Open Access. Powered by Scholars. Published by Universities.®
- Discipline
Articles 1 - 19 of 19
Full-Text Articles in Engineering
A Facile Approach To Synthesize Stable Cnts@Mno Electrocatalyst For High Energy Lithium Oxygen Batteries, Wenbin Luo, Shulei Chou, Jiazhao Wang, Yu-Chun Zhai, Hua-Kun Liu
A Facile Approach To Synthesize Stable Cnts@Mno Electrocatalyst For High Energy Lithium Oxygen Batteries, Wenbin Luo, Shulei Chou, Jiazhao Wang, Yu-Chun Zhai, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
A composite of manganese monoxide loaded onto carbon nanotubes (CNTs@MnO) has been synthesized by a facile approach, in which the CNTs form a continuous conductive network connecting the electrocatalyst MnO nanoparticles together to facilitate good electrochemical performance. The electrocatalyst MnO shows favourable rechargeability, and good phase and morphology stability in lithium oxygen batteries. Excellent cycling performance is also demonstrated, in which the terminal voltage is higher than 2.4 V after 100 cycles at 0.4 mA cm-2, with 1000 mAh g-1 (composite) capacity. Therefore, this hybrid material is promising for use as a cathode material for lithium oxygen …
Guanidinium Octahydrotriborate: An Ionic Liquid With High Hydrogen Storage Capacity, Weidong Chen, Zhenguo Huang, Guotao Wu, Teng He, Zhao Li, Juner Chen, Zaiping Guo, Hua-Kun Liu, Ping Chen
Guanidinium Octahydrotriborate: An Ionic Liquid With High Hydrogen Storage Capacity, Weidong Chen, Zhenguo Huang, Guotao Wu, Teng He, Zhao Li, Juner Chen, Zaiping Guo, Hua-Kun Liu, Ping Chen
Australian Institute for Innovative Materials - Papers
For chemical hydrogen storage, capacity is one key criterion that has spurred intense efforts to investigate compounds with high hydrogen content. The guanidinium cation and the octahydrotriborate anion possess 6 H+ and 8 H-, respectively. The combination of these two ions yields guanidinium octahydrotriborate with 13.8 wt% hydrogen. This paper presents its facile synthesis, as confirmed by 11B and 1H nuclear magnetic resonance spectroscopy. The results show that guanidinium octahydrotriborate is an ionic liquid with a melting point below -10°C, which makes it a possible injectable/pumpable hydrogen carrier. It decomposes selectively to hydrogen, in stark …
Dual Yolk-Shell Structure Of Carbon And Silica-Coated Silicon For High-Performance Lithium-Ion Batteries, L Y. Yang, H Z. Li, Jun Liu, Ziqi Sun, S S. Tang, M Lei
Dual Yolk-Shell Structure Of Carbon And Silica-Coated Silicon For High-Performance Lithium-Ion Batteries, L Y. Yang, H Z. Li, Jun Liu, Ziqi Sun, S S. Tang, M Lei
Australian Institute for Innovative Materials - Papers
Silicon batteries have attracted much attention in recent years due to their high theoretical capacity, although a rapid capacity fade is normally observed, attributed mainly to volume expansion during lithiation. Here, we report for the first time successful synthesis of Si/void/SiO2/void/C nanostructures. The synthesis strategy only involves selective etching of SiO2 in Si/SiO2/C structures with hydrofluoric acid solution. Compared with reported results, such novel structures include a hard SiO2-coated layer, a conductive carbon-coated layer, and two internal void spaces. In the structures, the carbon can enhance conductivity, the SiO2 layer has mechanically …
High Acetic Acid Production Rate Obtained By Microbial Electrosynthesis From Carbon Dioxide, Ludovic Jourdin, Timothy Grieger, Juliette Monetti, Victoria Flexer, Stefano Freguia, Yang Lu, Jun Chen, Mark S. Romano, Gordon G. Wallace, Jurg Keller
High Acetic Acid Production Rate Obtained By Microbial Electrosynthesis From Carbon Dioxide, Ludovic Jourdin, Timothy Grieger, Juliette Monetti, Victoria Flexer, Stefano Freguia, Yang Lu, Jun Chen, Mark S. Romano, Gordon G. Wallace, Jurg Keller
Australian Institute for Innovative Materials - Papers
High product specificity and production rate are regarded as key success parameters for large-scale applicability of a (bio)chemical reaction technology. Here, we report a significant performance enhancement in acetate formation from CO2, reaching comparable productivity levels as in industrial fermentation processes (volumetric production rate and product yield). A biocathode current density of -102 ± 1 A m-2 and an acetic acid production rate of 685 ± 30 (g m-2 day-1) have been achieved in this study. High recoveries of 94 ± 2% of the CO2 supplied as the sole carbon source and 100 ± 4% of electrons into the final …
