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Virginia Commonwealth University

Theses/Dissertations

2004

Electrospinning

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Full-Text Articles in Engineering

Electrospinning As A Processing Method For Electroactive Polymers And Composites, Kristin Joy Pawlowski Jan 2004

Electrospinning As A Processing Method For Electroactive Polymers And Composites, Kristin Joy Pawlowski

Theses and Dissertations

Electrospinning was examined for its potential to create functional materials. Three distinct electroactive materials were electrospun into fibers and fiber mats and then characterized with the intent of determining their utility in aerospace and biomedical applications such as micro-air vehicles and the cardiovascular system. Electrospun Graft Elastomers demonstrated potential as actuators, as electromechanical strain testing showed comparable response to the film form of this material. Further improvement of electroactive response was realized with high dielectric inclusions and fiber orientation. Electrospin processing imparted piezoelectric properties to the fibers of poly(vinylidene fluoride). Differential scanning calorimetry and infrared spectroscopy indicated a degree of …


Characterization Of Aligned Carbon Nanotube/Polymer Composites, Sumanth Banda Jan 2004

Characterization Of Aligned Carbon Nanotube/Polymer Composites, Sumanth Banda

Theses and Dissertations

The main objective of this thesis is to efficiently disperse and align SWNTs in two different polymer matrices to obtain an orthotropic composite whose strength, stiffness and electrical properties depend on the orientation of the SWNTs. The SWNTs are successfully dispersed and aligned in a polyimide matrix and a polymer blend of UDMA/HDDMA. In-situ polymerization under sonication is used to disperse the SWNTs in polyimide matrix and sonication is used to disperse SWNTs in the UDMA/HDDMA matrix. In both cases, an electric field is used to align the SWNTs in the polymer matrices. In the polyimide, the SWNTs are aligned …