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Full-Text Articles in Engineering
Fabrication Of Hierarchically One-Dimensional Znxcd1-Xs/Nitio3 Nanostructures And Their Enhanced Photocatalytic Water Splitting Activity, Ling Wang, Guorui Yang, Silan Wang, Jianan Wang, Muhammad Salman Nasir, Caiyun Wang, Shengjie Peng, Wei Yan, Seeram Ramakrishna
Fabrication Of Hierarchically One-Dimensional Znxcd1-Xs/Nitio3 Nanostructures And Their Enhanced Photocatalytic Water Splitting Activity, Ling Wang, Guorui Yang, Silan Wang, Jianan Wang, Muhammad Salman Nasir, Caiyun Wang, Shengjie Peng, Wei Yan, Seeram Ramakrishna
Australian Institute for Innovative Materials - Papers
Hierarchically one-dimensional nanomaterials represent a kind of promising catalyst for photocatalytic of hydrogen generation, where the photoinduced charge carriers can effectively separate and be engaged in the target reaction. Herein, we report the synthesis of hierarchically one-dimensional ZnxCd1-xS/NiTiO3 nanofibers and the investigations of their photocatalytic performance. These well-designed nanofibers demonstrate a typically one-dimensional heterostructure with an excellent continuity, and the element mapping, X-ray diffraction, and X-ray photoelectron spectroscopy collectively confirm the ZnxCd1-xS nanoparticles being decorated on the surface of NiTiO3 nanofibers successfully. The ZnxCd1-xS/NiTiO3 nanofibers exhibit enhanced efficiency in photocatalytic hydrogen production under visible light, compared with the ZnxCd1-xS/TiO2 nanofibers. …
Designed Conducting Polymer Composites That Facilitate Long-Lived, Light-Driven Oxygen And Hydrogen Evolution From Water In A Photoelectrochemical Concentration Cell (Pecc), Mohammed Alsultan, Khalid Zainulabdeen, Pawel W. Wagner, Gerhard F. Swiegers, Holly Warren
Designed Conducting Polymer Composites That Facilitate Long-Lived, Light-Driven Oxygen And Hydrogen Evolution From Water In A Photoelectrochemical Concentration Cell (Pecc), Mohammed Alsultan, Khalid Zainulabdeen, Pawel W. Wagner, Gerhard F. Swiegers, Holly Warren
Australian Institute for Innovative Materials - Papers
Light-driven water-splitting to generate hydrogen and oxygen from water is typically carried out in an electrochemical cell with an external voltage greater than 1.23 V applied between the electrodes. In this work, we examined the use of a concentration/chemical bias as a means of facilitating water-splitting under light illumination without the need for such an externally applied voltage. Such a concentration bias was created by employing a pH differential in the liquid electrolytes within the O2-generating anode half-cell and the H2-generating cathode half-cell. A novel, stretchable, highly ion-conductive polyacrylamide CsCl hydrogel was developed to connect the two half-cells. The key …
General Π-Electron-Assisted Strategy For Single-Atom (Ir, Pt, Ru, Pd, Fe, And Ni) Electrocatalysts With Bi-Functional Active Sites Toward Highly Efficient Water Splitting, Weihong Lai, Li-Fu Zhang, Wei-Bo Hua, Sylvio Indris, Zichao Yan, Zhe Hu, Binwei Zhang, Yani Liu, Li Wang, Min Liu, Rong Liu, Yunxiao Wang, Jiazhao Wang, Zhenpeng Hu, Hua-Kun Liu, Shulei Chou, Shi Xue Dou
General Π-Electron-Assisted Strategy For Single-Atom (Ir, Pt, Ru, Pd, Fe, And Ni) Electrocatalysts With Bi-Functional Active Sites Toward Highly Efficient Water Splitting, Weihong Lai, Li-Fu Zhang, Wei-Bo Hua, Sylvio Indris, Zichao Yan, Zhe Hu, Binwei Zhang, Yani Liu, Li Wang, Min Liu, Rong Liu, Yunxiao Wang, Jiazhao Wang, Zhenpeng Hu, Hua-Kun Liu, Shulei Chou, Shi Xue Dou
Australian Institute for Innovative Materials - Papers
Both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) are crucial to water splitting, but require alternative active sites. Now, a general pelectron- assisted strategy to anchor single-atom sites (M=Ir, Pt, Ru, Pd, Fe, Ni) on a heterogeneous support is reported. The Matoms can simultaneously anchor on two distinct domains of the hybrid support, four-fold N/C atoms (M@NC), and centers of Co octahedra (M@Co), which are expected to serve as bifunctional electrocatalysts towards the HER and the OER. The Ir catalyst exhibits the best water-splitting performance, showing a low applied potential of 1.603V to achieve 10 mAcm@2 …