3d Fe2(Moo4)3 Microspheres With Nanosheet Constituents As High-Capacity Anode Materials For Lithium-Ion Batteries, Hao Zheng, Shiqiang Wang, Jiazhao Wang, Jun Wang, Lin Li, Yun Yang, Chuanqi Feng, Ziqi Sun
3d Fe2(Moo4)3 Microspheres With Nanosheet Constituents As High-Capacity Anode Materials For Lithium-Ion Batteries, Hao Zheng, Shiqiang Wang, Jiazhao Wang, Jun Wang, Lin Li, Yun Yang, Chuanqi Feng, Ziqi Sun
Australian Institute for Innovative Materials - Papers
Three-dimensional (3D) Fe2(MoO4)3 microspheres with ultrathin nanosheet constituents are first synthesized as anode materials for the lithium-ion battery. It is interesting that the single-crystalline nanosheets allow rapid electron/ion transport on the inside, and the high porosity ensures fast diffusion of liquid electrolyte in energy storage applications. The electrochemical properties of Fe2(MoO4)3 as anode demonstrates that 3D Fe2(MoO4)3 microspheres deliver an initial capacity of 1855 mAh/g at a current density of 100 mA/g. Particularly, when the current density is increased to 800 mA/g, the reversible capacity of Fe2(MoO4)3 anode still arrived at 456 mAh/g over 50 cycles. The large and reversible …
High-Performance Flexible All-Solid-State Supercapacitor From Large Free-Standing Graphene-Pedot/Pss Films, Yuqing Liu, Bo Weng, Joselito M. Razal, Qun Xu, Chen Zhao, Yuyang Hou, Shayan Seyedin, Rouhollah Jalili, Gordon G. Wallace, Jun Chen
High-Performance Flexible All-Solid-State Supercapacitor From Large Free-Standing Graphene-Pedot/Pss Films, Yuqing Liu, Bo Weng, Joselito M. Razal, Qun Xu, Chen Zhao, Yuyang Hou, Shayan Seyedin, Rouhollah Jalili, Gordon G. Wallace, Jun Chen
Australian Institute for Innovative Materials - Papers
Although great attention has been paid to wearable electronic devices in recent years, flexible lightweight batteries or supercapacitors with high performance are still not readily available due to the limitations of the flexible electrode inventory. In this work, highly flexible, bendable and conductive rGO-PEDOT/PSS films were prepared using a simple bar-coating method. The assembled device using rGO-PEDOT/PSS electrode could be bent and rolled up without any decrease in electrochemical performance. A relatively high areal capacitance of 448 mF cm-2 was achieved at a scan rate of 10 mV s-1 using the composite electrode with a high mass loading (8.49 mg …
A New Strategy For Achieving A High Performance Anode For Lithium Ion Batteries-Encapsulating Germanium Nanoparticles In Carbon Nanoboxes, Dan Li, Hongqiang Wang, Hua-Kun Liu, Zaiping Guo
A New Strategy For Achieving A High Performance Anode For Lithium Ion Batteries-Encapsulating Germanium Nanoparticles In Carbon Nanoboxes, Dan Li, Hongqiang Wang, Hua-Kun Liu, Zaiping Guo
Australian Institute for Innovative Materials - Papers
A novel strategy to improve the electrochemical performance of a germanium anode is proposed via encapsulating germanium nanoparticles in carbon nanoboxes by carbon coating the precursor, germanium dioxide cubes, and then subjecting them to a reduction treatment. The complete and robust carbon boxes are shown to not only provide extra void space for the expansion of germanium nanoparticles after lithium insertion but also offer a large reactive area and reduced distance for the lithium diffusion. Furthermore, the thus-obtained composite, composed of densely stacked carbon nanoboxes encapsulating germanium nanoparticles (germanium at carbon cubes (Ge at CC)), exhibits a high tap density …
Two-Dimensional Nico2o4 Nanosheet-Coated Three-Dimensional Graphene Networks For High-Rate, Long-Cycle-Life Supercapacitors, Jiang Zhou, Ying Huang, Xiehong Cao, Bo Ouyang, Wenping Sun, Chaoliang Tan, Yu Zhang, Qinglang Ma, Shuquan Liang, Qingyu Yan, Hua Zhang
Two-Dimensional Nico2o4 Nanosheet-Coated Three-Dimensional Graphene Networks For High-Rate, Long-Cycle-Life Supercapacitors, Jiang Zhou, Ying Huang, Xiehong Cao, Bo Ouyang, Wenping Sun, Chaoliang Tan, Yu Zhang, Qinglang Ma, Shuquan Liang, Qingyu Yan, Hua Zhang
Australian Institute for Innovative Materials - Papers
We report the synthesis of two-dimensional (2D) NiCo2O4 nanosheet-coated three-dimensional graphene network (3DGN), which is then used as an electrode for high-rate, long-cycle-life supercapacitors. Using the 3DGN and nanoporous nanosheets, an ultrahigh specific capacitance (2173 F g-1 at 6 A g-1), excellent rate capability (954 F g-1 at 200 A g-1) and superior long-term cycling performance (94% capacitance retention after 14000 cycles at 100 A g-1) are achieved.
