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Full-Text Articles in Engineering

Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou Oct 2013

Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of the intermetallic compounds NdMn2−xTixSi2(x = 0, 0.1, 0.2, and 0.3) have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3–450 K. The Curie temperature and Néel temperature of NdMn2Si2 decrease from TC = 36 K and TN = 380 K to TC = 14 K and TN = 360 K, respectively, on substitution of Ti (x = 0.3) for Mn. The magnetocaloric effect …


Modulation Of The Properties Of Thin Ferromagnetic Films With An Externally Applied Electric Field In Ferromagnetic/Piezoelectric/Ferromagnetic Hybrids, D Stamopoulos, M Zeibekis, Shujun Zhang Jan 2013

Modulation Of The Properties Of Thin Ferromagnetic Films With An Externally Applied Electric Field In Ferromagnetic/Piezoelectric/Ferromagnetic Hybrids, D Stamopoulos, M Zeibekis, Shujun Zhang

Australian Institute for Innovative Materials - Papers

In many cases, technological advances are based on artificial low-dimensional structures of heterogeneous constituents, thus called hybrids, that when come together they provide stand-alone entities that exhibit entirely different properties. Such hybrids are nowadays intensively studied since they are attractive for both basic research and oncoming practical applications. Here, we studied hybrids constituted of piezoelectric (PE) and ferromagnetic (FM) components in the form FM/PE/FM, ultimately aiming to provide means for the controlled modulation of the properties of the FM electrodes, originating from the strain imposed to them by the PE mediator when an electric field is applied. The PE component …


Effect Of Sintering Temperature On The Superconducting Properties Of Graphene Doped Mgb2, K S B De Silva, X Xu, Sanjeev Gambhir, D C K Wong, W X Li, Q Y. Hu Jan 2013

Effect Of Sintering Temperature On The Superconducting Properties Of Graphene Doped Mgb2, K S B De Silva, X Xu, Sanjeev Gambhir, D C K Wong, W X Li, Q Y. Hu

Australian Institute for Innovative Materials - Papers

A comprehensive study on the effects of sintering temperature on graphene-doped MgB2 superconductor was conducted. Graphene has emerged as an effective dopant that is capable of improving the critical current density (J-{\rm c}) and flux pinning at a very low doping level, with only a slight reduction of the critical temperature (T-{\rm c}). MgB2 undoped and graphene-doped bulk samples were prepared by the in situ method and sintered within a temperature range from 650 to 950 {\circ}\hbox{C}. It is surprising to note that at the doping level of 1 at.% the sample sintered at 850 {\circ}\hbox{C} shows a J\rm c …


Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa Jan 2013

Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa

Australian Institute for Innovative Materials - Papers

The layered perovskite compound Sr2-xGdxCoO 4 has not yet been subjected to detailed study so far. In this report, structures, transport, magnetic properties, and first principle calculations will be reported for the two dimensional compounds Sr 2-xGdxCoO4 (x 0.5, 0.75, 1, 1.25). Rietveld refinement revealed that these compounds are crystallized in K2NiF 4-type structures with space group I4/mmm. It was found that the lattice parameter c decreases as x increases. Through the Curies Weiss fitting of the temperature dependent magnetization, it was found that the Sr 1.25Gd0.75CoO4 sample exhibits a weak ferromagnetic to paramagnetic transition at about 62 K, with …


Surface Properties And Interaction Forces Of Biopolymer-Doped Conductive Polypyrrole Surfaces By Atomic Force Microscopy, Jani M. Pelto, Suvi P. Haimi, Aliisa S. Siljander, Susanna S. Miettinen, Kirsi M. Tappura, Michael J. Higgins, Gordon G. Wallace Jan 2013

Surface Properties And Interaction Forces Of Biopolymer-Doped Conductive Polypyrrole Surfaces By Atomic Force Microscopy, Jani M. Pelto, Suvi P. Haimi, Aliisa S. Siljander, Susanna S. Miettinen, Kirsi M. Tappura, Michael J. Higgins, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Surface properties and electrical charges are critical factors elucidating cell interactions on biomaterial surfaces. The surface potential distribution and the nanoscopic and microscopic surface elasticity of organic polypyrrole-hyaluronic acid (PPy-HA) were studied by atomic force microscopy (AFM) in a fluid environment in order to explain the observed enhancement in the attachment of human adipose stem cells on positively charged PPy-HA films. The electrostatic force between the AFM tip and a charged PPy-HA surface, the tip-sample adhesion force, and elastic moduli were estimated from the AFM force curves, and the data were fitted to electrostatic double-layer and elastic contact models. The …


