Engineering Commons^™

Exploring A Platinum Nanocatalytic Microcombustion-Thermoelectric Coupled Device, Dylan Moore Mcnally

Theses and Dissertations

This work aimed to create a first-generation power device for eventual application to portable electronics. A platinum nanoparticle catalytic substrate was employed in a microcombustion-thermoelectric coupled (MTC) device for the purpose of chemical-to-electrical energy conversion. Multiple microcombustion reactors were designed, fabricated, and investigated. Most importantly, the reactor configuration was designed to accommodate thermoelectric generators (TEGs) for power production. Temperature studies with catalytic combustion of methanol-air fuel mixtures were used to evaluate the thermal power generation performance of each reactor. The final reactor design enabled ignition at room temperature with the ability to achieve repeat catalytic cycles upon subsequent exposure to …

Evaluating The Effectiveness Of The Pedestrian Safety Intervention Program: Behavioral And Observational Approach, Deep Patel

Theses and Dissertations

Pedestrians are considered as the most vulnerable road users. On a nationwide scale, according to the National Highway Traffic Safety Administration, there were 6,075 pedestrian fatalities and more than 85,000 pedestrian injuries as a result of traffic crashes in 2017. This study provides national and state pedestrian fatality statistics, a systematic literature review of pedestrian injury severity, observational (video-based) & behavioral (survey-based) evaluation of the Street-Smart NJ pedestrian safety intervention campaign. Street-Smart NJ is a public education, awareness, and behavioral change campaign program that aims to improve pedestrian safety by increasing awareness of pedestrian safety risks and improving compliance with …

Evaluation Of Impact Of Fiber Type And Dosage Rate On Volumetrics And Laboratory Performance Of Asphalt Mixtures, Ahmad G. M. Alfalah

Theses and Dissertations

The purpose of this study is to evaluate the impact of fiber types, binder content, and dosage rates on the volumetric properties and laboratory performance of asphalt mixtures. One asphalt mixture (control) and four fiber types (Fiberglass, Basalt, Carbon, and Polyolefin/Aramid) were used to evaluate the impact of fiber types and dosage rates. Two mixing procedures for introducing fibers into asphalt mixtures were also evaluated: dry and proportional dispersion methods. To evaluate the impact of fiber types, 0.16% by total mix weight was used. Rutting, cracking, and durability performance tests were evaluated. Furthermore, using 0.15% and 0.3% fiber dosage rates, …

Epoxy-Functional Thermoplastic Copolymers And Their Incorporation Into Thermosetting Resins, Kayla Rose Sweet

Theses and Dissertations

While polymers have secured a place in the consumer, industrial, and military markets over the last seventy years, the next generation of polymers must become more renewable, more adaptive, and higher performing to bridge industrial needs and environmental gaps. To this end, unique network configurations of copolymers and interpenetrating polymer networks (IPNs) have been employed to combine features of two or more polymers into a single material that surpasses the sum of its parts. The customization of polymer networks can be made possible via dual-functional monomers, molecules characterized by two different reactive substituents that allow for versatile methods of polymerization. …

Synthesis And Characterization Of Thermosetting Epoxy Resins From Lignin-Inspired Phenolics, Kelli Marie Hambleton

Theses and Dissertations

The need for renewable polymers able to replace their petrochemical counterparts continues to grow as sustainability concerns constantly rise. Bisguaiacol, a bio-based alternative to bisphenol-A, has been synthesized using vanillyl alcohol and guaiacol via an electrophilic aromatic condensation. Purification provides both bisguaiacol and an oligomeric coproduct with a consistent number average molecular weight and dispersity of about 650 Da and 1.00, respectively, across multiple reaction volume scales. This coproduct has been well characterized as a low molecular weight novolac averaging 5 hydroxyls per molecule and was transformed into an epoxy resin suitable for use in thermosetting resin development. By utilizing …

Bioprinted In Vitro Model Of Human Glioblastoma, Rachel Lauren Schwartz

Theses and Dissertations

Glioblastoma multiform (GBM) is one of the most aggressive forms of primary brain tumors. GBM is fast progressing and resistant to treatment, resulting in a low survival rate. Conventional 2-dimensional tissue culture models cannot fully replicate the complexities of cancer lesions that contain multiple cell types and structures (e.g. vessels composed of endothelial cells, cancer cells, normal cells, etc.) as well as an intricate scaffold of proteins comprising the extracellular matrix (ECM). In addition, animal models cannot translate into the clinical disease in patients. Thus, this study has developed a bioprintable organ-on-a-chip (OOAC) model that mimics the important ECM factors …