Surface Engineering And Design Strategy For Surface-Amorphized Tio 2 @Graphene Hybrids For High Power Li-Ion Battery Electrodes, Tengfei Zhou, Yang Zheng, Hong Gao, Shudi Min, Sean Li, Hua-Kun Liu, Zaiping Guo
Surface Engineering And Design Strategy For Surface-Amorphized Tio 2 @Graphene Hybrids For High Power Li-Ion Battery Electrodes, Tengfei Zhou, Yang Zheng, Hong Gao, Shudi Min, Sean Li, Hua-Kun Liu, Zaiping Guo
Australian Institute for Innovative Materials - Papers
Electrode materials with battery-like high capacity and capacitorlike rate performance are highly desirable, since they would signifi cantly advance next-generation energy storage technology. [ 1 ] TiO 2 has received increasing attention as an anode material for lithium-ion batteries (LIBs) due to its good reversible capacity and low volume expansion upon lithiation, as well as its low cost and safe lithiation potential. [ 2 ] The low lithium-ion mobility within the crystalline phase TiO 2 , however, together with its poor electrical conductivity, means that only a thin surface layer of the host material is available for Li intercalation at …
A Fe/Fe3o4/N-Carbon Composite With Hierarchical Porous Structure And In Situ Formed N-Doped Graphene-Like Layers For High-Performance Lithium Ion Batteries, Yao Li, Qing Meng, Shenmin Zhu, Zeng-Hui Sun, Hao Yang, Zhixin Chen, Chengling Zhu, Zaiping Guo, Di Zhang
A Fe/Fe3o4/N-Carbon Composite With Hierarchical Porous Structure And In Situ Formed N-Doped Graphene-Like Layers For High-Performance Lithium Ion Batteries, Yao Li, Qing Meng, Shenmin Zhu, Zeng-Hui Sun, Hao Yang, Zhixin Chen, Chengling Zhu, Zaiping Guo, Di Zhang
Faculty of Engineering and Information Sciences - Papers: Part A
Fe/Fe3O4/N-carbon composite consisting of a porous carbon matrix containing a highly conductive N-doped graphene-like network and Fe/Fe3O4 nanoparticles was prepared. The porous carbon has a hierarchical structure which is inherited from rice husk and the N-doped graphene-like network formed in situ. When used as an anode material for lithium batteries, the composite delivered a reversible capacity of approximately 610 mA h g(-1) at a current density of 200 mA g(-1) even after 100 cycles, due to the synergism between the unique hierarchical porous structures, highly electrically conductive N-doped graphene- like networks and nanosized particles of Fe/Fe3O4. This work provides a …
Interface Analysis And Hot Deformation Behaviour Of A Novel Laminated Composite With High-Cr Cast Iron And Low Carbon Steel Prepared By Hot Compression Bonding, Zhengyi Jiang, Xingjian Gao, Sheng-Li Li, Hong Mei Zhang, Dengfu Chen, Jian Zhong Xu
Interface Analysis And Hot Deformation Behaviour Of A Novel Laminated Composite With High-Cr Cast Iron And Low Carbon Steel Prepared By Hot Compression Bonding, Zhengyi Jiang, Xingjian Gao, Sheng-Li Li, Hong Mei Zhang, Dengfu Chen, Jian Zhong Xu
Faculty of Engineering and Information Sciences - Papers: Part A
A hot compression bonding process was developed to prepare a novel laminated composite consisting of high-Cr cast iron (HCCI) as the inner layer and low carbon steel (LCS) as the outer layers on a Gleeble 3500 thermomechanical simulator at a temperature of 950 °C and a strain rate of 0.001 S-1. Interfacial bond quality and hot deformation behaviour of the laminate were studied by microstructural characterisation and mechanical tests. Experimental results show that the metallurgical bond between the constituent metals was achieved under the proposed bonding conditions without discernible defects and the formation of interlayer or intermetallic layer …
