Engineering Commons^™

Semiconductor Nanomaterial Development For Photovoltaic And Thermoelectric Applications, Liangliang Chen

Open Access Dissertations

Today's world is frequently going through fossil energy shortage and environmental consequences brought by the over-emission of greenhouse gas from burning fossil fuels. Therefore, it is urgent now more than ever to discover or develop clean and sustainable power generation approaches. Among various approaches, photovoltaics and thermoelectrics have been more and more attentive both in academia and industry. Photovoltaic power generators can significantly decrease carbon dioxide emission by directly converting sunlight into electricity, and thermoelectric power generators can increase energy use efficiency by recycling waste heat into electricity. This research seeks to gain a better understanding of the mechanism that …

Atomic Level Study Of Water-Gas Shift Catalysts Via Transmission Electron Microscopy And X-Ray Spectroscopy, Mehmed Cem Akatay

Open Access Dissertations

Water-gas shift (WGS), CO + H₂ O [Special characters omitted.] CO₂ + H₂ (ΔH° = -41 kJ mol ^-1 ), is an industrially important reaction for the production of high purity hydrogen. Commercial Cu/ZnO/Al₂ O₃ catalystsare employed to accelerate this reaction, yet these catalysts suffer from certain drawbacks, including costly regeneration processes and sulfur poisoning. Extensive research is focused on developing new catalysts to replace the current technology. Supported noble metals stand out as promising candidates, yet comprise intricate nanostructures complicating the understanding of their working mechanism.

In this study, the structure of the supported …

Spectroscopic And Kinetic Study Of Copper-Exchanged Zeolites For The Selective Catalytic Reduction Of Nox With Ammonia, Shane Adam Bates

Open Access Dissertations

The recent application of metal-exchanged, small-pore zeolites for use in the selective catalytic reduction (SCR) of NO_x with ammonia NH₃ for automotive deNO_x applications has been a great stride in achieving emission standard goals. Copper-exchanged SSZ-13 (Cu-SSZ-13), the small-pore zeolite in this study, has been shown to be very hydrothermally stable and active under conditions presented in the exhaust of the lean-burn diesel engine. In this work, detailed studies were performed to identify many aspects of the active site(s) in Cu-SSZ-13 in order to learn about the standard SCR mechanism.

A series of seven Cu-SSZ-13 samples were …

Effects Of Hearing Aid Amplification On Robust Neural Coding Of Speech, Jonathan Daniel Boley

Open Access Dissertations

Hearing aids are able to restore some hearing abilities for people with auditory impairments, but background noise remains a significant problem. Unfortunately, we know very little about how speech is encoded in the auditory system, particularly in impaired systems with prosthetic amplifiers. There is growing evidence that relative timing in the neural signals (known as spatiotemporal coding) is important for speech perception, but there is little research that relates spatiotemporal coding and hearing aid amplification.

This research uses a combination of computational modeling and physiological experiments to characterize how hearing aids affect vowel coding in noise at the level of …

Transmit Signal Design For Mimo Radar And Massive Mimo Channel Estimation, Andrew Jason Duly

Open Access Dissertations

The widespread availability of antenna arrays and the capability to independently control signal emissions from each antenna make transmit signal design increasingly important for radar and wireless communication systems. In the rst part of this work, we develop the framework for a MIMO radar transmit scheme which trades o waveform diversity for beampattern directivity. Time-division beamforming consists of a linear precoder that provides direct control of the transmit beampattern and is able to form multiple transmit beams in a single pulse. The MIMO receive ambiguity function, which incorporates the receiver structure, reveals a space and delay-Doppler separability that emphasizes the …

Response Of Plasma Facing Components In Tokamaks Due To Intense Energy Deposition Using Particle-In-Cell(Pic) Methods, Filippo Genco

Open Access Dissertations

Damage to plasma-facing components (PFC) due to various plasma instabilities is still a major concern for the successful development of fusion energy and represents a significant research obstacle in the community. It is of great importance to fully understand the behavior and lifetime expectancy of PFC under both low energy cycles during normal events and highly energetic events as disruptions, Edge-Localized Modes (ELM), Vertical Displacement Events (VDE), and Run-away electron (RE). The consequences of these high energetic dumps with energy fluxes ranging from 10 MJ/m2 up to 200 MJ/m2 applied in very short periods (0.1 to 5 ms) can be …