Electrocatalytically Inactive Sns2 Promotes Water Adsorption/Dissociation On Molybdenum Dichalcogenides For Accelerated Alkaline Hydrogen Evolution, Yaping Chen, Xingyong Wang, Mengmeng Lao, Kun Rui, Xiaobo Zheng, Haibo Yu, Jing Ma, Shi Xue Dou, Wenping Sun
Electrocatalytically Inactive Sns2 Promotes Water Adsorption/Dissociation On Molybdenum Dichalcogenides For Accelerated Alkaline Hydrogen Evolution, Yaping Chen, Xingyong Wang, Mengmeng Lao, Kun Rui, Xiaobo Zheng, Haibo Yu, Jing Ma, Shi Xue Dou, Wenping Sun
Australian Institute for Innovative Materials - Papers
Molybdenum dichalcogenides, in particular, MoS2 and MoSe2, are very promising nonprecious metal-based electrocatalysts for hydrogen evolution reaction (HER) in acidic media. They exhibit inferior alkaline HER activity, however, due to the sluggish water dissociation process. Here, we design and synthesize new molybdenum dichalcogenide-based heterostructures with the basal planes decorated with SnS2 quantum dots towards enhanced alkaline HER activity. The electrochemical results reveal that the alkaline hydrogen evolution kinetics of molybdenum dichalcogenides is substantially accelerated after incorporation of SnS2 quantum dots. The optimal MoSe2/SnS2 heterostructure delivers a much lower overpotential of 285 mV than MoSe2 (367 mV) to reach a current …
Osmotic Versus Conventional Membrane Bioreactors Integrated With Reverse Osmosis For Water Reuse: Biological Stability, Membrane Fouling, And Contaminant Removal, Wenhai Luo, Hop Phan, Ming Xie, Faisal I. Hai, William E. Price, Menachem Elimelech, Long D. Nghiem
Osmotic Versus Conventional Membrane Bioreactors Integrated With Reverse Osmosis For Water Reuse: Biological Stability, Membrane Fouling, And Contaminant Removal, Wenhai Luo, Hop Phan, Ming Xie, Faisal I. Hai, William E. Price, Menachem Elimelech, Long D. Nghiem
Faculty of Engineering and Information Sciences - Papers: Part A
This study systematically compares the performance of osmotic membrane bioreactor - reverse osmosis (OMBR-RO) and conventional membrane bioreactor - reverse osmosis (MBR-RO) for advanced wastewater treatment and water reuse. Both systems achieved effective removal of bulk organic matter and nutrients, and almost complete removal of all 31 trace organic contaminants investigated. They both could produce high quality water suitable for recycling applications. During OMBR-RO operation, salinity build-up in the bioreactor reduced the water flux and negatively impacted the system biological treatment by altering biomass characteristics and microbial community structure. In addition, the elevated salinity also increased soluble microbial products and …
Effect Of Storage Environment On Hydrogen Generation By The Reaction Of Al With Water, Yin-Qiang Wang, Wei-Zhuo Gai, Xia-Yu Zhang, Hong-Yi Pan, Zhenxiang Cheng, Pingguang Xu, Zhen-Yan Deng
Effect Of Storage Environment On Hydrogen Generation By The Reaction Of Al With Water, Yin-Qiang Wang, Wei-Zhuo Gai, Xia-Yu Zhang, Hong-Yi Pan, Zhenxiang Cheng, Pingguang Xu, Zhen-Yan Deng
Australian Institute for Innovative Materials - Papers
Al powder was stored in saturated water vapor, oxygen, nitrogen and drying air separately for a time period of up to six months, the degradation behavior of Al activity was characterized by the reaction of Al with water. It was found that water vapor decreased the induction time for the beginning of Al-water reaction and reduced the total hydrogen generation per unit weight of Al, while oxygen increased the induction time and retarded the Al-water reaction. In contrast, the effect of nitrogen and drying air on Al activity was weak. The mechanism analyses indicated that water vapor promoted the hydration …
Effects Of Salinity Build-Up On The Performance Of An Anaerobic Membrane Bioreactor Regarding Basic Water Quality Parameters And Removal Of Trace Organic Contaminants, Xiaoye Song, James A. Mcdonald, William E. Price, Stuart J. Khan, Faisal I. Hai, Hao H. Ngo, Wenshan Guo, Long D. Nghiem