Excellent Melt Lubrication Of Alkali Metal Polyphosphate Glass For High Temperature Applications, A Kiet Tieu, Shanhong Wan, Ning Kong, Qiang Zhu, Hongtao Zhu
Excellent Melt Lubrication Of Alkali Metal Polyphosphate Glass For High Temperature Applications, A Kiet Tieu, Shanhong Wan, Ning Kong, Qiang Zhu, Hongtao Zhu
Faculty of Engineering and Information Sciences - Papers: Part A
A new class of high temperature lubricant of inorganic alkali metal polyphosphate was developed for hot metal forming, which involved a fundamental knowledge of melt lubrication. At elevated temperature a 55% reduction in friction and a 50% decrease in wear were achieved by the presence of the molten polyphosphate lubrication, as well as the excellent anti-oxidation capability at the rubbing steel/steel interface, which closely correlated with the tribo-induced hierarchical structure at the rubbing interface. This inorganic polyphosphate lubricant can be called a smart polymeric material, which will be an eco-friendly alternative for high temperature applications. This journal is
Comparative Evaluation Of Modern Dosimetry Techniques Near Low- And High-Density Heterogeneities, Eyad A. Alhakeem, Sami Alshaikh, Anatoly B. Rosenfeld, Sergei F. Zavgorodni
Comparative Evaluation Of Modern Dosimetry Techniques Near Low- And High-Density Heterogeneities, Eyad A. Alhakeem, Sami Alshaikh, Anatoly B. Rosenfeld, Sergei F. Zavgorodni
Faculty of Engineering and Information Sciences - Papers: Part A
The purpose of this study is to compare performance of several dosimetric methods in heterogeneous phantoms irradiated by 6 and 18 MV beams. Monte Carlo (MC) calculations were used, along with two versions of Acuros XB, anisotropic analytical algorithm (AAA), EBT2 film, and MOSkin dosimeters. Percent depth doses (PDD) were calculated and measured in three heterogeneous phantoms. The first two phantoms were a 30 x 30 x 30 cm3 solid-water slab that had an air-gap of 20x 2.5 x 2.35 cm3. The third phantom consisted of 30 x 30 x 5 cm3 solid water slabs, two 30 x 30 x …
Modeling Secondary Particle Tracks Generated By High-Energy Protons In Water, Francisco Blanco, Antonio Munoz, Diego T. Almeida, F. Ferreira Da Silva, Paulo Limao-Vieira, Alexey Verkhovtsev, L Ellis-Gibbings, K Krupa, A Traore, G Garcia
Modeling Secondary Particle Tracks Generated By High-Energy Protons In Water, Francisco Blanco, Antonio Munoz, Diego T. Almeida, F. Ferreira Da Silva, Paulo Limao-Vieira, Alexey Verkhovtsev, L Ellis-Gibbings, K Krupa, A Traore, G Garcia
Faculty of Engineering and Information Sciences - Papers: Part A
We present interaction probability data of low-energy secondary electrons and positrons produced due to the proton impact. The probability distribution functions serve as input data for the Low Energy Particle Track Simulation (LEPTS) approach which allows one to include the effect of low-energy species in medical applications of radiation and in ion-beam cancer therapy, in particular.
