Engineering Commons^™

Employing Discrete Solid Phases To Represent C-S-H Solid Solutions In The Cemdata07 Thermodynamic Database To Model Cement Hydration Using The Phreeqc Geochemical Software, Niall Holmes Dr., Mark Tyrer, Denis Kelliher

Articles

This paper presents a cement hydration model over time using the cemdata07 thermodynamic database and a series of derived discrete solid phases (DSPs) to represent calcium silicate hydrate (C-S-H) as a binary solid solution with two end-members. C-S-H in cement is amorphous and poorly crystalline with a range of molar Ca/Si ratios from 0.6 to 1.7. It displays strongly incongruent dissolution behaviour, where the release of calcium into solution is several orders of magnitude greater than silicon. It is, therefore, important that any cement hydration model provides a credible account of this behaviour. C-S-H has been described in the cemdata07 …

Modelling The Hydrating Behaviour Of Fly-Ash In Blended Cements Using Thermodynamics, Nikki Shaji, Niall Holmes Dr., Mark Tyrer

Conference papers

This paper presents a new method to thermodynamically model the hydration behaviour of fly-ash (FA) blended cements by deriving individual phase descriptions depending on the proportion of FA in the blended cement. The predicted hydrated phase assemblage, pore solution chemistries and pH over 1,000 days of hydration and with increasing FA proportions are presented. The thermodynamic data for the FA phases are derived using oxide proportions and mineral compositions are copied directly into the PHREEQC input file. The FA phases take account of all minerals to give a more accurate description of its behaviour during hydration. The calcium aluminosilicate hydrate …

Introducing A New Cement Hydration And Microstructure Model, Niall Holmes, Anselm Griffin, Bernard Enright, Denis Keliher

Conference papers

This paper presents a new cement hydration model to predict the microstructure evolution of hydrating tricalcium silicate (C3S). The model is written in MATLAB and employs the continuum approach and integrated particle kinetic relationships to show the change in C3S and the growth of Calcium Silicate Hydrate (C-S-H) and Calcium Hydroxide (CH) in the pore space over time.

Cement hydration is a highly complex process. While hydration models should never completely remove experimental analysis, they are an aid to better understand cement hydration and microstructure development by providing a method to analyse a large number of pastes with different cementitious …

Process Simulation Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell Stack, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

Biomass gasification-solid oxide fuel cell (BG-SOFC) combined heat and power (CHP) systems are of major interest in the context of climate change mitigation, energy security and increasing energy efficiency. Aspen Plus is employed to simulate various BG-SOFC CHP systems. The aim of the research work is to investigate the technical feasibility of these systems and to study the influence of important operating parameters and examine integration options. Systems based on dual fluidised bed steam gasification and tubular SOFC technologies are modelled. The cathode recycle and electric heater integration options are not attractive in comparison to the base case anode recycle …

Modelling Of Biomass Gasification Integrated With A Solid Oxide Fuel Cell System, Wayne Doherty

Doctoral

Biomass is of major interest as a renewable energy source in the context of climate change and energy security. Traditional biomass conversion technologies achieve low electrical efficiencies. Biomass gasification (BG) coupled with fuel cells offer higher efficiencies. Gasification is a process in which a carbonaceous fuel is converted to a combustible gas. It occurs when a controlled amount of oxidant is reacted at high temperatures with available carbon in a fuel within a gasifier. Two technologies (circulating fluidised bed air gasification and dual fluidised bed steam gasification) were modelled. Solid oxide fuel cells (SOFCs) are well suited to integration with …

Calculation Of Colouration Voltage For A Multifunctional Glazing Powered By Photovoltaic, Aritra Ghosh, Brian Norton, Aidan Duffy

Conference papers

Multifunctional glazing is a combination of various glazing systems and can comprise permutations of vacuum glazing, aerogel glazing, PV double glazing and Electrochromic (EC) glazing. It controls solar heat gain, improves thermal conductivity and can generate small scale electricity, in a variety of climates. The objective of this research is to investigate the switching voltage of multifunctional glazing, with respect to orientation, time of day and temperature of the system. We report a relation between temperature and voltage required for the switching condition.