Effects Of Salinity Build-Up On The Performance Of An Anaerobic Membrane Bioreactor Regarding Basic Water Quality Parameters And Removal Of Trace Organic Contaminants, Xiaoye Song, James A. Mcdonald, William E. Price, Stuart J. Khan, Faisal I. Hai, Hao H. Ngo, Wenshan Guo, Long D. Nghiem
Faculty of Engineering and Information Sciences - Papers: Part A
The effects of elevated inorganic salt concentration on anaerobic membrane bioreactor (AnMBR) treatment regarding basic biological performance and trace organic contaminant (TrOC) removal were investigated. A set of 33 TrOCs were selected to represent pharmaceuticals, steroids, and pesticides in municipal wastewater. Results show potential adverse effects of increase in the bioreactor salinity to 15 g/L (as NaCl) on the performance of AnMBR with respect to chemical oxygen demand removal, biogas production, and the removal of most hydrophilic TrOCs. Furthermore, a decrease in biomass production was observed as salinity in the bioreactor increased. The removal of most hydrophobic TrOCs was high …
Modelling Water Molecules Inside Cyclic Peptide Nanotubes, Prangsai Tiangtrong, Ngamta Thamwattana, Duangkamon Baowan
Modelling Water Molecules Inside Cyclic Peptide Nanotubes, Prangsai Tiangtrong, Ngamta Thamwattana, Duangkamon Baowan
Faculty of Engineering and Information Sciences - Papers: Part A
Cyclic peptide nanotubes occur during the selfassembly process of cyclic peptides. Due to the ease of synthesis and ability to control the properties of outer surface and inner diameter by manipulating the functional side chains and the number of amino acids, cyclic peptide nanotubes have attracted much interest from many research areas. A potential application of peptide nanotubes is their use as artificial transmembrane channels for transporting ions, biomolecules and waters into cells. Here, we use the Lennard-Jones potential and a continuum approach to study the interaction of a water molecule in a cyclo[(-DAla- L-Ala)4-] peptide nanotube. Assuming that each …
Membrane Distillation And Membrane Electrolysis Of Coal Seam Gas Reverse Osmosis Brine For Clean Water Extraction And Naoh Production, Hung Duong, Mikel C. Duke, Stephen Gray, Bart Nelemans, Long D. Nghiem
Membrane Distillation And Membrane Electrolysis Of Coal Seam Gas Reverse Osmosis Brine For Clean Water Extraction And Naoh Production, Hung Duong, Mikel C. Duke, Stephen Gray, Bart Nelemans, Long D. Nghiem
Faculty of Engineering and Information Sciences - Papers: Part A
Membrane distillation (MD) and membrane electrolysis (ME) were evaluated for simultaneous fresh water extraction and NaOH production from a mixture of NaCl and NaHCO3 to simulate the composition of coal seam gas (CSG) reverse osmosis (RO) brine. Experimental results demonstrate the potential of MD for producing fresh water and simultaneously concentrating CSG RO brine prior to the ME process. MD water flux was slightly reduced by the increased feed salinity and the decomposition of bicarbonate to CO2 during the concentration of CSG RO brine. MD operation of CSG RO brine at a concentration factor of 10 (90% water recovery) was …
Water Reclamation And Nitrogen Extraction From Municipal Solid Waste Landfill Leachate, Long D. Nghiem, Faisal I. Hai, Andre Listowski
Water Reclamation And Nitrogen Extraction From Municipal Solid Waste Landfill Leachate, Long D. Nghiem, Faisal I. Hai, Andre Listowski
Faculty of Engineering and Information Sciences - Papers: Part A
This study aims to explore several innovative technologies including electrocoagulation, nanofiltration (NF), membrane distillation (MD), and ion exchange resin for clean water extraction and resource recovery from landfill leachate. Our results demonstrate the technical feasibility of water reuse and ammonia recovery from landfill leachate. Electrocoagulation was effective as a pretreatment step for the NF process and could remove most suspended solids and some organic matter. The results show that the combination of NF and MD can produce high-quality water from landfill leachate suitable for reuse applications with respect to heavy metals (with the exception of arsenic) and pharmaceutically active compounds …