Manifold Learning Based Spectral Unmixing Of Hyperspectral Remote Sensing Data, Jun-Hwa Chi

Open Access Dissertations

Nonlinear mixing effects inherent in hyperspectral data are not properly represented in linear spectral unmixing models. Although direct nonlinear unmixing models provide capability to capture nonlinear phenomena, they are difficult to formulate and the results are not always generalizable. Manifold learning based spectral unmixing accommodates nonlinearity in the data in the feature extraction stage followed by linear mixing, thereby incorporating some characteristics of nonlinearity while retaining advantages of linear unmixing approaches. Since endmember selection is critical to successful spectral unmixing, it is important to select proper endmembers from the manifold space. However, excessive computational burden hinders development of manifolds for …

Research On Print Defect Visibility And Evaluation, Xiaochen Jing

Open Access Dissertations

Banding is a well-known artifact produced by printing systems. It usually appears as lines perpendicular to the process direction of the print. Therefore, banding is an important print quality issue which has been analyzed and assessed by many researchers. However, little literature has focused on the study of the masking effect of content for this kind of print quality issue. Compared with other image and print quality research, our work is focused on the print quality of typical documents printed on a digital commercial printing press. In this paper, we propose a Masking Mediated Print Defect Visibility Predictor (MMPDVP) to …

Human Cognitive Performance In Healthcare Information System Environment And Its Application On Nursing Tasks, Byung Cheol Lee

Open Access Dissertations

The US healthcare system has serious issues in care quality and patient safety. Patients often do not receive the care they need or the given care service cause harm. In addition, the significant amounts of medical and medication errors occur, and recurring adverse drug events due to damaging side effects from medications threaten patient safety. To solve these issues, healthcare information systems (HIS) have been recommended in various care processes. Though several studies have confirmed the benefits and usefulness of the systems (Cordero, Kuehn, Kumar, & Mekhjian, 2004; Kohn, Corrigan, & Donaldson, 2000; Sittig, Krall, Kaalaas-Sittig, & Ash, 2005; Weiner …

Image Reconstruction For X-Ray Computed Tomography In Security Screening Applications, Sherman Jordan Kisner

Open Access Dissertations

X-ray tomographic systems have increasingly widespread use in security screening applications. For example, most major airports now utilize X-ray CT

systems for efficient screening of baggage and cargo. While decades of research has benefited CT for medical diagnostics, a number of practical differences in the security application present a new set of challenges for the reconstruction problem. For example, the size and composition of the scan subjects, the throughput requirements, and the measure of image quality are

all factors that lead to a different set of design considerations. This thesis investigates the application of model-based iterative reconstruction (MBIR) methods for …

Adaptive Targeting: Engaging Farmers To Assess Perceptions And Improve Watershed Modeling, Optimization, And Adoption Of Agricultural Conservation Practices, Margaret Mccahon Kalcic

Open Access Dissertations

Targeting agricultural conservation practices to farmland that has the greatest impact on surface water quality has received wide support from scientists and watershed managers. The targeting approach has, however, been politically contentious as many believe farmers will oppose the approach on grounds such as privacy invasion and unfair distribution of government incentives. Targeting conservation practices using complex optimization models has become common in the scientific community, and yet targeted results are underutilized in practice because of difficulties such as knowledge transfer and absence of a political framework for their use. For targeting to be successful, it must be politically supported …

Mispronunciation Detection For Language Learning And Speech Recognition Adaptation, Zhenhao Ge

Open Access Dissertations

The areas of "mispronunciation detection" (or "accent detection" more specifically) within the speech recognition community are receiving increased attention now. Two application areas, namely language learning and speech recognition adaptation, are largely driving this research interest and are the focal points of this work.