Study Of The Consequences Of Co2 Released From High-Pressure Pipelines, Xiong Liu, Ajit R. Godbole, Cheng Lu, Guillaume Michal, Phillip Venton
Study Of The Consequences Of Co2 Released From High-Pressure Pipelines, Xiong Liu, Ajit R. Godbole, Cheng Lu, Guillaume Michal, Phillip Venton
Faculty of Engineering and Information Sciences - Papers: Part A
The development of the Carbon Capture and Storage (CCS) technique requires an understanding of the hazards posed by the operation of high-pressure CO2 pipelines. To allow the appropriate safety precautions to be taken, a comprehensive understanding of the consequences of unplanned CO2 releases is essential before the deployment of CO2 pipelines. In this paper, we present models for the predictions of discharge rate, atmospheric expansion and dispersion due to accidental CO2 releases from high-pressure pipelines. The GERG-2008 Equation of State (EOS) was used in the discharge and expansion models. This enabled more precise 'source strength' predictions. …
High Rate Serially Concatenated Codes With Low Error Floors, Bo Liu, Sheng Tong, Qinghua Guo, Jun Tong, Jiangtao Xi, Yanguang Yu
High Rate Serially Concatenated Codes With Low Error Floors, Bo Liu, Sheng Tong, Qinghua Guo, Jun Tong, Jiangtao Xi, Yanguang Yu
Faculty of Engineering and Information Sciences - Papers: Part A
Serial concatenation of Hamming codes and an accumulator has been shown to achieve near capacity performance at high code rates. However, these codes usually exhibit poor error floor performance due to their small minimum distances. To overcome this weakness, we propose to replace the outer Hamming codes by product codes constructed from Hamming codes and single-parity-check codes. In this way, the minimum distance of the outer code can be doubled, which is expected to increase the minimum distance of the serially concatenated code and thus to improve error floor performance. Three-dimensional EXIT chart is used for their convergence analysis and …
High Temperature Dislocation Structure And Nbc Precipitation In Three Ni-Fe-Nb-C Model Alloys, Andrii Kostryzhev, Parvez Mannan, Olexandra Marenych
High Temperature Dislocation Structure And Nbc Precipitation In Three Ni-Fe-Nb-C Model Alloys, Andrii Kostryzhev, Parvez Mannan, Olexandra Marenych
Faculty of Engineering and Information Sciences - Papers: Part A
In this original work, the dislocation structure and NbC precipitation were investigated in three Ni-based alloys (70Ni-Fe-0.331Nb-0.040C, 70Ni-Fe-0.851Nb-0.114C and 70Ni-Fe-1.420Nb-0.157C, wt%) thermomechanically processed in the temperature range of 1250-1075 °C. The dislocation structure inhomogeneity (dislocation networks and cell walls), which we observed in the middle and high Nb+C alloys, resulted from the dislocation pile-ups in the vicinity of >200 nm NbC particles. The dislocation density around >200 nm particles exceeded the average values by 5-7 times, and that in the cell walls might exceed the average values by 10 times. Twins and stacking faults were observed in all alloys after …
The Use Of Coastal Reservoirs And Spp Strategy To Provide Sufficient High Quality Water To Coastal Communities, Shu-Qing Yang, Samuel Kelly
The Use Of Coastal Reservoirs And Spp Strategy To Provide Sufficient High Quality Water To Coastal Communities, Shu-Qing Yang, Samuel Kelly
Faculty of Engineering and Information Sciences - Papers: Part B
Water quality-induced water shortage is emerging as one of the main threats for the growth of the world's population and economic development, especially for coastal cities in developing nations. This paper discusses how to supply enough sufficiently clean water to such cities using the technologies of coastal reservoirs and wetland pre-treatments, as well as employing the SPP strategy. The so-called coastal reservoir is defined as a freshwater reservoir situated in seawater which sources its water from river runoff; to improve its water quality, a wetland is used to pre-treat the runoff that is potentially polluted by domestic, agricultural and industrial …
3d Hierarchical Porous Graphene Aerogel With Tunable Meso-Pores On Graphene Nanosheets For High-Performance Energy Storage, Long Ren, K N. Hui, K S. Hui, Yundan Liu, Xiang Qi, Jianxin Zhong, Yi Du, Jianping Yang
3d Hierarchical Porous Graphene Aerogel With Tunable Meso-Pores On Graphene Nanosheets For High-Performance Energy Storage, Long Ren, K N. Hui, K S. Hui, Yundan Liu, Xiang Qi, Jianxin Zhong, Yi Du, Jianping Yang
Australian Institute for Innovative Materials - Papers
New and novel 3D hierarchical porous graphene aerogels (HPGA) with uniform and tunable mesopores (e.g., 21 and 53 nm) on graphene nanosheets (GNS) were prepared by a hydrothermal self-assembly process and an in-situ carbothermal reaction. The size and distribution of the meso-pores on the individual GNS were uniform and could be tuned by controlling the sizes of the Co3O4 NPs used in the hydrothermal reaction. This unique architecture of HPGA prevents the stacking of GNS and promises more electrochemically active sites that enhance the electrochemical storage level significantly. HPGA, as a lithium-ion battery anode, exhibited superior electrochemical performance, including a …