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Full-Text Articles in Engineering
Molecular View Modeling Of Atmospheric Organic Particulate Matter: Incorporating Molecular Structure And Co-Condensation Of Water, James F. Pankow, Marguerite Colasurdo Marks, Kelley C. Barsanti, Abdullah Mahmud, William E. Asher, Jingyi Li, Qi Ying, Shantanu H. Jathar, Michael J. Kleeman
Molecular View Modeling Of Atmospheric Organic Particulate Matter: Incorporating Molecular Structure And Co-Condensation Of Water, James F. Pankow, Marguerite Colasurdo Marks, Kelley C. Barsanti, Abdullah Mahmud, William E. Asher, Jingyi Li, Qi Ying, Shantanu H. Jathar, Michael J. Kleeman
Chemistry Faculty Publications and Presentations
Most urban and regional models used to predict levels of organic particulate matter (OPM) are based on fundamental equations for gas/particle partitioning, but make the highly simplifying, anonymized-view (AV) assumptions that OPM levels are not affected by either: a) the molecular. characteristics of the condensing organic compounds (other than simple volatility); or b) co-condensation of water as driven by non-zero relative humidity (RH) values. The simplifying assumptions have allowed parameterized chamber results for formation of secondary organic aerosol (SOA) (e.g., “two-product” (2p) coefficients) to be incorporated in chemical transport models. However, a return towards a less simplistic (and more computationally …
Flavour Chemicals In Electronic Cigarette Fluids, Peyton A. Tierney, Clarissa D. Karpinski, Jessica E. Brown, Wentai Luo, James F. Pankow
Flavour Chemicals In Electronic Cigarette Fluids, Peyton A. Tierney, Clarissa D. Karpinski, Jessica E. Brown, Wentai Luo, James F. Pankow
Chemistry Faculty Publications and Presentations
Background: Most e-cigarette liquids contain flavour chemicals. Flavour chemicals certified as safe for ingestion by the Flavor Extracts Manufacturers Association may not be safe for use in e-cigarettes. This study identified and measured flavour chemicals in 30 e-cigarette fluids.
Methods: Two brands of single-use e-cigarettes were selected and their fluids in multiple flavour types analysed by gas chromatography/mass spectrometry. For the same flavour types, and for selected confectionary flavours (eg, bubble gum and cotton candy), also analysed were convenience samples of e-cigarette fluids in refill bottles from local ‘vape’ shops and online retailers.
Results: In many liquids, total flavour chemicals …
Aerosol Optical Hygroscopicity Measurements During The 2010 Cares Campaign, Dean B. Atkinson, James Gregory Radney, Janel Lum, Katheryn R. Kolesar, Daniel J. Cziczo, Mikhail Pekour, Qi Zhang, Ari Setyan, Alla Zelenyuk, Christopher D. Cappa
Aerosol Optical Hygroscopicity Measurements During The 2010 Cares Campaign, Dean B. Atkinson, James Gregory Radney, Janel Lum, Katheryn R. Kolesar, Daniel J. Cziczo, Mikhail Pekour, Qi Zhang, Ari Setyan, Alla Zelenyuk, Christopher D. Cappa
Chemistry Faculty Publications and Presentations
Measurements of the effect of water uptake on particulate light extinction or scattering made at two locations during the 2010 CARES study around Sacramento, CA are reported. The observed influence of water uptake, characterized through the dimensionless optical hygroscopicity parameter γ, is compared with calculations constrained by observed particle size distributions and size-dependent particle composition. A closure assessment has been carried out that allowed for determination of the average hygroscopic growth factors (GF) at 85% relative humidity and the dimensionless hygroscopicity parameter κ for oxygenated organic aerosol (OA) and for supermicron particles, yielding κ = 0.1–0.15 and 0.9–1.0, respectively. The …