Aspen Plus Simulation Of Biomass Gasification In A Steam Blown Dual Fluidised Bed, Wayne Doherty, Anthony Reynolds, David Kennedy

Book/Book Chapters

The efficient utilisation of biomass resources is of utmost importance. Biomass gasification offers much higher efficiencies than combustion. Gasification is a process in which a fuel is converted to a combustible gas (syngas). A dual fluidised bed gasifier known as the fast internally circulating fluidised bed (FICFB) was selected. It has been demonstrated at industrial scale and data is readily available for model validation. An Aspen Plus model was developed to simulate the FICFB gasifier. The model is based on Gibbs free energy minimisation and the restricted equilibrium method was used to calibrate it. The model has been validated and …

A Simulation-Based Decision Support System To Model Complex Demand Driven Heathcare Facilities, Amr Arisha, Michael Thorwarth

Conference papers

Simulating healthcare processes is a sophisticated endeavor. Treatment processes and patient arrival patterns differ significantly in their statistical attributes and implicate a high degree of variability. In addition, there are several types of interconnected processes of medical staff involved that accompany a patient’s journey through the healthcare facility. Replicating this behavior with process flow models in a discrete event simulation model is highly complex and therefore difficult to create while maintaining a high degree of precision. A framework is thus introduced which delivers an algorithm that allows to implement Multiple Participant Pathway Modeling (MPPM) under the consideration of Flexible Resource …

The Implementation Of A Visco-Hyperelastic Numerical Material Model For Simulating The Behaviour Of Polymer Foam Materials, Conor Briody, Barry Duignan, Stephen Jerrams, John Tiernan

Articles

Polyurethane foam has been in use for some time in wheelchair seating systems as it offers good pressure relieving capabilities in most cases. However, little characterisation work has gone into seating foam materials by comparison with conventional elastomeric materials. Accurate material models could allow better prediction of foam in-service behaviour, which could potentially improve seating design practises. The objective of this work was to develop an approach for the validation of hyperelastic and viscoelastic material model parameters used to simulate polyurethane foam behaviour. Material parameters were identified from relevant test procedures and implemented in a Finite Element simulation of an …

Testing, Modelling And Validation Of Numerical Model Capable Of Predicting Stress Fields Throughout Polyurethane Foam, Conor Briody, Barry Duignan, Stephen Jerrams

Conference Papers

Wheelchair seating systems are specialised for a number of reasons as users can have impaired mobility, which increases the possibility of pressure build up. These areas of high pressure frequently occur in the trunk region under the bony prominences known as the Ischial Tuberosities (IT), pressure ulcers may occur consequently. Polyurethane foam has been in use for some time in wheelchair seating systems as it exhibits good pressure relieving capabilities in most cases. However, little quantitative research has gone into foamed polymers, in comparison with conventional elastomeric materials. This lack of knowledge can ultimately lead to more time being spent …

Characterisation, Modelling And Simulation Of Flexible Polyurethane Foam, Conor Briody, Barry Duignan, Stephen Jerrams

Conference Papers

Flexible polyurethane foam is an open-celled polymeric material that exhibits strain rate and temperature effects. It has found various applications in areas including the packaging, medical, sports, aerospace and aeronautical industries. Polyurethane foam is ubiquitous in seating applications and finds particular use in specialised wheelchair seating where customised seating solutions are required which can provide proper comfort and support without the risk of developing pressure ulcers. Proper seating design is critical for users if this problem is to be avoided, but a lack of quantitative knowledge of this material’s behaviour has limited its effectiveness. The objectives of the work presented …

Engineering Design And Development, David Kennedy

Conference Papers

Combining Industrial and Functional Design methodologies for the development of new products and systems requires a broad understanding of human behaviour and industrial activities. The requirements of international standards, protection of the environment and the ability to make a profit on sales requires a sound attitude and approach to succeed, especially in current economic conditions. This highlights the importance of good business and management strategy that must be dynamic to meet the changing needs of the market. Competitiveness depends largely upon advances in the fields of design and Innovation, cutting edge research and new advances over a broad range of …

Computer Simulation Of A Biomass Gasification-Solid Oxide Fuel Cell Power System Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

The operation and performance of a solid oxide fuel cell (SOFC) stack on biomass syn-gas from a biomass gasification combined heat and power (CHP) plant is investigated. The objective of this work is to develop a model of a biomass-SOFC system capable of predicting performance under diverse operating conditions. The tubular SOFC technology is selected. The SOFC stack model, equilibrium type based on Gibbs free energy minimisation, is developed using Aspen Plus. The model performs heat and mass balances and considers ohmic, activation and concentration losses for the voltage calculation. The model is validated against data available in the literature …

Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syngas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

A tubular solid oxide fuel cell (SOFC) stack was modelled and its operation on biomass syn-gas was investigated. The objective of this work was to develop a computer simulation model of a biomass gasification-SOFC (BG-SOFC) system capable of predicting performance under various operating conditions and using diverse fuels. The stack was modelled using Aspen Plus and considers ohmic, activation and concentration losses. It was validated against published data for operation on natural gas. Operating parameters such as fuel and air utilisation factor U_f and U_a, current density j and steam to carbon ratio STCR were varied and …

