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Full-Text Articles in Engineering
Enhanced Sonocatalytic Treatment Of Ibuprofen By Mechanical Mixing And Reusable Magnetic Core Titanium Dioxide
Faculty of Engineering University of Malaya
As a reusable sonocatalyst, magnetically separable titanium dioxide (MST) was synthesized by a sol-gel method and was evaluated in the removal of ibuprofen (IBP). MST was carefully characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), N-2 gas isotherms, band-gap energy, magnetization, zeta potential, and particle size distribution. The kinetics of IBP removal by sonolysis or MST-assisted sonocatalysis was systematically evaluated with various operational parameters such as pH, temperature, ultrasound (US) frequency, and mechanical mixing intensity. For the first time, authors found that mechanical mixing had an opposite effect on the oxidation rate constants of IBP removal by sonolysis …
Estimation Of The Effect Of Catalyst Physical Characteristics On Fenton-Like Oxidation Efficiency Using Adaptive Neuro-Fuzzy Computing Technique
Faculty of Engineering University of Malaya
Catalyst size, which determines surface area, is one of the major factors in catalytic performance. In this study, response surface methodology (RSM) and an adaptive neuro-fuzzy inference system (ANFIS) were applied to quantify the effects of physical characteristics of magnetite on Fenton-like oxidation efficiency of methylene blue. For this purpose, two magnetite samples (M and N) were used and characterized by XRD, BET surface area, particle size analyzer and FE-SEM. Central composite design (CCD) was applied to design the experiments, develop regression models, optimize and evaluate the individual and interactive effects of five independent variables: H2O2 and catalyst concentrations, pH, …