'Laser Chemistry' Synthesis, Physicochemical Properties, And Chemical Processing Of Nanostructured Carbon Foams, Andres Seral-Ascaso, Rosa Garriga, Maria Luisa Sanjuan, Joselito M. Razal, Ruth Lahoz, Mariano Laguna, German F. De La Fuente, Edgar Munoz Jan 2013

'Laser Chemistry' Synthesis, Physicochemical Properties, And Chemical Processing Of Nanostructured Carbon Foams, Andres Seral-Ascaso, Rosa Garriga, Maria Luisa Sanjuan, Joselito M. Razal, Ruth Lahoz, Mariano Laguna, German F. De La Fuente, Edgar Munoz

Australian Institute for Innovative Materials - Papers

Laser ablation of selected coordination complexes can lead to the production of metal-carbon hybrid materials, whose composition and structure can be tailored by suitably choosing the chemical composition of the irradiated targets. This 'laser chemistry' approach, initially applied by our group to the synthesis of P-containing nanostructured carbon foams (NCFs) from triphenylphosphine-based Au and Cu compounds, is broadened in this study to the production of other metal-NCFs and P-free NCFs. Thus, our results show that P-free coordination compounds and commercial organic precursors can act as efficient carbon source for the growth of NCFs. Physicochemical characterization reveals that NCFs are low-density …


Synthesis Of Hollow Geo2 Nanostructures, Transformation Into Geoc, And Lithium Storage Properties, Li Li, Kuok H. Seng, Chuanqi Feng, Hua-Kun Liu, Zaiping Guo Jan 2013

Synthesis Of Hollow Geo2 Nanostructures, Transformation Into Geoc, And Lithium Storage Properties, Li Li, Kuok H. Seng, Chuanqi Feng, Hua-Kun Liu, Zaiping Guo

Australian Institute for Innovative Materials - Papers

In this work, we synthesize mesoporous and hollow germanium@carbon nanostructures through simultaneous carbon coating and reduction of a hollow ellipsoidal GeO2 precursor. The formation mechanism of GeO 2 ellipsoids and the ratio of Ge4+ to Sn4+ as the starting materials are also investigated. Compared to the solid ellipsoidal Ge@carbon (Ge@C-3), the hollow ellipsoidal Ge@C-1 sample exhibits better cycling stability (100% capacity retention after 200 cycles at the 0.2 C rate) and higher rate capability (805 mA h g-1 at 20 C) compared to Ge@C-3 due to its unique hollow structure; therefore, this hollow ellipsoidal Ge@carbon can be considered as a …


Thermoelectric Properties Of Ca3co4o9 And Ca2.8bi0.2co4o9 Thin Films In Their Island Formation Mode, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou Jan 2013

Thermoelectric Properties Of Ca3co4o9 And Ca2.8bi0.2co4o9 Thin Films In Their Island Formation Mode, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

Ca3Co4O9 and Ca2.8Bi 0.2Co4O9 thin films were fabricated on LaAlO3 (LAO) substrate using pulsed laser deposition technique and were studied for their thermoelectric (TE) properties in Stranski-Krastanov mode for the first time. The thin films consisted of 3D clusters/islands on a 14-nm thick 2D layer with cluster density being higher for Ca 2.8Bi0.2Co4O9 thin films. The clusters also represent areas of dislocation and therefore act as carrier scattering centers, which leads to a temperature-activated type conductivity. Seebeck coefficient as high as 136 and 163 u V/K was measured for the Ca 3Co4O9 and Ca2.8Bi 0.2Co4O9 thin films, respectively, which is …


Improved Dehydrogenation Properties Of The Combined Mg(Bh4) 2·6nh3-Nnh3bh3 System, Xiaowei Chen, Feng Yuan, Qinfen Gu, Yingbin Tan, Hua-Kun Liu, S X. Dou, Xuebin Yu Jan 2013