A Rapid And Reliable Technique For N-Nitrosodimethylamine Analysis In Reclaimed Water By Hplc-Photochemical Reaction-Chemiluminescence, Takahiro Fujioka, Haruka Takeuchi, Hiroaki Tanaka, Long D. Nghiem, Kenneth P. Ishida, Hitoshi Kodamatani
A Rapid And Reliable Technique For N-Nitrosodimethylamine Analysis In Reclaimed Water By Hplc-Photochemical Reaction-Chemiluminescence, Takahiro Fujioka, Haruka Takeuchi, Hiroaki Tanaka, Long D. Nghiem, Kenneth P. Ishida, Hitoshi Kodamatani
Faculty of Engineering and Information Sciences - Papers: Part A
A fast and reliable analytical technique was evaluated and validated for determination of N-nitrosodimethylamine (NDMA) formation and rejection by reverse osmosis (RO) membranes in potable water reuse applications. The analytical instrument used in this study is high-performance liquid chromatography (HPLC), photochemical reaction (PR) and chemiluminescence (CL) e namely HPLC-PR-CL. Results reported here show that HPLC-PR-CL can be used to measure NDMA with a similar level of accuracy compared to conventional and more time-consuming techniques using gas chromatography and tandem mass spectrometry detection in combination with solid phase extraction. Among key residual chemicals (i.e. monochloramine, hydrogen peroxide and hypochlorite) in reclaimed …
Graphene/Pvdf Flat-Sheet Membrane For The Treatment Of Ro Brine From Coal Seam Gas Produced Water By Air Gap Membrane Distillation, Yun Chul Woo, Youngjin Kim, Wang-Geun Shim, Leonard D. Tijing, Minwei Yao, Long D. Nghiem, June-Seok Choi, Seung-Hyun Kim, Ho Kyong Shon
Graphene/Pvdf Flat-Sheet Membrane For The Treatment Of Ro Brine From Coal Seam Gas Produced Water By Air Gap Membrane Distillation, Yun Chul Woo, Youngjin Kim, Wang-Geun Shim, Leonard D. Tijing, Minwei Yao, Long D. Nghiem, June-Seok Choi, Seung-Hyun Kim, Ho Kyong Shon
Faculty of Engineering and Information Sciences - Papers: Part A
No abstract provided.
Evaluating Ionic Organic Draw Solutes In Osmotic Membrane Bioreactors For Water Reuse, Wenhai Luo, Faisal I. Hai, William E. Price, Menachem Elimelech, Long D. Nghiem
Evaluating Ionic Organic Draw Solutes In Osmotic Membrane Bioreactors For Water Reuse, Wenhai Luo, Faisal I. Hai, William E. Price, Menachem Elimelech, Long D. Nghiem
Faculty of Engineering and Information Sciences - Papers: Part A
The performance of two ionic organic draw solutes, namely sodium acetate (NaOAc) and ethylene-diamine-tetra acetic acid disodium salt (EDTA-2Na), during osmotic membrane bioreactor (OMBR) operation was investigated in this study. Their performance was compared to that of sodium chloride (NaCl). A reverse osmosis (RO) process was integrated with OMBR to form an OMBR-RO hybrid system for draw solute recovery and clean water production. Results show that the NaOAc and EDTA-2Na draw solutes significantly reduced salinity build-up in the bioreactor in comparison with NaCl during OMBR operation. At the same osmotic pressure, these two ionic organic draw solutions produced slightly lower …
Characterisation Of Water Sprays Using High-Speed Videography, Alan Green, Paul Cooper, Trent D. Penman, Ross A. Bradstock
Characterisation Of Water Sprays Using High-Speed Videography, Alan Green, Paul Cooper, Trent D. Penman, Ross A. Bradstock
Faculty of Engineering and Information Sciences - Papers: Part B
This paper reports on the characterisation of water sprays for the purpose of modelling the effectiveness of such sprays in mitigating the impacts of wildfires on residential buildings. Four types of water spray nozzles were experimentally tested and analysed using a single high-speed camera and image analysis software. The sprays were generated by a misting nozzle, a hollow-cone nozzle, a rotating 'butterfly' sprinkler and a deflector plate sprinkler. Back-illumination was used to produce silhouette images of droplets within each spray. The point spread function half-width of each droplet image was determined, to give an indication of the distance of the …
