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Faculty of Engineering University of Malaya

Adsorption

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Comparative Kinetic Study Of Functionalized Carbon Nanotubes And Magnetic Biochar For Removal Of Cd2+ Ions From Wastewater Mar 2015

Comparative Kinetic Study Of Functionalized Carbon Nanotubes And Magnetic Biochar For Removal Of Cd2+ Ions From Wastewater

Faculty of Engineering University of Malaya

We did a comparative study between functionalized multiwall carbon nanotube (FMWCNTs), and magnetic biochar was carried out to determine the most efficient adsorbent to be employed in the Cd2+ ion removal. We optimized parameters such as agitation speed, contact time, pH and adsorbent dosage using design expert vrsion 6.08. The statistical analysis reveals that optimized condition for highest removal of Cd2+ are at pH 5.0, with dosage 1.0 g, agitation speed and contact time of 100 rpm and 90 minutes, respectively. For the initial concentration of 10mg/l, the removal efficiency of Cd2+ using FMWCNTs was 90% and and 82% of …


Effect Of Microwave Frequency On Dielectric Properties Of Oil Palm Shell (Ops) And Ops Char Synthesized By Microwave Pyrolysis Of Ops Mar 2015

Effect Of Microwave Frequency On Dielectric Properties Of Oil Palm Shell (Ops) And Ops Char Synthesized By Microwave Pyrolysis Of Ops

Faculty of Engineering University of Malaya

Microwave heating is considered to be a potential, efficient and fast method for thermal treatment of biomass. Therefore, elemental understanding of dielectric properties of biomass is necessary before irradiating it with microwave radiations. Dielectric properties along with penetration depth, relaxation time and static permittivity of oil palm shell COPS) and OPS char were investigated in the frequency ranging between 0.5 and 20 GHz at room temperature. At low frequencies, dielectric constant of UPS was higher than that of UPS char while at higher frequencies, vice versa is observed. Penetration depth for UPS char was higher than that of UPS at …


Lead Sorption By Carbon Nanofibers Grown On Powdered Activated Carbon - Kinetics And Equilibrium Feb 2015

Lead Sorption By Carbon Nanofibers Grown On Powdered Activated Carbon - Kinetics And Equilibrium

Faculty of Engineering University of Malaya

Carbon nanofibers (CNFs) were synthesized by using a safe and less hazardous method, compared to using floating catalysts in chemical vapor deposition (CVD) process. This process used C2H2 as carbon source and oil palm kernel shell-based powdered activated carbon (PAC) as cheap solid substrate. Use of nickel (Ni2+) impregnated PAC as fixed substrate for the synthesis of CNF is one of the novelties of the research work accomplished by the authors. The PAC CNFs porous nanocomposite product was used for the sorption of lead ions (Pb2+) from synthetic aqueous solution. Kinetics of Pb2+ adsorption and isotherms were investigated by varying …


Utilization Of Palm Oil Sludge Through Pyrolysis For Bio-Oil And Bio-Char Production Feb 2015

Utilization Of Palm Oil Sludge Through Pyrolysis For Bio-Oil And Bio-Char Production

Faculty of Engineering University of Malaya

In this study, pyrolysis technique was utilized for converting palm oil sludge to value added materials: bio-oil (liquid fuel) and bio-char (soil amendment). The bio-oil yield obtained was 27.4 +/- 1.7 wt.% having a heating value of 22.2 +/- 3.7 MJ/kg and a negligible ash content of 0.23 +/- 0.01 wt.%. The pH of bio-oil was in alkaline region. The bio-char yielded 49.9 +/- 0.3 wt.%, which was further investigated for sorption efficiency by adsorbing metal (Cd2+ ions) from water. The removal efficiency of Cd2+ was 89.4 +/- 2%, which was almost similar to the removal efficiency of a commercial …