Improved Dehydrogenation Properties Of The Combined Mg(Bh4) 2·6nh3-Nnh3bh3 System, Xiaowei Chen, Feng Yuan, Qinfen Gu, Yingbin Tan, Hua-Kun Liu, S X. Dou, Xuebin Yu

Australian Institute for Innovative Materials - Papers

A combined strategy via mixing Mg(BH4)2·6NH3 with ammonia borane (AB) is employed to improve the dehydrogenation properties of Mg(BH4)2·6NH3. The combined system shows a mutual dehydrogenation improvement in terms of dehydrogenation temperature and hydrogen purity compared to the individual components. A further improved hydrogen liberation from the Mg(BH4)2·6NH3–6AB is achieved with the assistance of ZnCl2, which plays a crucial role in stabilizing the NH3 groups and promoting the recombination of NHδ+⋯HBδ−. Specifically, the Mg(BH4)2·6NH3–6AB/ZnCl2 (with a mole ratio of 1:0.5) composite is shown to release over 7 wt.% high-pure hydrogen (>99 mol%) at 95 °C within 10 min, thereby …


Influence Of Formulated Chemical Cleaning Reagents On The Surface Properties And Separation Efficiency Of Nanofiltration Membranes, Alexander Simon, William E. Price, Long D. Nghiem Jan 2013

Influence Of Formulated Chemical Cleaning Reagents On The Surface Properties And Separation Efficiency Of Nanofiltration Membranes, Alexander Simon, William E. Price, Long D. Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

This study investigated the impact of two caustic and one acidic cleaning formulations (namely MC11, PC98, and MC3, respectively) on the properties and separation efficiency of three different nanofiltration (NF) membranes (namely NF270, NF90 and TFC-SR100). Overall, the impact of chemical cleaning on surface properties and rejection was membrane and cleaning reagent specific. It was driven mostly by conformational changes of the membrane polymeric active skin layer in response to an extreme caustic or acidic environment and to a certain extent by the adsorption of cleaning additives (e.g., surfactants and chelating reagents). The influence of chemical cleaning on the membrane …


Mixed-Metal (Li, Al) Amidoborane: Synthesis And Enhanced Hydrogen Storage Properties, Guanglin Xia, Yingbin Tan, Xiaowei Chen, Zaiping Guo, Hua-Kun Liu, Xuebin Yu Jan 2013

Mixed-Metal (Li, Al) Amidoborane: Synthesis And Enhanced Hydrogen Storage Properties, Guanglin Xia, Yingbin Tan, Xiaowei Chen, Zaiping Guo, Hua-Kun Liu, Xuebin Yu

Faculty of Engineering and Information Sciences - Papers: Part A

Mixed-metal (Li, Al) amidoborane has been synthesized via mechanical ball milling of ammonia borane with lithium hexahydridoaluminate in different molar ratios. The reversible dehydrogenation properties of the thus-synthesized metallic amidoborane and its mixtures with ammonia borane in different ratios were systematically investigated in comparison with neat ammonia borane (AB). On the basis of thermogravimetric analysis and mass spectrometry results, the thus-synthesized mixed-metal amidoborane was shown to release around 10 wt% hydrogen below 200 degrees C, with an effective suppression of volatile side products. Furthermore, a synergistic effect between metallic amidoborane and ammonia borane has been identified, which leads to the …


Additive-Free Synthesis Of 3d Porous V2o5 Hierarchical Microspheres With Enhanced Lithium Storage Properties, Chaofeng Zhang, Zhixin Chen, Zaiping Guo, Xiong Wen Lou Jan 2013

Additive-Free Synthesis Of 3d Porous V2o5 Hierarchical Microspheres With Enhanced Lithium Storage Properties, Chaofeng Zhang, Zhixin Chen, Zaiping Guo, Xiong Wen Lou

Faculty of Engineering and Information Sciences - Papers: Part A

A facile synthesis of novel 3D porous V2O5 hierarchical microspheres has been developed, based on an additive-free solvothermal method and subsequent calcination. Due to their unique structure, these V2O5 microspheres display a very stable capacity retention of 130 mA h g (1) over 100 cycles at a current rate of 0.5 C, and show excellent rate capability with a capacity of 105 mA h g (1) even at the 30 C rate. The good electrochemical performance suggests that this unique hierarchical V2O5 material could be a promising candidate as a cathode material for lithium-ion batteries.


