Engineering Commons^™

Adsorption On Activated Flyash, John William Kubarewicz

Theses

An experimental study was undertaken to compare the adsorptive characteristics of activated carbon, flyash, and activated flyash. Due to the contradictory evidence available in the literature, emphasis was placed on the effect of acid activation on the physical properties of the adsorbent. The experiment consisted of two parts; batch isotherm studies, and continuous column operations. An artificial sewage composed of a mixture of deionized water and beef broth was used as the adsorbate. This solution was prepared daily and exerted a COD of 225 ± 30 mg/l. Flyash activation was found to increase the degree of adsorption indirectly rather than …

An Analysis Of The Passenger Vehicle Interface Of Street Transit Systems With Applications To Design Optimization, Walter H. Kraft

Dissertations

This research analyzes the Passenger Vehicle Interface of the street transit systems and presents applications for design optimization. The Passenger Vehicle Interface (PVI) is defined as the interaction between the passenger and vehicle elements of the street transit system.

Human observer and photographic studies were conducted in 17 cities in the United States and Canada to measure the time for queues of passengers to board various transit vehicles. The data were analyzed by considering seven factors that affect the Passenger Vehicle Interface: Human Factor, Modal Factor, Operating Practices, Operating Policies, Mobility, Climate and Weather, and Other System Elements. Those effects …

The Chemical Effect Of Ultrasound On Cyanide Solutions, Nabil R. Zaki

Theses

An experimental study was undertaken to investigate the chemical effects of high intensity ultrasonic radiation on cyanide solutions. The effects of aeration, concentration of cyanide and temperatures on the reaction rate are investigated. The experiment was preformed in a 30 mm pyrex tube immersed at a fixed height in a constant volume water bath. Ultrasonic energy was applied through the use of a transducer epoxied at the bottom of the water bath. The power inputs to the transducer were 40W (27KHz) and 100W (21KHz).

At a power of 40W, ultrasound had no chemical effect on cyanide solutions. At 100W, hydrogen …

Deposition Of Suspensions In Laminar Flow In The Entrance Region Ofa Channel And In A Diffuser, Shawki Mahmoud Eldighidy

Dissertations

In this investigation, the deposition of suspensions in laminar flow in the entrance region of a channel and a diffuser was considered.

The particulate phase was considered to he under the action of the electric field force clue to electrostatic charges. In addition, a lift force acting on each particle at the wall arising from the fluid shear near the wall and an adhesive force between each particle and the wall due to the difference of the material properties for both particle and walls were considered as surface forces.

The suspension flow was assumed to be incompressible, laminar, dilute, and …

Computer Program For Binary Distillation Using The Method Of Pochon-Savarit With Enthalpy Data Calculated By Lagrange Interpolation, Joseph J. Rogus

Theses

This thesis presents a Fortran Computer Program to solve binary distillation problems. The solution is obtained by the method of Pochon-Savarit which is based upon graphical use of an enthalpy-concentration diagram. The enthalpy data in this program is calculated using Lagrange interpolation. This is accomplished by utilizing the Lagrange interpolation to get values for the enthalpy of the vapor until we find that value which lies on the same line as the enthalpy of the liquid from the preceding tray and its corresponding del point.

The required input data consist of liquid-vapor equilibrium data, heat of solution data with the …

An Investigation Of The Optical Absorption Properties Of Silicon As Related To Its Electrical Conductivity, Onofrio Louis Russo

Dissertations

The purpose of this study is to demonstrate the feasibility of obtaining the electrical conductivity of band gap semiconductors, by considering the absorption of radiation in the visible region. The experimental evidence confirmed predictions that the conductivities of the silicon samples are related to the horizontal displacement of energy in the absorption curves. The material used in this study was p-doped silicon, although the approach should be valid in general for either elemental or compound semiconductors.

The absorption coefficient for silicon was measured in the radiation region between 2.0 and 3.0 ev. This region above the indirect band gap (= …

Optimal Control And Identification Of Stochastic Systems Using Differential Game Theory, Harry Marvin Burbank

Dissertations

This dissertation deals with linear systems subjected to stochastic disturbances. The class of stochastic processes considered is the class of second order stochastic processes characterized by having finite continuous covariance. The properties of the covariance provide means to formulate optimization problems without the difficulties present when the covariance is not finite or continuous.

The first aspect studied was several classes of optimal control problems. The effects of the stochastic processes were approximated by the effects of its first two moments. This procedure resulted in allowing optimal system controls to be found whatever the first two moments of the stochastic input …

Separation Of Isomers Via Thermal Parametric Pumping, Vincent J. D'Emidio

Theses

Continuous and semicontinuous thermal parametric pumps for separating isomers were experimentally investigated using the model system glucose-fructose-water on a cation exchange resin adsorbent. A comparison was made between the experimental data and the calculated results by a method based on an equilibrium theory. The method invokes the assumptions that a multicomponent mixture contains a series of pseudo binary systems. Each binary system consists of one of the solutes as one component and the common inert solvent as the other component. It has been shown that under certain conditions, the pump with feed at the enriched end has the capacity for …

The Thermal Dehydration Of Magnesium Sulfate Hexahydrate (Mgso3.6h2o) And Magnesium Sulfite Trihydrate (Mgso3.3h2o), Raafat F. Abdel-Malek

Theses

The thermal dehydration of MgSO₃.3H₂O and MgSO₃.6H₂O have been studied by differential thermal analysis, differential scanning calorimetry and thermal gravimetric analysis.

