Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 1 of 1
Full-Text Articles in Engineering
Organic Particulate Matter Formation At Varying Relative Humidity Using Surrogate Secondary And Primary Organic Compounds With Activity Corrections In The Condensed Phase Obtained Using A Method Based On The Wilson Equation, James F. Pankow, E. I. Chang
Organic Particulate Matter Formation At Varying Relative Humidity Using Surrogate Secondary And Primary Organic Compounds With Activity Corrections In The Condensed Phase Obtained Using A Method Based On The Wilson Equation, James F. Pankow, E. I. Chang
Civil and Environmental Engineering Faculty Publications and Presentations
Secondary organic aerosol (SOA) formation in the atmosphere is currently often modeled using a multiple lumped "two-product" (N · 2p) approach. The N · 2p approach neglects: 1) variation of activity coefficient (i) values and mean molecular weight MW in the particulate matter (PM) phase; 2) water uptake into the PM; and 3) the possibility of phase separation in the PM. This study considers these effects by adopting an (N ·2p)pMW, approach (is a phase index). Specific chemical structures are assigned to 25 lumped SOA compounds and to 15 representative primary organic aerosol (POA) compounds to allow calculation of i …