There are a number of Computer Aided Language Learning (CALL) systems with Computer Aided Pronunciation Training (CAPT) techniques that have been developed. In this thesis, a new HMM-based text-dependent mispronunciation system is introduced using text Adaptive Frequency Cepstral Coefficients (AFCCs). It is shown that this system outperforms the conventional HMM method based on Mel Frequency Cepstral …

Wireless Sensors For Condition Monitoring Applications Operating In Complete Metallic Environment, Lokesh Anilkumar Gupta

Open Access Dissertations

Condition monitoring of machines is advantageous in predicting failure and estimating machine component lifetime. Continuous monitoring of parameters such as temperature, vibration, and strain using sensors and consequent data analysis can help in reducing machine downtime by taking corrective actions before failure. Various wireless and wired sensors may be attached to critical components such as bearings, gears, mechanical seals, shafts etc. for measurements. These sensors however are often inadequate solutions as wired sensors are dicult to mount on rotating components, especially in millimeter-size spaces that may exist in some of these components. Wireless sensors provide a viable solution for measurements …

Unitary Space-Time Waveform Scheduling For High-Resolution Delay-Doppler Mimo Radar Sensing, Tariq R. Qureshi

Open Access Dissertations

In this dissertation, we deal with radar systems where multiple radar waveforms are simultaneously transmitted from different antennas. The goal is to process the returns in a way that the overall ambiguity function is a sum of individual ambiguity functions, such that the sum better approximates the ideal thumbtack shape. The transmitted waveforms are based on complementary sequences, which have this property that their individual autocorrelation functions sum to a delta function. A unitary design for the illustrative 4x4 example prescribes the scheduling of the complementary sequence based waveforms over four transmit antennas over four PRIs. Further, it dictates how …

Mechanisms Of Microstructure Formation Under The Influence Of Ultrasonic Vibrations, Milan Rakita

Open Access Dissertations

Positive effects of ultrasound on crystallization have been known for almost 90 years. Application of ultrasound has been very successful in many industries, most notably in chemistry, creating a new branch of science - sonochemistry. However, ultrasonication has not found wide commercial application in the solidification processing. The reason for that is the complexity of underlying phenomena and the lack of predicting models which correlate processing parameters with the properties of a product. The purpose of this study is to give some contribution toward better understanding of mechanisms that lead to changes in the solidifying microstructure. It has been found …

Elucidation Of Chiral Recognition Mechanisms Of Solutes By Amylose Tris[(S)-Alpha-Methylbenzylcarbamate] Sorbent, Hung-Wei Tsui

Open Access Dissertations

Enantioselective separations of chiral molecules are important in various chemical fields, such as pharmaceuticals and agrochemicals industries. Polysaccharide-based sorbents have been widely used in chiral liquid chromatography. The recognition mechanisms which determine their enantioselectivities are not completely understood.

In this dissertation, the chiral recognition mechanisms of a widely used commercial sorbent, amylose tris[(S)-alpha-methylbenzylcarbamate], for benzoin (B) enantiomers were first studied. The HPLC data for benzoin with pure n-hexane as the mobile phase have been obtained. The behavior of sorbent-solute-hexane systems can be interpreted by considering only sorbent solute two-component interactions. Infrared (IR) spectra showed evidence of substantial hydrogen bonding (H-bonding) …

Dynamic Behavior Of Sandwich Beams With Internal Resonators, Bhisham Nar Narain Sharma

Open Access Dissertations

Dynamic behavior of sandwich beams with internal resonators was investigated. The effect of inserting spring-mass resonators into the sandwich core was theoretically analyzed and it was shown that a wave attenuation bandgap exists due to local resonance. Steady state experiments were used to demonstrate such an attenuation bandgap. Frequency response functions were obtained for a beam with resonators and without resonators. It was shown that insertion of resonators into the core causes a wave attenuation bandgap to open up. The experimental results were verified using finite element simulations. Further experiments were carried out by tuning the resonators at 12 Hz …

Scholarly Collaboration In Engineering Education: From Big-Data Scientometrics To User-Centered Software Design, Hanjun Xian

Open Access Dissertations

Engineering education research has grown into a flourishing community with an-ever increasing number of publications and scholars. However, recent studies show that a significant amount of engineering education knowledge retains a clear disciplinary orientation. If the gaps in scholarly collaboration continue to be prevalent within the entire community, it will become increasingly difficult to sustain community memory. This will eventually inhibit the propagation of innovations and slow the movement of research findings into practice.

