Open Access. Powered by Scholars. Published by Universities.®
- Discipline
- Publication
-
- Civil, Architectural and Environmental Engineering Faculty Research & Creative Works (7)
- Chemical and Biochemical Engineering Faculty Research & Creative Works (1)
- Materials Science and Engineering Faculty Research & Creative Works (1)
- Mechanical and Aerospace Engineering Faculty Research & Creative Works (1)
Articles 1 - 10 of 10
Full-Text Articles in Engineering
Dissolution Rates Of Borophosphate Glasses In Deionized Water And In Simulated Body Fluid, Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow
Dissolution Rates Of Borophosphate Glasses In Deionized Water And In Simulated Body Fluid, Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow
Materials Science and Engineering Faculty Research & Creative Works
Particles of Borophosphate Glasses with the Nominal Molar Compositions 16Na2O-(24-Y)CaO-YSrO-XB2O3-(60-X)P2O5 (Mol%), Where 0 ≤ X ≤ 60 and Y = 0, 12, and 24, Were Reacted in Deionized Water and in Simulated Body Fluid (SBF) at 37 °C. for the Dissolution Experiments in Water, the PH of the Solution at the Conclusion of the Experiments Increased Systematically, from 2.1 to 9.5, for Y = 0 Glasses When 'x' Increased from 0 to 60. the Reaction Rates over the First 8–24 H of Dissolution in Both SBF and Deionized Water Followed Linear …
A Comprehensive Experimental And Modeling Study On Dissolution In Li-Ion Batteries, Yoon Koo Lee, Jonghyun Park, Wei Lu
A Comprehensive Experimental And Modeling Study On Dissolution In Li-Ion Batteries, Yoon Koo Lee, Jonghyun Park, Wei Lu
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Dissolution is a critical challenge in metal oxide battery materials, which affects battery performance across multiple scales. At the particle level, the loss of active material as a result of dissolution directly results in capacity fade. At the electrode level, the re-deposition of dissolved metal ions onto the cathode increases cell polarization and hinders lithium transport. At the cell level, the dissolved ions further transport to and deposit on the anode, which consumes cycle-able lithium and leads to capacity fade. These processes lead to poor lithium reversibility, diffusivity, and conductivity. In this work, detailed experimental studies from the particle level …
Characterization Of Air Dissolution And Reappearance Under Pressure In Cement Pastes By Means Of Rheology, Daniel Galvez-Moreno, Dimitri Feys, Kyle Riding
Characterization Of Air Dissolution And Reappearance Under Pressure In Cement Pastes By Means Of Rheology, Daniel Galvez-Moreno, Dimitri Feys, Kyle Riding
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Concrete pumping is the most used technique to transfer concrete from the mixer truck to the formwork. Numerous studies have been performed on the flow behavior of concrete in pipes, as well as the consequences of pumping on fluid and hardened concrete properties. One of the negative consequences of pumping concrete is a decrease in freeze-thaw resistance. This is caused by a decrease in air content and an increase in air bubble size, due to dissolution and reappearance of air and air bubble coalescence under pressure. This paper investigates the capability of rheology to understand air dissolution and reappearance in …
Ultrathin Conductive Ceo₂ Coating For Significant Improvement In Electrochemical Performance Of Limn₁.₅Ni₀.₅O₄ Cathode Materials, Rajankumar L. Patel, Sai Abhishek Palaparty, Xinhua Liang
Ultrathin Conductive Ceo₂ Coating For Significant Improvement In Electrochemical Performance Of Limn₁.₅Ni₀.₅O₄ Cathode Materials, Rajankumar L. Patel, Sai Abhishek Palaparty, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
LiMn1.5Ni0.5O4 (LMNO) has a huge potential for use as a cathode material in electric vehicular applications. However, it could face discharge capacity degradation with cycling at elevated temperatures due to attacks by hydrofluoric acid (HF) from the electrolyte, which could cause cationic dissolution. To overcome this barrier, we coated 3-5 micron sized LMNO particles with a ∼3 nm optimally thick and conductive CeO2 film prepared by atomic layer deposition (ALD). This provided optimal thickness for mass transfer resistance, species protection, and mitigation of cationic dissolution at elevated temperatures. After 1,000 cycles of chargedischarge between …
Chemical And Hydrodynamic Mechanisms For Long-Term Geological Carbon Storage, Susan J. Altman, Wen Deng, For Full List Of Authors, See Publisher's Website.
Chemical And Hydrodynamic Mechanisms For Long-Term Geological Carbon Storage, Susan J. Altman, Wen Deng, For Full List Of Authors, See Publisher's Website.