Microstructure And Mechanical Properties Of 1050/6061 Laminated Composite Processed By Accumulative Roll Bonding, Lihong Su, Cheng Lu, Guanyu Deng, A K. Tieu, Xudong Sun Jan 2013

Microstructure And Mechanical Properties Of 1050/6061 Laminated Composite Processed By Accumulative Roll Bonding, Lihong Su, Cheng Lu, Guanyu Deng, A K. Tieu, Xudong Sun

Faculty of Engineering and Information Sciences - Papers: Part A

1050/6061 laminated composite sheets have been fabricated by the accumulative roll bonding (ARB) using commercial 1050 and 6061 aluminium alloys. Through-thickness hardness and tensile testes have been conducted to examine the mechanical properties of the laminated composites. It has been found that the strength of the composite materials is between the strengths of 6061 and 1050 primary materials. The average hardness of the 6061 layer is almost twice of the average value of the 1050 layer for both one and two-cycle processed composites. Optical microscopy, scanning electron microscopy and transmission electron microscopy were used to evaluate the microstructure of the …


The Effect Of Cooling Rates On The Microstructure And Mechanical Properties Of Thermo-Mechanically Processed Ti-Al-Mo-V-Cr-Fe Alloys, Mansur Ahmed, Dmytro G. Savvakin, Orest M. Ivasishin, Elena V. Pereloma Jan 2013

The Effect Of Cooling Rates On The Microstructure And Mechanical Properties Of Thermo-Mechanically Processed Ti-Al-Mo-V-Cr-Fe Alloys, Mansur Ahmed, Dmytro G. Savvakin, Orest M. Ivasishin, Elena V. Pereloma

Faculty of Engineering and Information Sciences - Papers: Part A

Two near-β titanium alloys, Ti–5Al–5Mo–5V–1Cr–1Fe and a modified one containing 2 wt% Cr (Ti–5Al–5Mo–5V–2Cr–1Fe) were produced from Ti hydride precursor powders via the cost-effective blended elemental powder metallurgy technique. The effects of two cooling rates (10 K s−1 and 1 K s−1) during thermo-mechanical processing on the microstructure and mechanical properties were investigated using X-ray diffraction and scanning electron microscopy. X-ray line profile analysis revealed that dislocation densities and microstrain in β-Ti phase are higher than in α-Ti phase for all cases. In both alloys, slower cooling results in an increase in α volume fraction and promotes morphology of continuous …


Effects Of Tungsten Addition And Heat Treatment Conditions On Microstructure And Mechanical Properties Of Microalloyed Forging Steels, Jingwei Zhao, Zhengyi Jiang, Chong Soo Lee Jan 2013

Effects Of Tungsten Addition And Heat Treatment Conditions On Microstructure And Mechanical Properties Of Microalloyed Forging Steels, Jingwei Zhao, Zhengyi Jiang, Chong Soo Lee

Faculty of Engineering and Information Sciences - Papers: Part A

In the present work, the effects of tungsten (W) addition and heat treatment conditions on the microstructure, impact toughness and tensile properties of microalloyed forging steels were studied. Four kinds of microalloyed forging steels were produced by varying W additions (0, 0.5, 1 and 2 wt%). Heat treatment was carried out at temperatures ranging from 840 to 950 °C followed by air and furnace cooling. Mechanical tests were used to evaluate the room temperature Charpy impact and tensile properties. The resulting microstructures were analysed via optical microscope (OM), scanning electron microscope (SEM) and transmission electron microscope (TEM). The results show …


Enhancing Impact Fracture Toughness And Tensile Properties Of A Microalloyed Cast Steel By Hot Forging And Post-Forging Heat Treatment Processes, Jingwei Zhao, Zhengyi Jiang, Chong Soo Lee Jan 2013

Enhancing Impact Fracture Toughness And Tensile Properties Of A Microalloyed Cast Steel By Hot Forging And Post-Forging Heat Treatment Processes, Jingwei Zhao, Zhengyi Jiang, Chong Soo Lee