Aqueous Electrosynthesis Of An Electrochromic Material Based Water-Soluble Edot-Menh2 Hydrochloride, Hui Sun, Long Zhang, Liqi Dong, Xiaofei Zhu, Shouli Ming, Youshan Zhang, Huakun Xing, Xuemin Duan, Jingkun Xu
Aqueous Electrosynthesis Of An Electrochromic Material Based Water-Soluble Edot-Menh2 Hydrochloride, Hui Sun, Long Zhang, Liqi Dong, Xiaofei Zhu, Shouli Ming, Youshan Zhang, Huakun Xing, Xuemin Duan, Jingkun Xu
Australian Institute for Innovative Materials - Papers
2'-Aminomethyl-3,4-ethylenedioxythiophene (EDOT-MeNH2) showed unsatisfactory results when its polymerization occurred in organic solvent in our previous report. Therefore, a water-soluble EDOT derivative was designed by using hydrochloric modified EDOT-MeNH2 (EDOT-MeNH2·HCl) and electropolymerized in aqueous solution to form the corresponding polymer with excellent electrochromic properties. Moreover, the polymer was systematically explored, including electrochemical, optical properties and structure characterization. Cyclic voltammetry showed low oxidation potential of EDOT-MeNH2·HCl (0.85 V) in aqueous solution, leading to the facile electrodeposition of uniform the polymer film with outstanding electroactivity. Compared with poly(2′-aminomethyl- 3,4-ethylenedioxythiophene) (PEDOT-MeNH2), poly(2′-aminomethyl-3,4-ethylenedioxythiophene salt) (PEDOT-MeNH3 +A-) revealed higher efficiencies (156 cm2 C-1), lower bandgap (1.68 …
Size-Dependent Chemical Reactivity Of Silicon Nanocrystals With Water And Oxygen, Melanie L. Mastronardi, Kenneth K. Chen, Kristine Liao, Gilberto Casillas, Geoffrey A. Ozin
Size-Dependent Chemical Reactivity Of Silicon Nanocrystals With Water And Oxygen, Melanie L. Mastronardi, Kenneth K. Chen, Kristine Liao, Gilberto Casillas, Geoffrey A. Ozin
Australian Institute for Innovative Materials - Papers
A detailed investigation examines how the size of allylbenzene-capped silicon nanocrystals (ncSi:AB) affects their chemical reactivity with gaseous O2, H2O, and O2/H2O as probed by in situ luminescence spectroscopy. Specifically, changes in the photoluminescence (PL) of size-separated ncSi:AB are monitored through alterations of their PL absolute quantum yield (AQY) as well as the wavelength and intensity of their PL spectra over time. These experiments, conducted under both continuous and intermittent illumination, help elucidate the roles of O2, H2O, and mixtures of O2/H2O, with respect …
Oscillating Water Column Wave Energy Conversion Device Response Spectra, Brad Stappenbelt
Oscillating Water Column Wave Energy Conversion Device Response Spectra, Brad Stappenbelt
Faculty of Engineering and Information Sciences - Papers: Part A
The objective of the present work is to serve as a practical addendum to the discrete parameter Oscillating Water Column (OWC) Wave Energy Conversion (WEC) device model proposed by Folley and Whittaker [1] at the 24th International Conference on Offshore Mechanics and Arctic Engineering. In particular, a method for the interpretation of their discrete parameter model is presented, consisting of a translation from the tuning and air compressibility parameter map reported to a response spectrum representation. In this more commonly encountered form the model is more readily physically interpreted for design and analysis application.
Modeling Secondary Particle Tracks Generated By High-Energy Protons In Water, Francisco Blanco, Antonio Munoz, Diego T. Almeida, F. Ferreira Da Silva, Paulo Limao-Vieira, Alexey Verkhovtsev, L Ellis-Gibbings, K Krupa, A Traore, G Garcia
Modeling Secondary Particle Tracks Generated By High-Energy Protons In Water, Francisco Blanco, Antonio Munoz, Diego T. Almeida, F. Ferreira Da Silva, Paulo Limao-Vieira, Alexey Verkhovtsev, L Ellis-Gibbings, K Krupa, A Traore, G Garcia
Faculty of Engineering and Information Sciences - Papers: Part A
We present interaction probability data of low-energy secondary electrons and positrons produced due to the proton impact. The probability distribution functions serve as input data for the Low Energy Particle Track Simulation (LEPTS) approach which allows one to include the effect of low-energy species in medical applications of radiation and in ion-beam cancer therapy, in particular.