Similar studies by other groups led to contradictory conclusions. In this investigation, these results were reconciled and it was concluded that MgSO₃.6H₂O, under equilibrium conditions, dehydrates in two steps through the intermediate formation of MgSO₃.3H₂O.

One consequence of this work is the development of a simple analytical procedure, using TGA, for the quantitative determination of both hydrates in mixtures and in the presence …

Transient Phenomena Of Polymer Solutions, Nikolaus Zwetkow

Theses

With the aid of a rotational viscometer, several transient phenomena were studied with different polymer solutions. In order to be acquainted with the operations of the rotational viscometer, viscosity measurements were made on polystyrene solution of a 7.14 wt. % NBS-2-35967 in a 35 - 65 mixture of aroclor and TCP, polyisobutylene (16.5% in mineral spirits), Indopol H-1900 (polyisobutylene) and 4.5% polyisobutylene in Primol 355. All these were done at a temperature of 77°F, except for Indopol H-1900 which was done at different temperatures. The results are listed in the section of tables and graphs.

Viscosity was measured with a …

The Thermodynamics Of Electrolytic Solutions, Eric Robert Bixon

Theses

The thermodynamic properties of solutions of electrolytes may be accurately determined by the measurement of the activity of the s6lvent. when the. solute is nonvolatile, this quantity may be obtained from measurements of the lowering of the vapor pressure caused by the presence of the dissolved solute.

An experimental method has been devised to measure this effect using a semi-conventional Othmer Still. The experimental apparatus has been constructed. and evaluated. Data has been-obtained for the vapor pressure lowering of methanol due to the presence of dissolved electrolyte for five different electrolyte-methanol systems. An extrapolation technique was developed to make use …

A Preliminary Study Of The Thermodynamic Limitations Of The Nrtl/Lemf Equations, Robert Petrie

Theses

Analytical evaluations of the second and third derivatives of the molar Gibbs energy of mixing for the NRTL/LEMF equations indicate distinct zones of miscible and inmiscible prediction.

These calculations for a number of different α's have produced approximate miscibility limits for both NRTL/LEMF energy parameters and infinite dilution activity coefficients of a given system.

Soluble Surfactant Effects On Gas Absorption Of Organic Compounds, Angelo C. Morresi

Theses

A literature search dating back to the beginning of this century turned up no previous work similar to ours. We discuss several methods and experiments involving the scrubbing of air streams.

The objective of this work was the determination of surfactant affects on the solubility of certain organic compounds of varying solubility in water. A means of simulating a packed tower was devised to allow for bench scale evaluation and thus enabled a greater number of organic compounds to be examined with a greater variety of surfactants.

Curves were plotted based on organic vapor concentration, surfactant concentration, organic type, surfactant …

A Study Of The Vibrational Spectra Of Some Monosubstituted Benezene Derivatives Of Group Via Of The Periodic Table, Fawzi S. Rasheed

Theses

The vibrational frequencies for (C₆H₅)₂Se, (C₆H₅)₂Te, (C₆H₅)₂Se₂, (C₆H₅)₂Te₂, (C₆H₅)₂Hg, and (C6H5-Se)₂Hg are completely assigned and are consistent with the vibrational assignments for (C₆H₅)₂O, (C₆H₅)₂S, and (C₆H₅)₂S₂ previously reported. Further, whereas (C₆H₅)₂O and to a lesser extent (C₆H …

A Kinetic Study Of Lysine And Lysine Derivatives, Stephen Joseph Stanley

Theses

The kinetics of the reaction of iodoacetamide with lysine, polylysine, N-α-Acetyl lysine, and N-ε-Acetyl lysine, have been studied. The investigation was done at 23° C ± 123° C, as a function of pH, and concentration. In all cases it was noted that the rate of reaction increased as the pH increased. The rate data was analyzed in order to obtain the second order rate constants. In addition, the effects of the reactive site's environment on the rate was demonstrated.

Reactions Of Para-Nitroaniline With Acid Chlorides, Stephen Alan Zapoticzny

Theses

Para-nitroaniline was reacted with acid chlorides forming amides. Their structures were elucidated by the performance of various spectral analyses.

Steady State Heat Transfer From A Double Ring Of Identical Spheres In A Regular Orientation, Evelio A. Melo

Theses

Solutions to Laplace's equation are obtained by the method of reflections for the problem of heat transfer from two parallel rings of spheres arranged in regular polygonal arrays. The mathematical models developed describe the rate of heat transfer and spatial temperature distribution due to an arbitrary number of identical spheres of equal surface temperature correcting Fourier's heat transfer equation for the interference caused by a multiparticle array. Although the method of solution is quite rigorous and can be used to obtain as accurate a solution as desired, only the second reflection was obtained, yielding a first order correction. The model …

Design Of A Yig-Tuned Oscillator, Tien Liang Jin

Theses

A technique for designing YIG (yttrium-iron garnet) tuned transistor oscillators, tunable over the range of frequencies from 500 to 950 MHZ, is presented. The approach taken differs appreciably from that used in the design of conventional LC-tuned oscillators. One major difference is that the YIG tuning mechanism is electrically controlled. The YIG tuning element is treated as a single unit and is not resolved into an equivalent LC circuit. Instead, a direct method using reflection coefficients measured at network terminals to characterize various design stages is applied. The transistor is also characterized by reflection and transmission coefficients, i.e., S-parameters. Thus …