Faculty of Engineering and Information Sciences - Papers: Part A

In the present work, the effects of hot forging and post-forging heat treatment on the impact fracture toughness and tensile properties of a microalloyed cast steel were investigated. Mechanical tests were used to evaluate the room temperature impact fracture toughness and tensile properties of the steel. The resulting microstructures were analysed by optical microscope (OM), scanning electron microscope (SEM) and transmission electron microscope (TEM). The extraction replica technology was used to investigate the characterisation of complex precipitates formed during heat treatment. The obtained results showed that the coarse-grained microstructure of the forged specimen was significantly refined after post-forging heat treatment. …


Enhancing Mechanical Properties Of A Low-Carbon Microalloyed Cast Steel By Controlled Heat Treatment, Jingwei Zhao, Jeong Hun Lee, Yong Woo Kim, Zhengyi Jiang, Chong Soo Lee Jan 2013

Enhancing Mechanical Properties Of A Low-Carbon Microalloyed Cast Steel By Controlled Heat Treatment, Jingwei Zhao, Jeong Hun Lee, Yong Woo Kim, Zhengyi Jiang, Chong Soo Lee

Faculty of Engineering and Information Sciences - Papers: Part A

In the present work, detailed studies were made on the optimization of microstructure and mechanical properties of a low-carbon microalloyed cast steel through control of heat treatment conditions. Specimens were austenitized at temperatures ranging from 950 to 1200 °C for 2 h followed by different cooling methods (furnace, air and water). For analyzing the effect of holding time on mechanical properties, some cast specimens were austenitized at 1100 °C for different times followed by furnace cooling. After heat treatment, mechanical tests were employed to evaluate the room temperature Charpy impact and tensile properties. The characterization of complex precipitates formed during …


Mechanical Properties Of Al-Mg-Si Alloy Sheets Produced Using Asymmetric Cryorolling And Ageing Treatment, Hai-Liang Yu, A Kiet Tieu, Cheng Lu, Xiang-Hua Liu, Ajit Godbole, Charlie Kong Jan 2013

Mechanical Properties Of Al-Mg-Si Alloy Sheets Produced Using Asymmetric Cryorolling And Ageing Treatment, Hai-Liang Yu, A Kiet Tieu, Cheng Lu, Xiang-Hua Liu, Ajit Godbole, Charlie Kong

Faculty of Engineering and Information Sciences - Papers: Part A

An asymmetric cryorolling technique was used to reduce the thickness of an Al-Mg-Si alloy sheet from 1.5 mm to 0.19 mm. The samples were subsequently aged for 48 h at 100 degrees celcius. The hardness and tensile strength of both rolled and aged sheets increased with the number of passes up to the sixth pass, but the tensile stress decreased after the seventh pass. Investigation of the microstructure of the sheets showed that the grain size after seven passes was about 235 nm and revealed the presence of Fe-Cr-Mn-Si particles in the samples. The deformation of Fe-Cr-Mn-Si particles and sheet …


Tribological Properties Of Magnetite Precipitate From Oxide Scale In Hot-Rolled Microalloyed Steel, Xianglong Yu, Zhengyi Jiang, Dongbin Wei, Cunlong Zhou, Qingxue Huang, Daijun Yang Jan 2013

Tribological Properties Of Magnetite Precipitate From Oxide Scale In Hot-Rolled Microalloyed Steel, Xianglong Yu, Zhengyi Jiang, Dongbin Wei, Cunlong Zhou, Qingxue Huang, Daijun Yang

Faculty of Engineering and Information Sciences - Papers: Part A

Nano-magnetite (Fe3O4) particles have a potential to lead to the formation of lubrication tribofilm that reduces the friction and wear in hot steel strip rolling. In this paper, an attempt to fabricate the oxide film with magnetite precipitates from thermally-grown wustite (Fe1-xO) layer during isothermal cooling of low carbon microallyed steel, was obtained. The precipitation behaviors were investgated on Gleeble 3500 thermo-mechanical simulator under the humid air with water vaour content of 19.5 per vol percent. Several types of magnetite precipitates were examined using scanning electron microscope (SEM) with energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) analysis. The tribological …