Artificial Intelligence For Helicopter Safety: Head Pose Estimation In The Cockpit, Eric William Feuerstein

Theses and Dissertations

The recent impact of deep learning algorithms and their major breakthroughs on various aspects of our lives has led to the idea to investigate the application of these algorithms in different problem spaces. One of the novel areas of investigation is the aviation and air traffic control domain; as it offers a prime opportunity to enhance safety within the aviation community. Of particular importance to this community is improving the safety of rotorcraft operations, as this segment of the aviation industry is subject to a higher fatal accident rate than other segments of the industry. The improvement of safety for …

Laboratory Evaluation Of The Impact Of Additives On Asphalt Binders Used In Cold Regions, Neirouz Bouhrira

Theses and Dissertations

The objective of this research study is to evaluate the effect of additives (polymers, nanomaterials, and softening agents) on rutting, cracking, and fatigue performance of asphalt binders commonly used in cold regions (PG 52-34 and PG 64E-40). In this study, the first phase consisted of using polymers (Styrene-Butadiene-Styrene, Ground-Tire-Rubber) and nanomaterials (TiO2 and SiO2) to modify two asphalt binders used in cold regions (PG52-34 and PG64E-40). The second phase of the study consisted of adding a combination of softening agents (Corn oil or Sylvaroad) with polymers (SBR, Epoxy, and SBS) to PG52-34 asphalt binder. The performance evaluation was conducted using …

Remediation Of Desiccation Cracking In Clayey Soils Through Bio-Cementation And Bottom Ash, Mark Vail

Theses and Dissertations

Desiccation cracking considerably impairs the hydraulic and mechanical properties of clayey soils and is critical to the long-term performance of infrastructure foundations and earth structures. Classical crack remediation methods are associated with high labor and maintenance costs or the usage of environment-unfriendly chemicals. Recycling waste materials and developing bio-mediated techniques have emerged as green and sustainable soil stabilization solutions. The objective of this study is to investigate the feasibility of soil crack remediation through the usage of microbial-induced calcite precipitation (MICP) and bottom ash admixtures. We carry out monotonic drying and cyclic drying-wetting tests to characterize the effects of bottom …

Designing Silk Protein-Based Composite Materials With Tunable Heat Transfer And Magnetic Properties, Ye Xue

Theses and Dissertations

Renewable and biocompatible silk protein materials with desired physical properties show promising applications in biomedical field. In this work, a set of protein-based composites with desired thermal and magnetic properties, enhanced by the appropriate distribution of nanofillers in the protein matrix in both 2D-film and 1D-fiber forms was investigated. Results indicate that secondary structures of silk protein materials regenerated by a formic acid-calcium chloride method are different from those of their respective natural silk fibers. Intramolecular beta-sheet structures were found to dominate these silk films, causing these regenerated samples to be water-insoluble but more flexible than traditional silk films with …

Examining Global Perspectives Of Engineering Students: Determining Educational Impact, Brian R. Moore

Theses and Dissertations

Globalization is causing higher education to adapt their approaches to student learning, especially those in the engineering disciplines as the nature and impact of their work becomes more cross-cultural and diverse. The efforts of programmatic change have led universities to emphasize new or different student experiences and educational practices to better prepare graduates for this societal change. Given this trend, research on which educational practices have the most impact on preparing engineering graduates to enter a global workforce is needed. Research has shown that international experiences like study abroad have a positive impact on students' global perspectives, especially when they …

Polyimide/Silicon Dioxide Nanocomposites As Dielectrics For Helium-Cooled High-Temperature Superconducting Cables, Harrison Michael Hones

Theses and Dissertations

In this thesis, polyimide (PI) and silicon dioxide (SiO2) were combined in the form of a nanocomposite for use as a dielectric on helium-cooled high-temperature superconducting (HTS) cables. Further, a cryogenic chamber was designed with the intent of cooling samples to 40 K for dielectric and thermal contraction testing. Composites were created through an in situ process which resulted in nanoparticle formation within the host matrix. Samples were tested for dielectric strength at room temperature (300 K) as well as cryogenic temperature (92 K) using liquid nitrogen as the coolant. Composite samples tested at 300 K averaged a dielectric strength …

Bijels Made By Solvent Transfer Induced Phase Separation: Formation Principles And Transport, Stephen Boakye-Ansah

Theses and Dissertations

Bijels are made of non-equilibrium particle-stabilized emulsions with a bicontinuous arrangement of the constituent fluid phases. They spontaneously form through arrested spinodal decomposition in mixtures of partially miscible liquids and neutrally wetting colloidal particles. Soon after their discovery over 10 years ago, Prof. Mike Cates, Lucasian Professor of Mathematics, predicted their future use as continuously operated cross-flow reactors for chemical reactions between immiscible reactants.

