Engineering Commons^™

Heavy Metal Adsorption On Iron Oxide And Iron Oxide-Coated Silica : Macroscopic, Spectroscopic, And Modeling Studies, Ying Xu

Dissertations

To accurately model metal mobility and bioavailability in soils and sediments, systematic sorption studies are needed using representative and well-characterized minerals. Two important surfaces are iron oxide and silica, which are ubiquitous and associated with one another in the environment playing important roles in metal distribution. The objectives of this research are to develop models for predicting speciation and mobility of toxic trace metal ions in groundwater, soils, and sediments when competing ions are present. A model system for soils and sediments, iron oxide-coated silica, was synthesized; the degree of coatings was highly sensitive to the particle size of silica …

Optimal Speed Limit For Shared-Use Roadways, Yongqiang Yang

Dissertations

Motor vehicle crashes are a serious social problem in the United States. Each year a large number of motor vehicle crashes occur and many people are killed or injured, resulting in substantial economic costs. To minimize economic costs, it is necessary to determine optimal speed limits on roadways because of the strong relationship among posted speed limit, crash frequency, and crash injury severity.

A comprehensive literature review about the relationship among posted speed limit, crash frequency, and crash injury severity level was conducted. Crash frequency prediction models and crash injury severity models are developed to obtain crash frequency and injury …

Development Of Adsorption Filtration Process For Virus Removal For Drinking Water Treatment, Vishal Vijay Gawarikar

Dissertations

Recent monitoring studies have indicated that many ground water (GW) sources would benefit from the development of effective technologies for removing viruses. Although reverse osmosis can achieve high log removal it is not economical. The main objective of this study is to test and validate a novel adsorption filtration (AF) technology for removing viruses from GW sources for drinking water production in New Jersey.

The convective diffusion of viruses to adsorbent particle surfaces in flow packed beds (FPB) enhances their removal efficiency if the adsorbent particle size can be decreased to about 100 microns. The development of effective virus removal …

Mechanics Of Biocell Landfill Settlements, Chamil Hiroshan Hettiarachchi

Dissertations

Prediction of landfill gas generation and settlements are of concerns in design and maintenance of biocell landfills. Accurate settlement prediction is essential for design of piping systems used for the delivery of re-circulated leachate and recovery of landfill gas. Landfill settlement is the result of change in overburden stresses and biodegradation of waste. Biodegradation-induced settlement results from the re-arrangement of waste skeleton in response to the decomposition of waste mass.

Current practice of landfill settlement modeling is predominantly empirical, thus most of the available techniques make no attempt to simulate the real mechanisms of waste settlement. Traditionally compressibility index is …

Virtual Transshipments And Revenue-Sharing Contracts In Supply Chain Management, Zhaoqiong Qin

Dissertations

This dissertation presents the use of virtual transshipments and revenue-sharing contracts for inventory control in a small scale supply chain. The main objective is to maximize the total profit in a centralized supply chain or maximize the supply chain's profit while keeping the individual components' incentives in a decentralized supply chain.

First, a centralized supply chain with two capacitated manufacturing plants situated in two distinct geographical regions is considered. Normally, demand in each region is mostly satisfied by the local plant. However, if the local plant is understocked while the remote one is overstocked, some of the newly generated demand …

Utility Of Remote Sensing Data In Retrieval Of Water Quality Consituents Concentrations In Coastal Water Of New Jersey, Ting Yu

Dissertations

Three important optical properties used for monitoring coastal water quality are the concentrations of chlorophyll (CHL), color dissolved organic matter (CDOM) and total suspended materials (TSM). Ocean color remote sensing, a technique to collect color data by detection of upward radiance from a distance (Bukata et al.,1995), provides a synoptic view for determining these concentrations from upwelling radiances. In the open ocean (Case-I), it is not difficult to derive empirical algorithms relating the received radiances to surface concentrations of water quality parameters. In coastal waters (Case-Il), there are serious unresolved problems in extracting chlorophyll concentration because of high concentration of …

Behavior Of Structural Concrete Members Strengthened By Composite Fabrics, Jian Chen

Dissertations

The new technique of using Fiber Reinforced Polymer (FRP) materials to repair and strengthen various concrete members is becoming more and more popular in structural retrofitting field. Among all the confining materials, Carbon Fiber Reinforced Polymer (CFRP) fabric jackets are identified as an effective way to enhance the strength and ductility of concrete members due to its superior mechanical properties. This study investigates the detailed structural behavior of confined concrete members using CFRP fabric jackets by both analytical and experimental approaches.