This dissertation studies scholarly collaboration in the engineering education research community. It provides a clear characterization of collaboration problems and proposes potential solutions. The dissertation is …

Atomistic Simulation Of Plasma Interaction With Plasma Facing Components In Fusion Reactors, Xue Yang

Open Access Dissertations

The interaction between plasma and fusion relevant materials is one of the critical issues in successfully using those materials in Tokamak reactors. This research uses molecular dynamics, kinetic Monte Carlo and binary collision approximation methods to model fusion relevant material bombarded by energetic particles to investigate retention, deposition, sputtering, erosion, blistering effects, diffusion, and so on.

The deuterium bombardment of monocrystalline tungsten was modeled by LAMMPS code using Tersoff type interatomic potential. The deuterium trapping rate, implantation depth, and stopping time in 600-2000 K tungsten bombarded by 5-100 eV deuterium atoms were simulated. Irradiated monocrystalline tungsten became amorphous prior to …

The Comparison Of Composite Aircraft Field Repair Method (Cafrm) With Traditional Aircraft Repair Technologies, Peng Hao Wang

Open Access Dissertations

In the aviation industry, manufacturers made the transition from aluminum to composite materials for the majority of their primary structures over the last few decades. While the design and manufacturing techniques have consistently evolved, field repair methods were consistently overlooked. In this study, specimens fabricated using some of the common repair methods such as the autoclave repair method, and Double Vacuum Debulk (DVD) repair method were tested against the Composite Aircraft Field Repair Method (CAFRM) proposed by the researcher. Specimens were tested with microscopy, acid digestion, short beam shear, and mode I fracture tests. The researcher was able to determine …

A Novel Fluid Structure Interaction And Thermal Model To Predict The Cylinder Block / Valve Plate Interface Performance In Swash Plate Type Axial Piston Machines, Marco Zecchi

Open Access Dissertations

The cylinder block / valve plate interface represents one of the most critical design element in the rotating kit of axial piston machines. The thin film of lubricant between cylinder block and valve plate has to fulfill simultaneously a bearing and a sealing function under dynamic load conditions; on the other hand, it represents an important source of power losses due to viscous friction and leakage flow.

An accurate prediction of the time changing characteristics of the interface, in terms of fluid film thickness, dynamic pressure field, load carrying ability and energy dissipation is necessary to generate more efficient and …

Preparation Of Mesoporous Silica Supported Ruthenium Oxides And The Application And Kinetic Study In The Catalysis Of Water Oxidation, Yang Zhang

Open Access Dissertations

Photo-induced water splitting of water into H2 and O2 has been a major focus in the development of clean and renewable energy. The development of viable and efficient catalysts that facilitates O2 production remains the major challenge in the study of the corresponding half-reaction of water oxidation. There are plenty of metal oxides reported active in the catalysis of water oxidation. However, several important performance bench marks of those materials, such as the non-stoichiometric production of O2, slow reaction rate and/or low quantum efficiency, remain to be improved.

Ruthenium oxide (RuO2) has long been known as one of the most …

Effects Of Dip-Coated Films On The Properties Of Implantable Intracortical Microelectrodes, Salah Sommakia

Open Access Dissertations

The successful clinical use of implantable intracortical microelectrodes (ICMs) to treat certain types of deafness, blindness, and paralysis is limited by a reactive tissue response (RTR) of the brain. This RTR culminates in the formation of a tight glial scar and a loss of neuronal density around implanted ICMs, and is accompanied by a decrease in signal to noise ratio and an increase in impedance. While no comprehensive mechanistic understanding of the underlying biology is currently agreed upon in the field, a general consensus exists around a highly volatile acute RTR phase. During this acute phase, the electrical properties of …

Analysis And Optimization Of Cooperative Wireless Networks, Phuong Thanh Tran

Open Access Dissertations

Recently, cooperative communication between users in wireless networks has attracted a considerable amount of attention. A significant amount of research has been conducted to optimize the performance of different cooperative communication schemes, subject to some resource constraints such as power, bandwidth, and time. However, in previous research, each optimization problem has been investigated separately, and the optimal solution for one problem is usually not optimal for the other problems.