Towards this goal, work in this thesis focuses on designing bijels via Solvent Transfer Induced Phase Separation (STrIPS) for microfluidic transport applications. Structure-function relationships of STrIPS bijels stabilized by silane functionalized nanoparticles are developed. In-situ surfactant …

Evaluating Cracking Performance Of Polymer Enhanced And Fiber Reinforced Microsurface Mixtures Using Asphalt Laboratory Testing, George Joseph Shackil

Theses and Dissertations

This study presents a method to improve and evaluate the cracking resistance of microsurfacing mixtures using common asphalt laboratory testing. A preliminary optimal timing study and a study to evaluate improvements to cracking performance were conducted. The control mixture was based on NJDOT standard mix design specifications. Three mixtures were tested in this study: a fiber reinforced mixture using one-quarter inch glass fibers, an emulsion with increased SBR (polymer) contents, and a mixture using the one-quarter inch glass fibers combined with the increased polymer contents. Three laboratory tests were used to evaluate three different cracking resistance parameters: crack initiation (Semi-Circular …

Study And Characterization Of Conductive Elastomers For Biomedical Applications, Hadis Gharacheh

Theses and Dissertations

Health issues have always been one of humankind's biggest challenges. Over the last century, there has been significant and monumental progress in health and biomedical science, with the end goal of alleviating and eliminating illnesses and ailments. For developing biomedical devices, polymers and elastomers group among other types of biomaterials have been highlighted to be used due to high flexibility, stability, biocompatibility, and mechanical and rheological characteristics. In this work, the characterization of acrylated poly glycerol_sebacate (PGSA) polymer conjugated with bio ionic liquid (BIL) was investigated. Results showed high biocompatibility, high printability with tunable mechanical, adhesive, and conductivity properties. For …

Improving The Piezoelectric Properties Of Flexible Polymer-Nanoparticle Energy Harvesters, Muhammet Emin Cavusoglu

Theses and Dissertations

In this research, one of the widely used polymers, poly(vinylidene fluoride)(PVDF), was used to develop thin-film polymer energy harvesters. Dimethylformamide (DMF) and methyl ethyl ketone (MEK) were used to dissolve the PVDF powder. Four different (0%, 3%, 5%, and 7%) ZnO nanoparticle (NP) concentrations were used to enhance the electrical output of the thin-film energy harvesters. A sonication bath and additional MEK were used in dispersing the ZnO NPs to obtained uniform PVDF/ZnO NP solution. The electrode poling technique was used for dipole alignment to improve the electrical performance of the devices. The fabricated samples were tested using the tensile …

Toward Precision Medicine With Nanopore Technology, Trang Andrea Vu

Theses and Dissertations

Currently, when patients are diagnosed with cancer, they often receive a treatment based on the type and stage of the tumor. However, different patients may respond to the same treatment differently, due to the variation in their genomic alteration profile. Thus, it is essential to understand the effect of genomic alterations on cancer drug efficiency and engineer devices to monitor these changes for therapeutic response prediction. Nanopore-based detection technology features devices containing a nanometer-scale pore embedded in a thin membrane that can be utilized for DNA sequencing, biosensing, and detection of biological or chemical modifications on single molecules. Overall, this …

Towards Machine Self-Awareness - A Bayesian Framework For Uncertainty Propagation In Deep Neural Networks, Dimah Dera

Theses and Dissertations

Deep neural networks (DNNs) have surpassed human-level accuracy in various fields, including object recognition and classification. However, DNNs being inherently deterministic, are unable to evaluate their confidence in the decisions. Bayesian inference provides a principled approach to reason about model confidence or uncertainty by estimating the posterior distribution of the unknown parameters. The challenge in DNNs is the multi-layer stages of non-linearities, which makes propagation of high-dimensional distributions mathematically intractable. This dissertation establishes the theoretical and algorithmic foundations of uncertainty or belief propagation by developing new deep learning models that can quantify their uncertainty in the decision and self-assess their …

