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Full-Text Articles in Engineering

Evaluation Of Ferrate Preoxidation For Drinking Water Treatment, Joseph E. Goodwill Nov 2015

Evaluation Of Ferrate Preoxidation For Drinking Water Treatment, Joseph E. Goodwill

Doctoral Dissertations

Ferrate (Fe(IV)) has been proposed as a viable alternative for pre-oxidation in drinking water treatment (Jiang & Lloyd, 2002; Sharma, Kazama, Jiangyong, & Ray, 2005). The primary advantages of ferrate include a strong oxidation potential without the formation of halogenated by-products. In addition, the by-product of ferrate oxidation, ferric iron (Fe(III)), may have beneficial impacts on downstream particle destabilization and removal processes. Also, ferrate has disinfectant properties and may also provide pathogen inactivation in drinking water (Sharma et al., 2005). However, despite these advantages, there is a dearth of research experience that examines the implications of using ferrate for treating …


Effects Of Disinfectants On The Formation Of Aldehydes, Megan Dutra Sep 2015

Effects Of Disinfectants On The Formation Of Aldehydes, Megan Dutra

Environmental & Water Resources Engineering Masters Projects

Disinfection by-products have been the subject of intense study in the water treatment community due to the established adverse health effects of many known by-products and the postulated adverse health effects of many other known and unknown by-products. Aldehydes are one such group of by-products, containing compounds of both known and postulated health effects. This thesis explores the formation of simple alkyl aldehydes due to different disinfectants; these relationships are important because they can aid in determining possible by-product formation of potentially harmful substances with a particular disinfectant or disinfectant combination. Compounds such as these biodegrade easily, presenting a potential …


Occurrence, Formation And Persistence Of Halobenzoquinones: A Case Study On 2, 6 -Dichloro-1, 4 -Benzoquinone, Aarthi Mohan Sep 2015

Occurrence, Formation And Persistence Of Halobenzoquinones: A Case Study On 2, 6 -Dichloro-1, 4 -Benzoquinone, Aarthi Mohan

Environmental & Water Resources Engineering Masters Projects

Halobenzoquinones (HBQs) constitute an emerging class of potentially carcinogenic disinfection by-products (DBPs). Given that HBQs are not measured in routine analysis of drinking water, there is little data on their occurrence in the USA. The presence of 2, 6-dichloro-1, 4-benzoquinone (2, 6-DCBQ) in US drinking water facilities was investigated in 8 utilities to provide an initial assessment of occurrence and fate in relation to the regulated DBPs. Point of entry (POE) and distribution system (DS) samples with DCBQ concentrations greater than the 90th percentile values were from treatment plants that used free chlorine. Across distribution systems, DCBQ exhibited decreasing concentrations …


Stream Temperature Modeling: A Modeling Comparison For Resource Managers And Climate Change Analysis, Lynn Brennan Jul 2015

Stream Temperature Modeling: A Modeling Comparison For Resource Managers And Climate Change Analysis, Lynn Brennan

Environmental & Water Resources Engineering Masters Projects

In the Northeast U.S. increasing stream temperatures due to climate change pose a serious threat to cool and cold water fish communities, as well as aquatic ecosystems as a whole. In this study, three stream temperature models were implemented for two different case-study basins in the Northeast Climate Science Center region. Two coupled hydrology-stream temperature (physical) models were used: VIC-RBM and SWAT-Ficklin et al. (2012). The third model implemented was a nonlinear regression (statistical) model developed by Mohseni et al. (1998). Metrics were developed to assess these models regarding their prediction skill, data input requirements, spatial and temporal resolutions, and …


Effects Of Sulfidation And Natural Organic Matter On The Deposition Of Silver Nanoparticles, Yunqui Chen Jun 2015

Effects Of Sulfidation And Natural Organic Matter On The Deposition Of Silver Nanoparticles, Yunqui Chen

Environmental & Water Resources Engineering Masters Projects

Environmental transformation through sulfidation and complexation with natural organic matter (NOM) are two major factors that may affect the fate and transport of silver nanoparticles (AgNPs) in the aquatic systems by changing their dissolution, deposition, and surface properties. To understand the impact of sulfidation and NOM on the aggregation and deposition of AgNPs, a combination of dynamic light scattering and quartz crystal microgravimetry with dissipation monitoring was used. Polyvinylpyrrolidone (PVP)-capped AgNPs that were modified through sulfidation and/or complexed with NOM had a greater extent of deposition than unmodified PVP-AgNPs. Specifically, the deposition extent of sulfidized AgNPs in the presence of …


Prioritizing Mitigation Of Road-Stream Crossings For Resident Aquatic Organisms By Accounting For Habitat Quantity, Quality, And Accessibility, Rachael L. Weiter May 2015

Prioritizing Mitigation Of Road-Stream Crossings For Resident Aquatic Organisms By Accounting For Habitat Quantity, Quality, And Accessibility, Rachael L. Weiter

Environmental & Water Resources Engineering Masters Projects

Road crossings and dams may act as barriers to movement for a wide range of aquatic organisms in lotic freshwater systems. Limited funding constrains the number of barriers that may be mitigated by repair or removal, so systematic methods of prioritization are needed for selecting barriers for mitigation. A new formulation is proposed that links the number of organisms in the watershed to the amount and quality of accessible habitat in order to quantify habitat connectivity of a watershed. The method is applied to a case study performed on the Upper West Branch of the Westfield River in Massachusetts, with …


Socioeconomic Assessment Of The Epic Sustainable Road Infrastructure Program In Nepal, Maria Fernandez, Trista Ristvedt Jan 2015

Socioeconomic Assessment Of The Epic Sustainable Road Infrastructure Program In Nepal, Maria Fernandez, Trista Ristvedt

School of Public Policy Capstones

Roads are being constructed in rural Nepal at a rapid pace. Due to a number of factors many of these roads are poorly built, often without any oversight or planning provided by an engineer; this causes a multitude of problems including roads that are not safe to travel in the rainy season, and damages to property and agricultural lands due to risk of landslide and increased erosion. IUCN's EPIC project in Nepal is intended to showcase an attainable option for local communities to construct and repair roads in such a way to improve their reliability and safety, while also decreasing …