This dissertation focuses on joint optimization or cross-layer optimization in wireless cooperative networks. One important obstacle is the non-convexity of the joint optimization problem, which makes the problem difficult to solve …

Predictive Duty Cycling Of Radios And Cameras Using Augmented Sensing In Wireless Camera Networks, Joonhwa Shin

Open Access Dissertations

Energy efficiency dominates practically every aspect of the design of wireless camera networks (WCNs), and duty cycling of radios and cameras is an important tool for achieving high energy efficiencies. However, duty cycling in WCNs is made complex by the camera nodes having to anticipate the arrival of the objects in their field-of-view. What adds to this complexity is the fact that radio duty cycling and camera duty cycling are tightly coupled notions in WCNs.

Abstract In this dissertation, we present a predictive framework to provide camera nodes with an ability to anticipate the arrival of an object in the …

Design, Development, And Testing Of A Conformal Power Control Interface For Thrust Vectoring Aircraft, David Rozovski

Open Access Dissertations

Over the last five years, a new power control inceptor for tiltrotor aircraft, known as the Rotational Throttle Interface (RTI) was designed and built. Prior to the RTI, no tiltrotor inceptor had been able to simultaneously indicate both the direction and magnitude of thrust conformally. The purpose of the RTI is to provide an interface that maps to the intended vehicle response throughout ALL ranges of operation. Doing so is expected to reduce confusion that may have contributed to several tiltrotor accidents

Two tests were conducted with the RTI, one at the NASA Vertical Motion Simulator, and one at Canada's …

Utilizing Electron Microscopy And Spectroscopy Methods To Understand Water Structure And Water Doping, Lior Miller

Open Access Dissertations

Water is the second most common element in the universe and the most studied material on earth. Most of the studies concerning water are from the fields of chemistry and biology. Hence, the structure of water molecules and short range order and interactions are well characterized and understood. However, the collective arrangement of water molecules and the long range order are still missing. Understanding of this long range order in water is needed, as it is the key to many water activities.

To fill this gap, this study utilizes a new direct method for characterization of water in the vapor …

Spacecraft Orbit Design In The Circular Restricted Three-Body Problem Using Higher-Dimensional Poincaré Maps, Christopher D. Geisel

Open Access Dissertations

Strategies for designing three-dimensional spacecraft trajectories in a multi-body dynamical environment are investigated using four-dimensional Poincaré maps. Unlike the planar circular restricted three-body problem, where a two-dimensional map provides a simplified view of a portion of the vast and often chaotic design space, the spatial problem requires a four-dimensional map to achieve an equivalent perspective. Such higher-dimensional maps present a visualization challenge. Furthermore, a spacecraft in the spatial problem can exhibit fundamentally more diverse and complex behavior than in the planar problem. A novel approach to four-dimensional-map-based design in the spatial circular restricted three-body problem is developed and applied to …

Near-Field Pressure Distributions To Enhance Sound Transmission Into Multi-Layer Materials, Andrew Martin Jessop

Open Access Dissertations

The large impedance difference between air and most solids prevents significant energy transfer from incident acoustic waves across the air-material interface. Refraction also plays a role in preventing acoustic transmission, as the wave speed difference between air and solid materials results in an increase of the resulting propagation angles, creating near-field pressure distributions in the solid material. By utilizing evanescent pressure distributions, which decay normal to the usual direction of propagation and are represented as plane waves propagating with complex angles, energy propagation through the interface can be increased in the subsonic region of wave propagation: i.e., where waves typically …

Fault Detection And Diagnosis For Air Conditioners And Heat Pumps Based On Virtual Sensors, Woohyun Kim

Open Access Dissertations

The primary goal of this research is to develop and demonstrate an integrated, on-line performance monitoring and diagnostic system with low cost sensors for air conditioning and heat pump equipment. Automated fault detection and diagnostics (FDD) has the potential for improving energy efficiency along with reducing service costs and comfort complaints. To achieve this goal, virtual sensors with low cost measurements and simple models were developed to estimate quantities that would be expensive and or difficult to measure directly.

A virtual refrigerant charge sensor (VRC) was extended with three approaches for determining refrigerant charge for equipment having variable-speed compressors and …