Synthesis And Evaluation Of Catalytic Application Of Porous Resin, Mahboubeh Nabavinia

Theses and Dissertations

The abilities to tailor catalytic functional groups and chemical characteristics onto a robust polymer structure make mesoporous phenolic resins great candidates for catalytic support applications. The use of a template synthesis method for configuring a catalytic structure is neither commercially nor environmentally friendly. In this Ph.D. thesis, new one-pot template-free methods for synthesizing mesoporous metal-doped phenol-formaldehyderesin were developed. The methods facilitate scaling for industrial catalytic applications in pharmaceutical, environmental, and medical applications. Heterogeneous palladium centered catalytic mesoporous structures were synthesized by a single-stage template-free method. BET adsorption measurements, SEM, EDX, XPS, and TEM were used to study the surface area, …

Enhancing Facility Management For Existing Facilities With Building Information Modeling, Ryan Loeh

Theses and Dissertations

Building information modeling (BIM) refers to the process of creating a comprehensive three-dimensional (3D) model that allows for a seamless transition from design and construction to operation & maintenance during a building's lifecycle. While a majority of past research for building information modelling was focused on design and construction, research has shifted to operation, maintenance and renovation. This study investigates the feasibility of integrating BIM (Autodesk Revit) and facility management (BUILDER SMS). BUILDER SMS is currently used at the sponsor's facilities to encourage proactive maintenance and provide updated condition assessments. While both datasets have their own benefits, this study investigates …

Hybrid Monomers & Resins For High-Performance Thermosetting Polymers, Thermoplastics, & Additive Manufacturing, Alexander William Bassett

Theses and Dissertations

Vinyl ester and epoxy resins are used to produce thermosetting polymeric materials for a variety of commercial and military applications due to their relatively high moduli (2-3 GPa at 25 deg C), glass transition temperatures (Tgs) (greater than or equal to 120 deg C), and adequate fracture toughness (G1C approx. 200-250 J m-2). Most commercially available vinyl ester and epoxy resins are typically cured via traditional manufacturing techniques such as resin transfer molding and thermal curing. However, additive manufacturing (AM) has gained significant traction as a favorable manufacturing technique over traditional methods due to the ability to create customizable parts …

Low-Cost Solid State Nanopore Biosensing Technology Towards Early Disease Detection, Julian Bello

Theses and Dissertations

Solid-state nanopore based biosensors are cost effective, high-throughput engines for single molecule detection of biomolecules, which is useful for detecting epigenetic modifications on DNA; one of these being the potentially cancerous hypo, or hypermethylation of CpG islands. Despite its immense potential in the realm of disease diagnostics, nanopore detection as it stands faces various limitations that inhibit it from widespread commercial use. These include the complex method of solid-state nanopore fabrication, fast DNA translocations through the pore causing poor resolution, and poor signal to noise ratio. The following work aims to improve the efficacy of the solid-state nanopore biosensing platform …

Fabrication Of Vascularized Scaffolds For The Treatment Of Spinal Cord Injury, Paul P. Partyka

Theses and Dissertations

The overall goal of the research presented here is to evaluate the efficacy of transplanting scaffolds containing central nervous system vasculature to repair spinal cord injury. There are three major phases of this effort: development of a three-dimensional model of central nervous system vasculature, transplantation of a pre-vascularized scaffold and optimization of the biomaterial used to deliver vasculature to the injured spinal cord. This research has produced the first ever compliant, three-dimensional (3D) blood-brain barrier (BBB) vessel. In order to create vascularized scaffolds appropriate for transplantation into a rat model of spinal cord injury, techniques to fabricate and spatially pattern …

Bioadhesive Hydrogel Composite Cell Carrier For The Repair Of The Degenerated Intervertebral Disc, Thomas Richard Christiani

Theses and Dissertations

Lower back pain (LBP) affects the worldwide population and can be attributed to the degeneration of the intervertebral disc (IVD). The IVD is composed of a central nucleus pulposus (NP), a peripheral annulus fibrosus (AF), and adjacent cartilage endplates (CEPs). IVD degeneration is characterized by proteoglycan loss, tissue dehydration, and decreased hydrostatic pressure. In this work, the use of an injectable bioadhesive hydrogel composite for replacement of the degenerated NP was investigated.

Results indicate that the composite exhibits similar mechanical properties to the NP, adheres to AF tissue, and supports encapsulated mesenchymal stem cell (MSC) differentiation toward an NP-like phenotype …