Towards Improved Steel Alloy Designs For Control Of Weld Heat Affected Zone Properties, F J. Barbaro, Z Zhu, L Kuzmikova, H Li, J M. Gray Jan 2013

Towards Improved Steel Alloy Designs For Control Of Weld Heat Affected Zone Properties, F J. Barbaro, Z Zhu, L Kuzmikova, H Li, J M. Gray

Faculty of Engineering and Information Sciences - Papers: Part A

This paper reviews the current technology related to control of weld HAZ properties in high strength steels. The debate related to appropriate balance of Ti and N is addressed and it appears that a stoichiometric ratio provides optimum fracture toughness. The results are significant because despite the well established difficulties in controlling Ti/N ratio, this data now provides guidance in terms of alloy design to achieve optimum fracture toughness in the HAZ of welds. The enhanced resistance to grain coarsening behaviour of high Nb steels has now provided another incremental improvement in the weldability of steels for critical applications such …


Effect Of Particle Properties On The Discrete Element Simulation Of Wall Friction, Andrew Grima, Peter Wypych Jan 2013

Effect Of Particle Properties On The Discrete Element Simulation Of Wall Friction, Andrew Grima, Peter Wypych

Faculty of Engineering and Information Sciences - Papers: Part A

Modelling the interaction between particles and boundaries is of great interest and importance in many Discrete Element Method (DEM) applications where boundary failure conditions dictate the flow behaviour and velocity gradients of a bulk material. Bulk wall friction angles in DEM models are dependent on the mechanical properties of the particles and boundary material as well as the constraints of the contact models used, especially the tangential and rolling torque components. This paper examines the parameters determined from the calibration inclination test by conducting direct wall shear tests to validate the accuracy of the calibration parameters and the sensitivity of …


Facile Synthesis Of Hierarchical Networks Composed Of Highly Interconnected V2o5 Nanosheets Assembled On Carbon Nanotubes And Their Superior Lithium Storage Properties, Ruixiang Yu, Chaofeng Zhang, Qing Meng, Zhixin Chen, Hua-Kun Liu, Zaiping Guo Jan 2013

Facile Synthesis Of Hierarchical Networks Composed Of Highly Interconnected V2o5 Nanosheets Assembled On Carbon Nanotubes And Their Superior Lithium Storage Properties, Ruixiang Yu, Chaofeng Zhang, Qing Meng, Zhixin Chen, Hua-Kun Liu, Zaiping Guo

Faculty of Engineering and Information Sciences - Papers: Part A

Hierarchical networks with highly interconnected V2O5 nanosheets (NSs) anchored on skeletons of carbon nanotubes (CNTs) are prepared by a facile hydrothermal treatment and a following calcination for the first time. Benefiting from these unique structural features, the as-prepared CNT@V2O5 material shows dramatically excellent electrochemical performance with remarkable long cyclability (137-116 mA h g-1 after 400 cycles) at various high rates (20 C to 30 C) and very good rate capability for highly reversible lithium storage. The excellent electrochemical performance suggests its promising use as a cathode material for future lithium-ion batteries.


Polypyrrole-Coated Α-Lifeo2 Nanocomposite With Enhanced Electrochemical Properties For Lithium-Ion Batteries, Zhi-Jia Zhang, Jia-Zhao Wang, Shulei Chou, Hua-Kun Liu, Kiyoshi Ozawa, Hui-Jun Li Jan 2013

Polypyrrole-Coated Α-Lifeo2 Nanocomposite With Enhanced Electrochemical Properties For Lithium-Ion Batteries, Zhi-Jia Zhang, Jia-Zhao Wang, Shulei Chou, Hua-Kun Liu, Kiyoshi Ozawa, Hui-Jun Li

Faculty of Engineering and Information Sciences - Papers: Part A

A conducting alpha-LiFeO2-polypyrrole (alpha-LiFeO2-PPy) nanocomposite material was prepared by the chemical polymerization method as a cathode material for lithium-ion batteries. The porous alpha-LiFeO2 was prepared via the microwave hydrothermal method and a post-annealing. The X-ray diffraction, Fourier transform infrared spectroscopy, and field emission scanning electron microscopy measurements showed that the alpha-LiFeO2 nanoparticles were coated with PPy. The polypyrrole coating improves the reversible capacity and cycling stability (104 mAh g(-1) at 0.1C after 100 cycles) for lithium-ion batteries. Even at the high rate of 10C, the electrode showed more than 40% of the capacity at low rate (0.1C).


