of gas pollutants, e.g., volatile organic compounds (VOCs) and particulate matters (PMs) are often 2–5 times higher than that of outdoors. Especially, people spend 87% of their time indoors and increasing to more than 90% during COVID-19 pandemic. The high concentration of these indoor air pollutants is mainly due to the reduced air exchange rate for the design of energy-efficient building construction and the increased usage of furnishings, glues, paints, furnaces, etc., leading to VOC outgassing and particle emission. Evidence has …


Novel Development Of A Low-Cost, Micrometer-Scale Tip-Enhanced Raman Spectroscopy System, John Yates Jan 2023

Novel Development Of A Low-Cost, Micrometer-Scale Tip-Enhanced Raman Spectroscopy System, John Yates

Theses and Dissertations

Modern scientific instruments are significant capital investments for universities. These investments can be outside of the funding capabilities of some smaller universities or departments and can be a significant barrier in the pursuit of scientific breakthroughs. This project aims to provide a template for universities or research groups to upgrade, at a reasonable price, an existing Raman spectroscopy system to a Tip-Enhanced Raman Spectroscopy (TERS) system. This system can serve as a permanent upgrade to an existing system or as a bridge necessary to prove the viability of a research path before significant capital investment in a commercial TERS system. …


Virtual Plc Platform For Security And Forensics Of Industrial Control Systems, Syed Ali Qasim Jan 2023

Virtual Plc Platform For Security And Forensics Of Industrial Control Systems, Syed Ali Qasim

Theses and Dissertations

Industrial Control Systems (ICS) are vital in managing critical infrastructures, including nuclear power plants and electric grids. With the advent of the Industrial Internet of Things (IIoT), these systems have been integrated into broader networks, enhancing efficiency but also becoming targets for cyberattacks. Central to ICS are Programmable Logic Controllers (PLCs), which bridge the physical and cyber worlds and are often exploited by attackers. There's a critical need for tools to analyze cyberattacks on PLCs, uncover vulnerabilities, and improve ICS security. Existing tools are hindered by the proprietary nature of PLC software, limiting scalability and efficiency.

To overcome these challenges, …


Portable Robotic Navigation Aid For The Visually Impaired, Lingqiu Jin Jan 2023

Portable Robotic Navigation Aid For The Visually Impaired, Lingqiu Jin

Theses and Dissertations

This dissertation aims to address the limitations of existing visual-inertial (VI) SLAM methods - lack of needed robustness and accuracy - for assistive navigation in a large indoor space. Several improvements are made to existing SLAM technology, and the improved methods are used to enable two robotic assistive devices, a robot cane, and a robotic object manipulation aid, for the visually impaired for assistive wayfinding and object detection/grasping. First, depth measurements are incorporated into the optimization process for device pose estimation to improve the success rate of VI SLAM's initialization and reduce scale drift. The improved method, called depth-enhanced visual-inertial …


Thermal Performance And Fluid Flow Studies Of Twisted Tape Inserts Using Scaled Surrogate Fluids For Molten Salt Energy Applications, Arturo Cabral Jan 2023

Thermal Performance And Fluid Flow Studies Of Twisted Tape Inserts Using Scaled Surrogate Fluids For Molten Salt Energy Applications, Arturo Cabral

Theses and Dissertations

Global energy consumption is expected to increase with population growth and innovative clean sources of energy are sought out that can help meet the needs of a continuously power-hungry world. Some of these innovative sources of energy use molten salts as their operating and cooling fluid, such as fission reactors, fusion reactors, and solar power with energy storage. Molten salts are considered due to their efficient heat transfer properties, thermal energy storage capabilities, and high operating temperatures. To expedite their deployment, a further understanding of the heat transfer systems is required to accurately design and develop the heat transfer components …


Investigating Tgf-Β1 And Fibronectin Signaling In Low Oxygen Environments, Caitlin E. Williams Jan 2023

Investigating Tgf-Β1 And Fibronectin Signaling In Low Oxygen Environments, Caitlin E. Williams

Theses and Dissertations

Breast cancer is the second leading cause of death in women, second to lung cancer. It’s one of the most well-known cancers, with almost 300,000 new cases estimated to be diagnosed in 2023. Breast cancer often begins in ductal epithelial cells, and these cells will typically undergo a cellular transformation process known as epithelial-mesenchymal transition (EMT) in early stages. Breast cancer becomes deadly when it reaches a metastatic stage. As a part of the metastatic process, transformed cells will conduct remodeling of the extracellular matrix (ECM) to allow for migration of an otherwise non-migratory cell type.