The Use Of Coastal Reservoirs And Spp Strategy To Provide Sufficient High Quality Water To Coastal Communities, Shu-Qing Yang, Samuel Kelly
The Use Of Coastal Reservoirs And Spp Strategy To Provide Sufficient High Quality Water To Coastal Communities, Shu-Qing Yang, Samuel Kelly
Faculty of Engineering and Information Sciences - Papers: Part B
Water quality-induced water shortage is emerging as one of the main threats for the growth of the world's population and economic development, especially for coastal cities in developing nations. This paper discusses how to supply enough sufficiently clean water to such cities using the technologies of coastal reservoirs and wetland pre-treatments, as well as employing the SPP strategy. The so-called coastal reservoir is defined as a freshwater reservoir situated in seawater which sources its water from river runoff; to improve its water quality, a wetland is used to pre-treat the runoff that is potentially polluted by domestic, agricultural and industrial …
The Optimisation Of The Secondary Cooling Water Distribution With Improved Genetic Algorithm In Continuous Casting Of Steels, Yu-Chun Zhai, Ying Li, Beiyue Ma, C Yan, Zhengyi Jiang
The Optimisation Of The Secondary Cooling Water Distribution With Improved Genetic Algorithm In Continuous Casting Of Steels, Yu-Chun Zhai, Ying Li, Beiyue Ma, C Yan, Zhengyi Jiang
Faculty of Engineering and Information Sciences - Papers: Part A
An improved genetic algorithm is presented for the water consumption of the secondary cooling zone based on the heat transfer model of the off-line bloom caster. This study is to control the existing cooling systems and the steel casting practises in order to produce steel with best possible quality. The fitness function of improved genetic algorithm is founded according to the metallurgical criteria. This algorithm coupled with heat transfer model and metallurgical criteria, added dynamic coding method and self-adapting mutation on the original genetic algorithm can increase water distribution adaptively and improve the process efficiency. The simulation results of T91 …
The Role Of Pyrimidine And Water As Underlying Molecular Constituents For Describing Radiation Damage In Living Tissue: A Comparative Study, Martina C. Fuss, L Ellis-Gibbings, Darryl B. Jones, M J. Brunger, Francisco Blanco, A Muñoz, Paulo Limao-Vieira, Gustavo Garcia
The Role Of Pyrimidine And Water As Underlying Molecular Constituents For Describing Radiation Damage In Living Tissue: A Comparative Study, Martina C. Fuss, L Ellis-Gibbings, Darryl B. Jones, M J. Brunger, Francisco Blanco, A Muñoz, Paulo Limao-Vieira, Gustavo Garcia
Faculty of Engineering and Information Sciences - Papers: Part A
Water is often used as the medium for characterizing the effects of radiation on living tissue. However, in this study, charged-particle track simulations are employed to quantify the induced physicochemical and potential biological implications when a primary ionising particle with energy 10 keV strikes a medium made up entirely of water or pyrimidine. Note that pyrimidine was chosen as the DNA/RNA bases cytosine, thymine, and uracil can be considered pyrimidine derivatives. This study aims to assess the influence of the choice of medium on the charged-particle transport, and identify how appropriate it is to use water as the default medium …
Electronic Structure And Photocatalytic Water Oxidation Activity Of Rtino2 (R = Ce, Pr And Nd) Perovskite Nitride Oxides, Spencer H. Porter, Zhenguo Huang, S X. Dou, Samantha Brown-Xu, Md. Golam Mahabub Sarwar, Roberto C. Myers, Patrick M. Woodward
Electronic Structure And Photocatalytic Water Oxidation Activity Of Rtino2 (R = Ce, Pr And Nd) Perovskite Nitride Oxides, Spencer H. Porter, Zhenguo Huang, S X. Dou, Samantha Brown-Xu, Md. Golam Mahabub Sarwar, Roberto C. Myers, Patrick M. Woodward
Australian Institute for Innovative Materials - Papers
Three perovskite nitride oxides CeTiNO2, PrTiNO2, and NdTiNO2 have been synthesized and their electronic structures and photocatalytic activities characterized and compared to LaTiNO2. All three compounds have band gaps that fall in the range 2.0 − 2.1 eV, very similar to LaTiNO2, which enables them to absorb a significant fraction of the visible spectrum. Photocatalytic oxygen evolution studies under visible light irradiation in the presence of a sacrificial electron acceptor (Ag+) show that the activity of NdTiNO2 (16 μmol/g/hr) is comparable to that of LaTiNO2 (17 μmol/g/hr), …