The Effect Of Chemical Composition On Microstructure And Properties Of Intercritically Reheated Coarse-Grained Heat-Affected Zone In X70 Steels, Zhixiong Zhu, Lenka Kuzmikova, Huijun Li, Frank J. Barbaro Jan 2013

The Effect Of Chemical Composition On Microstructure And Properties Of Intercritically Reheated Coarse-Grained Heat-Affected Zone In X70 Steels, Zhixiong Zhu, Lenka Kuzmikova, Huijun Li, Frank J. Barbaro

Faculty of Engineering and Information Sciences - Papers: Part A

The current study investigates the effect of different levels of Ti, N, and Ti/N ratios on microstructure and properties in the intercritically reheated coarse-grained heat-affected zone (ICCGHAZ) of two-pass submerged arc welds in API 5L grade X70 pipe. Gleeble simulation was employed to reproduce the ICCGHAZ of actual welds. Hardness and Charpy V-notch (CVN) tests were performed on the simulated samples. The microstructure of simulated ICCGHAZ was characterized by optical microscopy and scanning electron microscopy (SEM). LePera color etching technique was employed to identify and quantify the martensitic-austenitic (M-A) constituent. Results show that the simulated ICCGHAZ exhibited extremely low toughness, …


Dynamic Properties Of Sand-Tyre Chip Mixtures, M S. Mashiri, M. Neaz Sheikh, J S Vinod, Hing Ho Tsang Jan 2013

Dynamic Properties Of Sand-Tyre Chip Mixtures, M S. Mashiri, M. Neaz Sheikh, J S Vinod, Hing Ho Tsang

Faculty of Engineering and Information Sciences - Papers: Part A

The stockpiling of scrap tyres is a significant environmental hazard and has attracted ample research attention to explore viable solutions to recycling and reuse of scrap tyres. The authors have recently proposed a novel seismic isolation method using sand-tyre chips (STCh) mixture for protecting buildings and infrastructure. Although the static properties of STCh mixture have been extensively studied, the investigation on the dynamic properties of the mixture has been limited. The dynamic properties of STCh mixture are important to its application for seismic protection of infrastructure. This paper presents the dynamic properties (shear modulus and damping ratio) of STCh mixture …


Effects Of Tungsten Addition On The Microstructure And Mechanical Properties Of Microalloyed Forging Steels, Jingwei Zhao, Taekyung Lee, Jeong Hun Lee, Zhengyi Jiang, Chong Soo Lee Jan 2013

Effects Of Tungsten Addition On The Microstructure And Mechanical Properties Of Microalloyed Forging Steels, Jingwei Zhao, Taekyung Lee, Jeong Hun Lee, Zhengyi Jiang, Chong Soo Lee

Faculty of Engineering and Information Sciences - Papers: Part A

In the current study, the effects of tungsten (W) addition on the microstructure, hardness, and room/low [223 K and 173 K (-50 C and -100 C)] temperature tensile properties of microalloyed forging steels were systematically investigated. Four kinds of steel specimens were produced by varying the W additions (0, 0.1, 0.5, and 1 wt pct). The microstructure showed that the addition of W does not have any noticeable effect on the amount of precipitates. The precipitates in W-containing steels were all rich in W, and the W concentration in the precipitates increased with the increasing W content. The mean sizes …


Changes In Surface Properties And Separation Efficiency Of A Nanofiltration Membrane After Repeated Fouling And Chemical Cleaning Cycles, Alexander Simon, William E. Price, Long D. Nghiem Jan 2013

Changes In Surface Properties And Separation Efficiency Of A Nanofiltration Membrane After Repeated Fouling And Chemical Cleaning Cycles, Alexander Simon, William E. Price, Long D. Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