As dense tumors form, …


Computational Modeling Of Temporal Eeg Responses To Cyclic Binary Visual Stimulus Patterns, Connor M. Delaney Jan 2023

Computational Modeling Of Temporal Eeg Responses To Cyclic Binary Visual Stimulus Patterns, Connor M. Delaney

Theses and Dissertations

The human visual system serves as the basis for many modern computer vision and machine learning approaches. While detailed biophysical models of certain aspects of the visual system exist, little work has been done to develop an end-to-end model from the visual stimulus to the signals generated at the visual cortex measured via the scalp electroencephalogram (EEG). The creation of such a model would not only provide a better understanding of the visual processing pathways but would also facilitate the design and evaluation of more robust visual stimuli for brain-computer interfaces (BCIs). A novel experiment was designed and conducted where …


The Wound Healing And Antibacterial Properties Of Mesenchymal Stromal Cell Extracellular Matrix Nanoparticles, Emily N. Wandling Jan 2023

The Wound Healing And Antibacterial Properties Of Mesenchymal Stromal Cell Extracellular Matrix Nanoparticles, Emily N. Wandling

Theses and Dissertations

Treatments for acute respiratory distress syndrome (ARDS) are still unavailable and the prevalence of the disease has only increased due to the Covid-19 pandemic. Mechanical ventilation regiments are still utilized to support declining lung function, but they also contribute to lung damage and increase the risk of bacterial infection. The anti-inflammatory and pro-regenerative abilities of mesenchymal stromal cells (MSCs) have shown to be a promising therapy for ARDS. We propose to utilize the regenerative effects of MSC secretome and the extracellular matrix (ECM) into a nanoparticle. Our mouse MSC (MMSC) ECM nanoparticles were characterized using size, zeta-potential, and mass spectrometry …


Wifi Sensing At The Edge Towards Scalable On-Device Wireless Sensing Systems, Steven M. Hernandez Jan 2023

Wifi Sensing At The Edge Towards Scalable On-Device Wireless Sensing Systems, Steven M. Hernandez

Theses and Dissertations

WiFi sensing offers a powerful method for tracking physical activities using the radio-frequency signals already found throughout our homes and offices. This novel sensing modality offers continuous and non-intrusive activity tracking since sensing can be performed (i) without requiring wearable sensors, (ii) outside the line-of-sight, and even (iii) through the wall. Furthermore, WiFi has become a ubiquitous technology in our computers, our smartphones, and even in low-cost Internet of Things devices. In this work, we consider how the ubiquity of these low-cost WiFi devices offer an unparalleled opportunity for improving the scalability of wireless sensing systems. Thus far, WiFi sensing …


Aerosol Synthesis Of Tungsten Bronze Particles For Nir Shielding, Hao Tu Jan 2023

Aerosol Synthesis Of Tungsten Bronze Particles For Nir Shielding, Hao Tu

Theses and Dissertations

This dissertation emphasizes the need for efficient energy use in buildings and transportation due to global warming and the energy crisis. It suggests that improving energy efficiency can help reduce energy consumption and emissions and support sustainability. The dissertation introduces various transparent materials that can block near-infrared (NIR) radiation from solar radiation to save energy and money, and it highlights the growing market value of such products. The dissertation compares tungsten bronze with other NIR shielding materials and shows its advantages. The dissertation introduces a cheap and environmentally friendly method for continuously producing tungsten bronze particles via aerosol synthesis. Particle …


Material Extrusion-Based Additive Manufacturing: G-Code And Firmware Attacks And Defense Frameworks, Haris Rais Jan 2023

Material Extrusion-Based Additive Manufacturing: G-Code And Firmware Attacks And Defense Frameworks, Haris Rais

Theses and Dissertations

Additive Manufacturing (AM) refers to a group of manufacturing processes that create physical objects by sequentially depositing thin layers. AM enables highly customized production with minimal material wastage, rapid and inexpensive prototyping, and the production of complex assemblies as single parts in smaller production facilities. These features make AM an essential component of Industry 4.0 or Smart Manufacturing. It is now used to print functional components for aircraft, rocket engines, automobiles, medical implants, and more. However, the increased popularity of AM also raises concerns about cybersecurity. Researchers have demonstrated strength degradation attacks on printed objects by injecting cavities in the …


A Sustainable Ultrafiltration Of Sub-20 Nm Nanoparticles In Water And Isopropanol: Experiments, Theory And Machine Learning, Jie Mcatee Jan 2023

A Sustainable Ultrafiltration Of Sub-20 Nm Nanoparticles In Water And Isopropanol: Experiments, Theory And Machine Learning, Jie Mcatee

Theses and Dissertations

This research focused on ultrafiltration (UF) for particles down to 2 nm against membranes with larger pore size in water and IPA, which has the potential to save up to 90% of energy. This study developed electrospray (ES) - scanning mobility particle sizer (SMPS) method to fast and effective measure retention efficiencies for small particles (ZnS, Au and PSL) on polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF) and polycarbonate (PCTE) in different liquids. Theoretical models that could quantitatively explain the experimental results for small particles in medium-polarity organic solvents were also developed. Results showed that the highest efficiency was up to ~80% …


Synthesis And Application Of Redox-Active Covalent Organic Frameworks In Rechargeable Batteries, Mohammad K. Shehab Jan 2023

Synthesis And Application Of Redox-Active Covalent Organic Frameworks In Rechargeable Batteries, Mohammad K. Shehab

Theses and Dissertations

Synthesis and Application of Redox-Active Covalent Organic Frameworks in Rechargeable Batteries

