Engineering Commons^™

Functional Bottlebrush Polymer Additives For Thin Films And Coatings, Travis S. Laws

Doctoral Dissertations

Bottlebrush polymers are a class of highly branched polymers consisting of polymeric side chains that are densely grafted to a linear backbone. Their highly branched architecture results in surface enrichment across a broad range of materials. The goal of my research has been centered around the design of functional bottlebrush polymers and their use as surface active additives in blend films and coatings.

In the first chapter, we examine the segregation behavior of polystyrene bottlebrushes that are blended with linear polystyrene. We systematically vary the lengths of the bottlebrush backbone (Nb), side-chain (Nsc), and the linear matrix (Nm) in order …

Trajectory Planning Of Non-Gravity Aligned (Nga) Segments In Arbitrary Directions For Large Scale Additive Manufacturing Of Metals (Lsamm), James Logan Mcneil

Doctoral Dissertations

Traditionally, slicing and path planning are done along the gravity-aligned direction of a part, causing more complex geometrical shapes to have unsupported overhangs. Wire Arc Additive Manufacturing (WAAM) has typically handled overhangs with a robotic part positioner; but, to extend the current capabilities of LSAMM, a new framework for slicing and building parts out of gravity alignment has been developed. The proposed framework focuses on segmenting more complex geometrical parts into gravity-aligned (GA), non-gravity aligned (NGA), and transition zones to support tool-path generation. GA and NGA segments can be planned with traditional slicing techniques, but the NGA tool-paths must be …

Redundant Kinematics Solution For A Combined 6dof Robotic Manipulator And 2dof Part Positioner In A Waam Application, Ethan C. Vals

Masters Theses

A typical wire arc additive manufacturing (WAAM) robot cell consists of a 6 DOF robot manipulator and a 2 DOF part positioner. Since the WAAM process requires a minimum of 5 DOFs, there are three redundant DOFs in the system that can be utilized to improve the robot manipulator positioning during part printing. In this thesis, the redundant kinematics of a manipulator and part positioner robot system are solved and then implemented on an actual robot system. The inverse kinematics of the manipulator and part positioner are solved as a kinematic chain using the pseudo-inverse Jacobian method. The two DOFs …

Tribological Testing And Analysis Of Ionic Liquids As Candidate Anti-Wear Additives For Next-Generation Engine Lubricants, William Charles Barnhill

Masters Theses

In this work, fourteen ionic liquids (ILs) were assayed as potential next-generation engine oil additives. After screening for corrosion, thermal stability and oil solubility, candidate additives were subjected to friction and wear tests in both boundary and mixed regime lubrication. While each IL demonstrated friction and wear reduction compared to base oil without any additives, oil miscible ILs tetraoctylphosphonium bis 2-ethylhexyl phosphate ([P8888][DEHP]) and trioctylammonium bis 2-ethylhexylphosphate ([N888H][DEHP]) were the best performers in bench tests with a XX% and XX% improvement in wear over the base oil respectively. Each of these ILs excellent solubility and superior performance was attributed to …

Dynamic Extruder Control For Polymer Printing In Big Area Additive Manufacturing, Alex Christopher Roschli

Masters Theses

Big Area Additive Manufacturing (BAAM) is 3D Printing on a large scale and can be used to create structures on the scale of cars and houses. Scaling up 3D printing to BAAM size meant fundamentally altering the traditional fused deposition modeling process by switching from a filament to a pellet material feed. This meant switching from a stepper motor extruder to a servo driven screw extruder. While increasing the throughput of the system, this new extruder increases the overall complexity. Effective control of the system is paramount to the success of BAAM enabling it to effectively scale in speed in …