Hierarchical Heteroaggregation Of Binary Metal-Organic Gels With Tunable Porosity And Mixed Valence Metal Sites For Removal Of Dyes In Water, Asif Mahmood, Wei Xia, Nasir Mahmood, Qingfei Wang, Ruqiang Zou
Hierarchical Heteroaggregation Of Binary Metal-Organic Gels With Tunable Porosity And Mixed Valence Metal Sites For Removal Of Dyes In Water, Asif Mahmood, Wei Xia, Nasir Mahmood, Qingfei Wang, Ruqiang Zou
Australian Institute for Innovative Materials - Papers
Hierarchical heteronuclear metal-organic gels (MOGs) based on iron (Fe) and aluminium (Al) metal-organic framework (MOF) backbones bridged by tri-carboxylate ligands have firstly been synthesized by simple solvothermal method. Monometallic MOGs based on Fe or Al give homogenous monoliths, which have been tuned by introduction of heterogeneity in the system (mismatched growth). The developed gels demonstrate that surface areas, pore volumes and pore sizes can be readily tuned by optimizing heterogeneity. The work also elaborates effect of heterogeneity on size of MOG particles which increase substantially with increasing heterogeneity as well as obtaining mixed valence sites in the gels. High surface …
Water Reclamation From Shale Gas Drilling Flow-Back Fluid Using A Novel Forward Osmosis-Vacuum Membrane Distillation Hybrid System, Xue-Mei Li, Baolong Zhao, Zhongwei Wang, Ming Xie, Jianfeng Song, Long Nghiem, Tao He, Chi Yang, Chunxia Li, Ghang Chen
Water Reclamation From Shale Gas Drilling Flow-Back Fluid Using A Novel Forward Osmosis-Vacuum Membrane Distillation Hybrid System, Xue-Mei Li, Baolong Zhao, Zhongwei Wang, Ming Xie, Jianfeng Song, Long Nghiem, Tao He, Chi Yang, Chunxia Li, Ghang Chen
Faculty of Engineering and Information Sciences - Papers: Part A
This study examined the performance of a novel hybrid system of forward osmosis (FO) combined with vacuum membrane distillation (VMD) for reclaiming water from shale gas drilling flow-back fluid (SGDF). In the hybrid FO-VMD system, water permeated through the FO membrane into a draw solution reservoir, and the VMD process was used for draw solute recovery and clean water production. Using a SGDF sample obtained from a drilling site in China, the hybrid system could achieve almost 90% water recovery. Quality of the reclaimed water was comparable to that of bottled water. In the hybrid FO-VMD system, FO functions as …
Ozonation Of N-Nitrosamines In The Reverse Osmosis Concentrate From Water Recycling Applications, Takahiro Fujioka, Stuart Khan, James Mcdonald, Long Nghiem
Ozonation Of N-Nitrosamines In The Reverse Osmosis Concentrate From Water Recycling Applications, Takahiro Fujioka, Stuart Khan, James Mcdonald, Long Nghiem
Faculty of Engineering and Information Sciences - Papers: Part A
This study aims to evaluate the performance of ozone treatment for removing N-nitrosamines from reverse osmosis (RO) concentrate in water recycling applications. In the absence of any N-nitrosamine precursors, the destruction efficiency of N-nitrosamines was dependent on their molecular weight or the length of the alkyl chain in their molecular structure. Experiments conducted with RO concentrate showed that ozonation could lead to the formation of N-nitrosodimethylamine (NDMA) and N-nitrosodiethylamine (NDEA), resulting in an increase in concentrations of these N-nitrosamines. Nevertheless, ozonation was effective for destruction of N-nitrosamines with molecular weight greater than that of NDEA (102 g/mol). 2014 Copyright 2014 …
A Light-Assisted, Polymeric Water Oxidation Catalyst That Selectively Oxidizes Seawater With A Low Onset Potential, Jun Chen, Pawel W. Wagner, Lei Tong, Danijel Boskovic, Weimin Zhang, David L. Officer, Gordon G. Wallace, Gerhard F. Swiegers
A Light-Assisted, Polymeric Water Oxidation Catalyst That Selectively Oxidizes Seawater With A Low Onset Potential, Jun Chen, Pawel W. Wagner, Lei Tong, Danijel Boskovic, Weimin Zhang, David L. Officer, Gordon G. Wallace, Gerhard F. Swiegers
Australian Institute for Innovative Materials - Papers
Vapour phase polymerisation (vpp) of PEDOT to incorporate high levels of a sulphonated manganese porphyrin yields a vivid green conducting polymer that, under illumination, catalyzes selective oxidation of water from seawater from ca. 0.40 V (vs. NHE; Pt counter electrode) without observable chlorine formation. This onset potential is comparable to that of certain metal oxide semiconductors that achieve higher photocurrents but are not capable of selectively oxidising the water in seawater.