Simulation Procedure For The Co-Optimization Of Photovoltaic Water Pumping Systems., Brian Norton

Articles

Abstract: Photovoltaic (PV)-powered centrifugal water pumping systems have been modelled based on field experience and analysis of long-term measured performance of several installed PV-powered water pumping systems. This paper presents detailed modelling of a PV array, an inverter, a three-phase induction motor, a centrifugal pump, a well, a storage tank, an overflow controller, and an integrated reverse osmosis desalination unit. The component models were validated using both laboratory measurements and long-term monitored data. All system components have been modelled separately, and the system was modelled in TRNSYS. The models are capable of simulating grid-connected, diesel-powered, and PV-powered water pumping systems, …

Preliminary Modelling Results For An Otto Cycle/Stirling Cycle Hybrid-Engine-Based Power Generation System, Barry Cullen, Jim Mcgovern, Michel Feidt, Stoian Petrescu

Conference Papers

This paper presents preliminary data and results for a system mathematical model for a proposed Otto Cycle / Stirling Cycle hybrid-engine-based power generation system. The system is a combined cycle system with the Stirling cycle machine operating as a bottoming cycle on the Otto cycle exhaust. The application considered is that of a stationary power generation scenario wherein the Stirling cycle engine operates as a waste heat recovery device on the exhaust stream of the Otto cycle engine. This paper is primarily concerned with the development of a model for a suitable Stirling cycle engine capable of running on the …

Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syn-Gas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

A tubular solid oxide fuel cell (SOFC) stack is modelled and its operation on biomass syn-gas is investigated. The objective of this work is to develop a computer simulation model of a biomass gasification-SOFC (BG-SOFC) system capable of predicting performance under various operating conditions and using diverse fuels. The stack is modelled using Aspen Plus and considers ohmic, activation and concentration losses. It is validated against published data for operation on natural gas. Operating parameters such as fuel and air utilisation factor (U_f and U_a), current density (j) and steam to carbon ratio ( …

The Effect Of Air Preheating In A Biomass Cfb Gasifier Using Aspen Plus Simulation, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

In the context of climate change, increasing efficiency and energy security, biomass gasification is likely to play an important role in energy production. Atmospheric circulating fluidised bed (CFB) technology was selected for the current study. The primary objective of this research is to develop a computer simulation model of a CFB biomass gasifier that can accurately predict gasifier performance under various operating conditions. An original model was developed using ASPEN Plus (Advanced System for Process ENgineering Plus). The model is based on Gibbs free energy minimisation. The restricted equilibrium method was used to calibrate the model against experimental data. This …

Water Quality Modelling In Dublin From Bray To Balbriggan Gdsds/75407/130, Aodh Dowley, Zeinab Bedri

Reports

No abstract provided.

Transfer Function Modelling: A Student-Centred Learning Approach, Aidan O'Dwyer

Conference papers

Traditionally, the modelling of real systems in engineering, using transfer functions, has been done in a mathematically intense manner. However, non-traditional learners such as mature students, part-time students and students without a conventional second-level educational background may not have strong mathematical foundations; in addition, all students increasingly expect technical work which is practical and which motivates independent learning. This paper reports on, reflects on and evaluates an innovative experiment developed by the author to estimate a transfer function model of a person’s eye-brain-hand motor response. In the experiment, carried out using a PC with data acquisition capability, the person is …

A Case Study In Modeling And Process Control: The Control Of A Pilot Scale Heating And Ventilation System, Robin Mooney, Aidan O'Dwyer

Conference papers

This paper details the control of a pilot scale laboratory heating and ventilation system. The system is represented in 2x2 multi-input, multi-output (MIMO) form. A process reaction curve identification technique was used to model (in first order lag plus delay - FOLPD - form) the flow process and temperature process portions of the system, over a range of operating conditions. Tests revealed that both processes were continuously non-linear. A gain scheduler with static decoupling was designed, using look-up tables, to continuously interpolate for the most suitable proportional-integral (PI) or proportional-integral-derivative (PID) controller settings and decoupler gains. The contribution of this …

Modelling And Control Of A Suspension System For Vehicle Applications, Padraig Dowds, Aidan O'Dwyer

Conference papers

This paper discusses the modelling of passive and active suspension systems in a car, and the subsequent design of appropriate feedback controllers for the active suspension system. The models will be investigated using a quarter car model and a full car model approach.