Engineering Commons^™

Development Of A New Kinetic Model For Methanol To Propylene Process On Mn/H-Zsm-5 Catalyst, Naser Hady, Ali Niaei, Reza Nabavi, Ali Farzi, Masoud Navaei Shirazi

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The activity of the H-ZSM-5 was modified by the addition of Ca, Mn, Cr, Fe, Ni, Ag, Ce and P. The highest selectivity of propylene was obtained over the Mn/H-ZSM-5 catalyst. The Mn modified catalyst was selected as the optimal catalyst and the kinetic study was carried out on it. All of the experiments were carried out in an isothermal fixed bed and plug flow reactor with the mixture of methanol and water. The temperature range was 400–550 °C and the weight hourly space velocities (WHSV) of methanol were: 2.51, 5.42, and 8.17 h–1. A reaction mechanism based on the …

Optimization And Statistical Modeling Of Catalytic Oxidation Of 2-Propanol Over Cumn_Mco_(2-M)O4 Nano Spinels By Unreplicated Split Design Methodology, Seyed Ali Hosseini, Aligholi Niaei, Dariush Salari, Raimundo K. Vieira, Shamil Sadigov, Reza Nabavi

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Optimization of 2-propanol oxidation over CuMn_mCo_(2-m)O4 nanospinels was carried out by a split design method. 15-term model was proposed to fit the experimental data. The model revealed that both whole plot and subplot variables have significant effects on conversion of 2-propanol. The model predicted the interaction of subplot and whole plot variables as well as their importance. The maximum conversion of 2-propanol was observed over CuMn2O4 (x1 = 0.33, x2 = 0, x3 = 0.67) at calcination and reaction temperatures of 800 8C (z1 = 1) and 300 8C (z2 = 1), respectively. The predicted response and the response obtained …

Nanocrystalline Amn2o4 (A = Co, Ni, Cu) Spinels For Remediation Of Volatile Organic Compounds—Synthesis, Characterization And Catalytic Performance, Ali Hosseini, Ali Niaei, Darioush Salari, Reza Nabavi

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Nanocrystalline AMn2O4 (A = Co, Ni, Cu) manganite spinels were prepared by using the sol–gel auto combustion method under the same

synthesis conditions and their physico-chemical properties were studied by XRD, UV–vis DRS, SEM, BET and FTIR. Besides, the reducibility of

oxides was studied by temperature-programmed reduction (TPR). The relationship between the properties and activity of spinels in oxidation of 2-

propanol and toluene was investigated. Among all, nickel manganite exhibited the most promising activity, in which the completed conversion of 2-

propanol and toluene occurred at 250 and 350 8C, respectively. Higher activity of nickel manganite oxide was explained …

Design Optimization Of An Lpg Thermal Cracker For Multiple Objectives, Reza Nabavi, G.P Rangaiah, A Niaei, D Salari

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Ethylene and propylene, building blocks of the petrochemical industries, are mostly produced by steam cracking of hydrocarbons. In our recent work (Nabavi, Rangaiah, Niaei and Salari, Multiobjective Optimization of an Industrial LPG Thermal Cracker using a First Principles Model, Ind. Eng. Chem. Res. 2009, 48, 9523-9533), operation of an industrial liquefied petroleum gas (LPG) cracker was optimized for several sets of two and three objectives. In this work, optimization of an LPG cracker design is investigated for multiple objectives. The objectives considered are maximization of annual ethylene and propylene production, selectivity and run length, and minimization of severity and total …

Multiobjective Optimization Of An Industrial Lpg Thermal Cracker Using A First Principles Model, Reza Nabavi, G.P Rangaiah, Ali Niaei, Dariush Salari

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Thermal cracking of hydrocarbons in the presence of steam is the most important process for the production of ethylene and propylene, which are the raw materials for many petrochemicals. In this work, multiobjective optimization (MOO) of an industrial LPG (liquefied petroleum gas containing mainly propane and butane) thermal cracker is studied using the elitist nondominated sorting genetic algorithm adapted with the jumping gene operator, NSGA-II-aJG. A first principles model based on free radical mechanism for LPG thermal cracking is employed for optimization. Several bi- and triobjective optimization problems are solved; these problems involved maximization of annual ethylene/propylene production, selectivity and …

Investigation Of Coke Deposition And Coke Inhibition By Organosulfur Compounds In The Pyrolysis Of Naphtha In The Jet Stirred Reactor System, D Salari, A Niaei, J Towfighi, P Panahi, Reza Nabavi

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No abstract provided.