A series of CFRP wrapped concrete cylinder tests were conducted to study the compressive stress-strain behavior for CFRP confined …

Corrosion Studies On Alpha Tantalum And Beta Tantalum Coated Steel, Sung Min Maeng

Dissertations

Tantalum coating by sputtering, one form of physical vapor deposition (PVD), has been investigated as a replacement for chromium coatings on gun bores to protect them from erosion and corrosion due to its high ductility and high corrosion resistance in aggressive environments. When deposited as a film on steel substrates by sputtering, either α-Ta, β-Ta, or a mixture of both phases have been observed under varying deposition conditions. To evaluate corrosion behavior of Ta coatings, electrochemical impedance spectroscopy and potentiodynamic polarization were conducted as a function of coating thickness. The coating porosity was observed to decrease with increasing coating thickness …

Bus Arrival Time Prediction Using Stochastic Time Series And Markov Chains, Rajat Rajbhandari

Dissertations

Public transit agencies rely on disseminating accurate and reliable information to transit users to achieve higher service quality and attract more users. With the development of new technologies, the concept of providing users with reliable information about bus arrival times at bus stops has become increasingly attractive. Due to the fact that bus operation parameters and variables are highly stochastic, modeling prediction of bus travel and arrival times has become one of the many challenging tasks.

Stochastic time series and delay propagation models to predict bus arrival times using historical information were developed. Markov models were developed to predict propagation …

Uniaxial And Triaxial Behavior Of High Strength Concrete With And Without Steel Fibers, Xiaobin Lu

Dissertations

This study first presents an extensive experimental research program on the true uniaxial and triaxial compression behavior for both high strength concrete (HSC) and steel fiber reinforced high strength concrete (SFHSC). The experimental study mainly focuses on the octahedral shear stress strain relationship of those two types of concrete, which is adopted as the basis to develop a new incremental constitutive model. Emphasis is also put on the investigation of the variation of tangent Poisson's ratio under not only uniaxial but also triaxial stress conditions. The effect of cyclic loading on this parameter is also addressed.

According to this research, …

Development And Application Of Fractionation Procedure For Drinking Water Organic Matters, Yong Pu

Dissertations

USEPA mandates a control of disinfection by-products (DBPs) in finished drinking water and recommends reduction of natural organic matters (NOM), DBP precursors, to achieve this regulatory goal. Studies relating NOM with DBP include fractionation of water samples, characterization of collected organic fractions, fractions' formation potential tests, and jar or similar tests to remove NOM. This study discussed a current resin fractionation procedure on principle, procedure, and its efficiency when applied to water samples of low NOM (< 5mgIL). The primary objective of this research is to develop a fractionation procedure intended for water of low NOM by carefully applying mass balance concept through each fraction's fractionation and a selection of stable ion exchange resins. A new protocol was presented with triple columns of XAD-8 adsorption resin, one column of AG-MP-50 cationic resin, and another column of WA 10 weak anionic resin in sequence. This protocol was experimented and confirmed for its efficiency (±10% loss of mass) with samples from Canal Road (CR) and Raritan Millstone (RM) surface water treatment plants (WTPs) in central New Jersey. The second objective of this study is to develop a statistical model with a potential of online delineation of organic fractions of NOM. The resulting model based on samples of Passaic Valley Water Commission (PVWC) WTP in northern New Jersey was applied to predict organic fractions of samples from CR and RM plants. Paired T-test (paired t ratio 1.15 < t critical 2.02) indicated a good correlation between the predicted and actual fraction concentration. Finally, samples of Middlesex Water Company (MWC) were fractionated and Trihalomethane formation potential tests (THMFP) on collected fraction showed hydrophilic matters possessed a higher potential to produce TTHM in finished water than hydrophobic matter. Jar tests indicated while coagulation was effective in removing hydrophobic matter, it may not be optimum for removal of hydrophilic matter.

This study developed an accurate fractionation procedure for low NOM waters. It provided a better understanding of organic matter transformation at different treatment …

Tide-Influenced Contaminant Transport In Coastal Aquifers, Yong Peng

Dissertations

Coastal aquifers are distinguished from other aquifers because of tidal effects which cause complicated groundwater flow and contaminant transport phenomena in regions immediately adjacent to the coast. This study is designed to address the significance of tidal influence on contaminant transport by focusing on one-dimensional homogeneous coastal aquifers.

This study formulates a conceptual model and corresponding flow and transport equations, analyzes coastal boundary conditions, solves numerically the transport equation, and uses experiments to verify the numerical results.

Results of numerical and experimental studies conclude that tides can have a significant impact on contaminant transport, especially when under unconfined conditions, subject …