Behaviour Of A Compacted Silty Sand Under Constant Water Content Shearing, Ana Heitor, Cholachat Rujikiatkamjorn, Buddhima Indraratna
Behaviour Of A Compacted Silty Sand Under Constant Water Content Shearing, Ana Heitor, Cholachat Rujikiatkamjorn, Buddhima Indraratna
Faculty of Engineering and Information Sciences - Papers: Part A
This structure derived from compacting the soil at different water contents and energy levels can have a substantial effect on its shear strength. While the shear strength with varying suction can be estimated based on the saturated shear strength parameters and the unsaturated angle of shearing resistance (0b), limited studies have explored the variation of strength properties with different compaction states. In this paper, the shear strength of a silty sand soil was investigated using a conventional direct shear box under constant water content condition. The tests were conducted on specimens prepared by Proctor compaction with three different normal pressures. …
Coastal Reservoirs Strategy For Water Resource Development-A Review Of Future Trend, Jianli Liu, Shu-Qing Yang, Changbo Jiang
Coastal Reservoirs Strategy For Water Resource Development-A Review Of Future Trend, Jianli Liu, Shu-Qing Yang, Changbo Jiang
Faculty of Engineering and Information Sciences - Papers: Part A
Water use and access become a more and more important determinant of environmental equity and human development according to the view held by the UN [1]. Water scarcity is one of the major crises which has overarching implications for other world problems especially poverty, hunger, ecosystem degradation, desertification, climate change, threatening world peace and security [2]. In the decades to come, freshwater consumed by human will get to a tipping point. Many projects and concepts have been proposed and implemented for several years to improve the effectiveness of us-ing water. These research activities can be grouped as: desalination plants; water …
Mine Water Treatment Using A Vacuum Membrane Distillation System, Muttucumaru Sivakumar, M Ramezanianpour, G O Halloran
Mine Water Treatment Using A Vacuum Membrane Distillation System, Muttucumaru Sivakumar, M Ramezanianpour, G O Halloran
Faculty of Engineering and Information Sciences - Papers: Part A
Water scarcity and strict environmental regulations has seen the rapid development of membrane technologies in water and wastewater treatment. Effluent discharge from a local coal mine containing 2332 mg/L of TDS (Total Dissolved Solids), 14.4 mg/L of Ca, 2.72 mg/L of Mg, 1.92 mg/L of Fe and 3.38 mg/L of Al is treated by a vacuum membrane distillation system. This technology aims to remove particles and dissolved impurities by evaporation and condensation technique that mimics what occurs in nature within a water cycle. It employs a hollow-fiber membrane that enables to remove 99.9% of TDS from mine water. This paper …
Highly Water-Soluble Magnetic Iron Oxide (Fe3o4) Nanoparticles For Drug Delivery: Enhanced In Vitro Therapeutic Efficacy Of Doxorubicin And Mion Conjugates, Muhammad Irfan Majeed, Qunwei Lu, Wei Yan, Zhen Li, Irshad Hussain, Muhammad Nawaz Tahir, Wolfgang Tremel, Bien Tan
Highly Water-Soluble Magnetic Iron Oxide (Fe3o4) Nanoparticles For Drug Delivery: Enhanced In Vitro Therapeutic Efficacy Of Doxorubicin And Mion Conjugates, Muhammad Irfan Majeed, Qunwei Lu, Wei Yan, Zhen Li, Irshad Hussain, Muhammad Nawaz Tahir, Wolfgang Tremel, Bien Tan
Australian Institute for Innovative Materials - Papers
We report a simple one step protocol for the preparation of fairly monodisperse and highly water-soluble magnetic iron oxide nanoparticles (MIONs) through a co-precipitation method using a novel multifunctional, biocompatible and water-soluble polymer ligand dodecanethiol-polymethacrylic acid (DDT-PMAA). DDT-PMAA owing to its several intrinsic properties, not only efficiently controls the size of the MIONs but also gives them excellent water solubility, long time stability against aggregation and oxidation, biocompatibility and multifunctional surface rich in thioether and carboxylic acid groups. The molecular weight and concentration of the polymer ligand were optimized to produce ultrasmall (4.6 +/- 0.7 nm) MIONs with high magnetization …