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Characteristics Of The Hydrogen Electrode In High Temperature Steam Electrolysis Process, Chao Jin, Chenghao Yang, Fanglin Chen
Characteristics Of The Hydrogen Electrode In High Temperature Steam Electrolysis Process, Chao Jin, Chenghao Yang, Fanglin Chen
Faculty Publications
YSZ-electrolyte supported solid oxide electrolyzer cells (SOECs) using LSM-YSZ oxygen electrode but with three types of hydrogen electrode, Ni–SDC, Ni–YSZ and LSCM–YSZ have been fabricated and characterized under different steam contents in the feeding gas at 850°C. Electrochemical impedance spectra results show that cell resistances increase with the increase in steam concentrations under both open circuit voltage and electrolysis conditions, suggesting that electrolysis reaction becomes more difficult in high steam content. Pt reference electrode was applied to evaluate the contributions of the hydrogen electrode and oxygen electrode in the electrolysis process. Electrochemical impedance spectra and over potential of both electrodes …
Sr2Fe1.5Mo0.5O6 As Cathodes For Intermediate-Temperature Solid Oxide Fuel Cells With La0.8Sr0.2Ga0.87Mg0.13O3 Electrolyte, Guoliang Xiao, Qiang Liu, Fei Zhao, Lei Zhang, Changrong Xia, Fanglin Chen
Sr2Fe1.5Mo0.5O6 As Cathodes For Intermediate-Temperature Solid Oxide Fuel Cells With La0.8Sr0.2Ga0.87Mg0.13O3 Electrolyte, Guoliang Xiao, Qiang Liu, Fei Zhao, Lei Zhang, Changrong Xia, Fanglin Chen
Faculty Publications
The performance of Sr2Fe1.5Mo0.5O6 (SFMO) as a cathode material has been investigated in this study. The oxygen ionic conductivityof SFMO reaches 0.13 S cm-1 at 800°C in air. The chemical diffusion coefficient (Dchem) and surface exchange constant (kex) of SFMO at 750°C are 5.0 x 10-6 cm2 s-1 and 2.8 x 10-5 cm s-1, respectively, suggesting that SFMO may have good electrochemicalactivity for oxygen reduction. SFMO shows a thermal expansion coefficient (TEC) of 14.5 x 10-6 K-1 the …
Single-Particle Model For A Lithium-Ion Cell: Thermal Behavior, Meng Guo, Godfrey Sikha, Ralph E. White
Single-Particle Model For A Lithium-Ion Cell: Thermal Behavior, Meng Guo, Godfrey Sikha, Ralph E. White
Faculty Publications
The single-particle model presented by Santhanagopalan et al. [ J. Power Sources , 156 , 620 (2006)] is extended to include an energy balance. The temperature dependence of the solid phase diffusion coefficient of the lithium in the intercalation particles, the electrochemical reaction rate constants, and the open circuit potentials (OCPs) of the positive and negative electrodes are included in the model. The solution phase polarization is approximated using a nonlinear resistance, which is a function of current and temperature. The model is used to predict the temperature and voltage profiles in a lithium-ion cell during galvanostatic operations. The single-particle …