The aim of this study was to evaluate the changes in membrane surface properties and solute separation by a nanofiltration membrane during repetitive membrane fouling and chemical cleaning. Secondary treated effluent and model fouling solutions containing humic acids, sodium alginate, or silica colloids were used to simulate membrane fouling. Chemical cleaning was carried out using a commercially available caustic cleaning formulation. Carbamazepine and sulfamethoxazole were selected to examine the filtration behaviour of neutral and negatively charged organic compounds, respectively. Results show that the impact of membrane fouling on solute rejection is governed by pore blocking, modification of the membrane surface …


Crystallization, Phase Evolution And Ferroelectric Properties Of Sol-Gel-Synthesized Ba(Ti0.8zr0.2)O3- X(Ba0.7ca0.3)Tio3 Thin Films, Zeng-Mei Wang, Kuan Zhao, Xin-Li Guo, Wei Sun, Hua-Long Jiang, Xue-Qin Han, Xu-Tang Tao, Zhen-Xiang Cheng, Hong-Yang Zhao, Hideo Kimura, Guo-Liang Yuan, Jiang Yin, Zhi-Guo Liu Jan 2013

Crystallization, Phase Evolution And Ferroelectric Properties Of Sol-Gel-Synthesized Ba(Ti0.8zr0.2)O3- X(Ba0.7ca0.3)Tio3 Thin Films, Zeng-Mei Wang, Kuan Zhao, Xin-Li Guo, Wei Sun, Hua-Long Jiang, Xue-Qin Han, Xu-Tang Tao, Zhen-Xiang Cheng, Hong-Yang Zhao, Hideo Kimura, Guo-Liang Yuan, Jiang Yin, Zhi-Guo Liu

Australian Institute for Innovative Materials - Papers

A lead-free piezoelectric material with ultra-high properties, Ba(Ti0.8Zr0.2)O3-x(Ba0.7Ca0.3)TiO3(BZT-xBCT) nanocrystals was synthesized via a sol-gel method, and the corresponding thin films were also deposited on Pt/Ti/SiO2/Si substrates by a spin-coating approach. The BZT-xBCT thin film exhibited a high remnant polarization of 22.15 mC cm2 with a large coercive field of 68.06 kV cm1. The resultant gel is calcined at various elevated temperatures and studied with FTIR/XRD/Raman/DSC-TGA/AFM/SEM techniques for gel composition, crystallization, phase transition, thermochemistry and the morphology of the film. Although the room temperature crystal structure of the BZT-xBCT nanocrystals appears to be a standard perovskite structure by conventional X-ray diffraction …


The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou Jan 2013

The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

The lithium/sulfur battery is a promising electrochemical system with high capacity, which is well-known to undergo a complex multistep reaction during the discharge process. Two types of electrolytes including poly (ethylene glycol) dimethyl ether (PEGDME)-based and 1.3 - dioxolane (DOL)/ dimethoxyethane (DME)-based electrolytes were investigated here. Furthermore, LiNO3 additive was introduced into the electrolyte in order to effectively eliminate the overcharge effect. The lithium sulfur battery with 1.0 M LiN(CF3SO2)2 in PEGME with 0.1 M LiNo3 shows highly stable reversible capacity of 624.8 mAh g-1 after 200 cycles and improved average coulombic efficiency of 98 percent.


Bio-Ink Properties And Printability For Extrusion Printing Living Cells, Johnson H. Y Chung, Sina Naficy, Zhilian Yue, Robert Kapsa, Anita Quigley, Simon E. Moulton, Gordon G. Wallace Jan 2013

Bio-Ink Properties And Printability For Extrusion Printing Living Cells, Johnson H. Y Chung, Sina Naficy, Zhilian Yue, Robert Kapsa, Anita Quigley, Simon E. Moulton, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Additive biofabrication (3D bioprinting) makes it possible to create scaffolds with precise geometries, control over pore interconnectivity and architectures that are not possible with conventional techniques. Inclusion of cells within the ink to form a “bio-ink” presents the potential to print 3D structures that can be implanted into damaged/diseased tissue to promote highly controlled cell-based regeneration and repair. The properties of an ‘ink’ are defined by its formulation and critically influence the delivery and integrity of structure formed. Importantly, the ink properties need to conform to biological requirements necessary for the cell system that they are intended to support and …