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Geological storage of CO₂ (GCS), also referred to as carbon sequestration, is a critical component for decreasing anthropogenic CO₂ atmospheric emissions. Stored CO₂ will exist as a supercritical phase, most likely in deep, saline, sedimentary reservoirs. Research at the Center for Frontiers of Subsurface Energy Security (CFSES), a Department of Energy, Energy Frontier Research Center, provides insights into the storage process. The integration of pore-scale experiments, molecular dynamics simulations, and study of natural analogue sites has enabled understanding of the efficacy of capillary, solubility, and dissolution trapping of CO₂ for GCS. Molecular dynamics simulations provide insight on relative wetting of …
Effect Of Crumb Rubber Dissolution On Low-Temperature Performance And Aging Of Asphalt-Rubber Binder, Amir Ghavibazoo, Magdy Abdelrahman
Effect Of Crumb Rubber Dissolution On Low-Temperature Performance And Aging Of Asphalt-Rubber Binder, Amir Ghavibazoo, Magdy Abdelrahman
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Asphalt binder plays a critical role in defining the low-temperature performance of asphalt pavement, and, therefore, enhancing its mechanical behavior at low service temperatures through modification always has been of great interest. Crumb rubber modification of asphalt is one of the common practices in the industry. However, the effect of a crumb rubber modifier (CRM) on low-temperature performance of the binder is not well understood. A CRM swells by absorbing the aromat-ics and light molecular components of asphalt at low interaction temperatures (i.e., 160°C) and dissolves at higher interaction temperatures (i.e., 190°C, 220°C). Each of those activities affects the performance …
Effects Of Interaction Conditions On Internal Network Structure Of Crumb Rubber-Modified Asphalts, Mohyeldin Ragab, Magdy Abdelrahman
Effects Of Interaction Conditions On Internal Network Structure Of Crumb Rubber-Modified Asphalts, Mohyeldin Ragab, Magdy Abdelrahman
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Investigation of the effect of interaction conditions on the development of the internal network structure of crumb rubber-modified asphalt (CRMA) was carried out. Enhancements in the CRMA physical properties, such as stiffness, expressed in the complex modulus (G*), and elasticity, expressed in the phase angle (δ), as a result of the development of three-dimensional (3-D) entangled network structure were achieved. These results came from controlling the interaction conditions of CRMA synthesis to regulate the crumb rubber-modified (CRM) components that were responsible for the formation of the 3-1) entangled network structure. Dissolution tests and thermogravimetric analysis (TGA) were performed on the …
Mechanism Of Crumb Rubber Modifier Dissolution Into Asphalt Matrix And Its Effect On Final Physical Properties Of Crumb Rubber-Modified Binder, Amir Ghavibazoo, Magdy Abdelrahman, Mohyeldin Ragab
Mechanism Of Crumb Rubber Modifier Dissolution Into Asphalt Matrix And Its Effect On Final Physical Properties Of Crumb Rubber-Modified Binder, Amir Ghavibazoo, Magdy Abdelrahman, Mohyeldin Ragab
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Modification of asphalt by crumb rubber modifier (CRM) is mostly done through exchange of components between asphalt and CRM. At 160⁰ C and 10 Hz, CRM absorbs aromatics of asphalt and swells; however, at 220⁰ C and 50 Hz, CRM dissolves into the asphalt; this process leads to the release of different components of CRM including carbon black, fillers, and polymeric and oily components. Depending on interaction conditions, CRM dissolution is performed differently, and therefore the state and role of the released components can be different. In this research different mechanisms of dissolution of one size of CRM in asphalt …
Effect Of Crumb Rubber Modifier Dissolution On Storage Stability Of Crumb Rubber-Modified Asphalt, Amir Ghavibazoo, Magdy Abdelrahman, Mohyeldin Ragab
Effect Of Crumb Rubber Modifier Dissolution On Storage Stability Of Crumb Rubber-Modified Asphalt, Amir Ghavibazoo, Magdy Abdelrahman, Mohyeldin Ragab
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Crumb rubber-modified asphalt (CRMA) extensively suffers from high-temperature storage instability. Because of the higher density of the crumb rubber modifier (CRM) particles, they settle down to the bottom of storage tanks and cause variation between physical properties of the top and bottom samples. The storage stability of the CRMA changes under different interaction parameters and consequently different mechanisms of interaction. In this research the mechanism of separation under different levels of CRM dissolution was investigated by using Stokes' law. The extent and mechanism of CRM dissolution in asphalt was controlled through regulating interaction temperature and interaction mixing speed. A standard …
Effects Of Nano-Copper(Ii) Oxide And Nano- Magnesium Oxide Particles On Activated Sludge, Guoqiang Liu, Jianmin Wang
Effects Of Nano-Copper(Ii) Oxide And Nano- Magnesium Oxide Particles On Activated Sludge, Guoqiang Liu, Jianmin Wang
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Effects of nano-copper (II) oxide (nano-CuO) and nano-magnesium oxide (nano-MgO) particles on activated sludge endogenous respiration (aerobic digestion), biochemical oxygen demand (BOD) biodegradation, and nitrification were investigated through respiration rate measurement. for comparison, the effects of Cu (II) and Mg (II) ions on activated sludge were also studied. Results indicated that soluble Cu (II) has half maximum inhibitory concentration (IC50) values of 19, 5.5, 53, and 117 mg Cu/L for endogenous respiration, BOD biodegradation, ammonium oxidation, and nitrite oxidation, respectively. However, nano-CuO only inhibited BOD biodegradation at 240 mg Cu/L or more, and its associated toxicity was primarily caused by …