Mohammad K. Shehab

Department of Chemistry, Virginia Commonwealth University, Richmond, Virginia 23284, United States

Abstract

In recent years, lithium-ion batteries (LIBs) have been considered the dominant energy storage devices for portable electronics and electric vehicles due to their high energy density, low self-discharge rate, and long cycle life. In LIBs, the traditional positive electrodes employed are mainly derived from metal-containing inorganic compounds composed of cobalt, iron, nickel, or manganese (LiCoO2, LiMn2O4, and LiFePO4) coupled with graphite as the negative electrode. Despite …


Radiation Shielding Effectiveness Of Hafnium Diboride (Hfb2) Reinforced Epoxy Composites For Enhanced Radiation Protection And Safety, Furkan Erdogan Jan 2023

Radiation Shielding Effectiveness Of Hafnium Diboride (Hfb2) Reinforced Epoxy Composites For Enhanced Radiation Protection And Safety, Furkan Erdogan

Theses and Dissertations

This thesis investigates the radiation shielding effectiveness of hafnium diboride (HfB2) reinforced epoxy composites, with the aim of enhancing radiation protection and safety in various applications. The study focuses on the development and characterization of HfB2-epoxy composites with varying weight percentages of HfB2 nanoparticles, as well as on the evaluation of their shielding effectiveness against gamma rays and thermal neutrons. The radiation shielding performance of the composites is assessed using gamma-ray spectroscopy and neutron counting, and the neutron attenuation efficacy is compared with that of 5% borated high-dense polyethylene. The results indicate that the HfB2-epoxy composites exhibit promising radiation shielding …


Model Based Systems Engineering Approaches To Chemicals And Materials Manufacturing, Quang Le Jan 2023

Model Based Systems Engineering Approaches To Chemicals And Materials Manufacturing, Quang Le

Theses and Dissertations

Model-based systems engineering (MBSE) is part of a long-term trend toward model-centric approaches adopted by many engineering disciplines. This work establishes the need for an MBSE approach by reviewing the importance, complexity, and vulnerability of the U.S. chemical supply chains. The origins, work processes, modeling approaches, and supporting tools of the systems engineering discipline (SE) are discussed, along with the limitations of the current Process Systems Engineering (PSE) framework. The case is made for MBSE as a more generalizable and robust approach. Systems modeling strategies for MBSE are introduced, as well as a novel MBSE method that supports the automation …


Mechanisms Of Emulsion Destabilization: An Investigation Of Surfactant, Stabilizer, And Detergent Based Formulations Using Diffusing Wave Spectroscopy, Jordan N. Nowaczyk Jan 2023

Mechanisms Of Emulsion Destabilization: An Investigation Of Surfactant, Stabilizer, And Detergent Based Formulations Using Diffusing Wave Spectroscopy, Jordan N. Nowaczyk

Theses and Dissertations

Conventional approaches for studying emulsions, such as microscopy and macroscopic phase tracking, present challenges when it comes to establishing detailed mechanistic descriptions of the impact of emulsifier and stabilizer additives. Additionally, while a combination of sizing methods and macroscopic phase tracking can provide insights into droplet size changes and concentration, the use of multiple measurements can be cumbersome and error-prone. It is the focus of this work, to present a new method for studying water in oil (W/O) emulsions that involves using diffusing wave spectroscopy (DWS) to examine the impact of three different surface stabilizing additives at varying concentrations. By …


Machine Learning Models To Automate Radiotherapy Structure Name Standardization, Priyankar Bose Jan 2023

Machine Learning Models To Automate Radiotherapy Structure Name Standardization, Priyankar Bose

Theses and Dissertations

Structure name standardization is a critical problem in Radiotherapy planning systems to correctly identify the various Organs-at-Risk, Planning Target Volumes and `Other' organs for monitoring present and future medications. Physicians often label anatomical structure sets in Digital Imaging and Communications in Medicine (DICOM) images with nonstandard random names. Hence, the standardization of these names for the Organs at Risk (OARs), Planning Target Volumes (PTVs), and `Other' organs is a vital problem. Prior works considered traditional machine learning approaches on structure sets with moderate success. We compare both traditional methods and deep neural network-based approaches on the multimodal vision-language prostate cancer …


Characterization And Decoding Of Speech Activity From Intracranial Signals, Pedram Zanganeh Soroush Jan 2023

Characterization And Decoding Of Speech Activity From Intracranial Signals, Pedram Zanganeh Soroush

Theses and Dissertations

Speech is the first and foremost means of human communication. Millions of people worldwide suffer from severe speech disorders due to neurological diseases such as amyotrophic lateral sclerosis (ALS), brain stem stroke, and severe paralysis. A speech neuroprosthesis that decodes speech directly from neural signals could dramatically improve life for these individuals. Recent studies have demonstrated that it is possible to decode and synthesize various aspects of acoustic speech directly from intracranial measurements of electrophysiological brain activity. For those who have completely lost the ability to speak, the objective is to synthesize acoustic speech directly from brain activity during imagined …