Engineering Commons^™

Enabling Premixed Hydrogen-Air Combustion For Aeroengines Via Laboratory Experiment Modeling, Christopher James Caulfield

Masters Theses

All combustion systems from large scale power plants to the engines of cars to gas turbines in aircraft are looking for new fuel sources. Recently, clean energy for aviation has come into the foreground as an important issue due to the environment impacts of current combustion methods and fuels used. The aircraft industry is looking towards hydrogen as a new, powerful, and clean fuel of the future. However there are several engineering and scientific challenges to overcome before hydrogen can be deployed into the industry. These issues
range from storing the hydrogen in a viable cryogenic form for an aircraft …

The Controlled Synthesis Of Hydrogen Electrocatalysts For Alkaline Exchange Membrane Fuel Cell And Electrolysis Applications Via Chemical Vapor Deposition, Stefan Thurston Dubard Williams

Doctoral Dissertations

The development of catalysts for the electrochemical processes of hydrogen systems (e.g., fuel cells and electrolyzer systems) continues to be an attractive area of research for renewable energy technologies. One significant challenge has been developing hydrogen catalysts suitable for alkaline environments, mainly due to the sluggish kinetics of hydrogen reactions. In alkaline environments, the kinetics are decreased by two orders of magnitude when compared to acidic environments. Chemical vapor deposition (CVD) is a conventional method used to synthesize these types of catalysts. This effort discusses extending work being done using a modified CVD process known as “Poor Man’s” CVD (PMCVD) …

Mechanical Behavior Of Pipeline Steels And An Al0.1cocrfeni High-Entropy Alloy, Bilin Chen

Doctoral Dissertations

This dissertation is composed of two parts. The first part focuses on the mechanical behavior study on pipelines steels. More specifically, the effect of hydrogen on the deformation behavior of the crack tip of an X52 pipeline steel specimen, and the overload effects on the fatigue crack growth of an x70 pipeline weld metal are discussed. For the second part of the dissertation, fatigue behavior of an Al0.1CoCrFeNi high-entropy alloy (HEA) is studied, and the influence of heat treatment is discussed.

The objectives of the first part of this proposed work are to (1) detect the influence of hydrogen on …

Managing Exoelectrogenic Microbial Community Development Through Bioprocess Control For Conversion Of Biomass-Derived Streams, Alex James Lewis

Doctoral Dissertations

Bioelectrochemical systems are an emerging technology capable of utilizing aqueous waste streams generated during biomass conversion of lignocellulosic feedstocks to produce valuable co-products and thus, have potential to be integrated into biorefineries. In a microbial electrolysis cell, organic compounds are converted to electrons, protons, and CO₂ by fermentative and exoelectrogenic bacteria in the anode compartment. By having the ability to extract electrons from waste streams, these systems can treat water while also producing hydrogen, and thus can improve the efficiency of biomass to fuel production by minimizing external hydrogen requirement and enabling water recycle. The overall goal of this …

Studies Of High Temperature Hydrogen Related Damage In Welded Carbon Steel Components Used In Refineries, Maneel Bharadwaj

Masters Theses

Five materials encompassing various grades of carbon steel were received from retired and ex-service petroleum refinery equipment for root-cause evaluation of High Temperature Hydrogen Attack (HTHA) damage at UTK. These materials were submitted by three contributors: Irving Oil Refinery (IOR #1110-2), Valero (#67 & #1252134), and Phillips 66 (#555-S1 & #555-S2) on behalf of American Petroleum Institute (API). These materials originated from various flange-to-pipe welded components that were exposed in hydrogen pressure environment at elevated temperatures (> 640°F and >70 psia).

A singular crack originating at the flange inside surface just outside of the visible HAZ was observed in IOR …

Adsorption And Diffusion Of Gases In Nano-Porous Materials, Nethika Sahani Suraweera

Doctoral Dissertations

In this work, a systematic computational study directed toward developing a molecular-level understanding of gas adsorption and diffusion characteristics in nano-porous materials is presented. Two different types of porous adsorbents were studied, one crystalline and the other amorphous. Physisorption and diffusion of hydrogen in ten iso-reticular metal-organic frameworks (IRMOFs) were investigated. A set of nine adsorbents taken from a class of novel, amorphous nano-porous materials composed of spherosilicate building blocks and isolated metal sites was also studied, with attention paid to the adsorptive and diffusive behavior of hydrogen, methane, carbon dioxide and their binary mixtures. Both classes of materials were …

Fatigue Study Of Pipeline Steels, Bilin Chen

Masters Theses

Two types of pipeline steels, Alloy B [Fe-0.05C-1.52Mn-0.12Si-0.092Nb, weight percent (wt.%)] and Alloy C [Fe-0.04C-1.61Mn-0.14Si-0.096Nb, wt.%)], were tested. Vickers hardness and nanoindentation tests were used to obtain the hardness and elastic modulus. Compact-tension (CT) specimens were employed for fatigue experiments. Different frequencies (10 Hz, 1 Hz, and 0.1 Hz) and different stress ratios [0.1 and 0.5, stress ratio (R) is the ratio between P_min. [minimum applied load] and P_max.[maximum applied load]. R = P_min./P_max.] were used, and the tests were done in air, at room temperature. The effects of frequencies and different R …

Sustainability Analysis Of Personal Transportation For Near Urban Commuting, Theodore Ansink, Matthew Atchley, Virginia Browning, Yue Cao, Michelle Everett, James Hall Jr, William R. Henson, Eugene Ng, Michael Picklesimer, Justin Ridenour, Scott Teeters, James Wilson

Chancellor’s Honors Program Projects

No abstract provided.

Protein Engineering For The Enhanced Photo-Production Of Hydrogen By Cyanobacterial Photosystem I, Ifeyinwa Jane Iwuchukwu

Doctoral Dissertations

Photosystem I (PSI) from plants, algae, and cyanobacteria can mediate H2 evolution in vivo and in vitro. A simple, self-platinization procedure that permits stable PSI-mediated H2 evolution in vitro has been developed. The H2 evolution capabilities of PSI from Thermosynechococcus elongatus have been characterized. This organism utilizes cytochrome c6 (cyt c6) as the e- donor to P700. Using a solution-based, self-organized platinization of the PSI nanoparticles, this study demonstrates a sodium ascorbate-cyt-PSI-Pt-H2 electron transport and proton reduction system that yields light-dependent H2. The system was thermostable with H2 evolution increasing up to 55°C. In addition, stability studies have shown the …

Design And Installation Of A Compressed Hydrogen Fueling System In A 2009 Chevrolet Colorado, Nick Edward Shaffer, Dean Deter, Terrance Johnson, John Pate

Chancellor’s Honors Program Projects

No abstract provided.