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Missouri University of Science and Technology

Series

Materials Science and Engineering Faculty Research & Creative Works

1976

Articles 1 - 8 of 8

Full-Text Articles in Engineering

Evaluation Of Zinc Sulfate Electrolytes By Cyclic Voltammetry And Electron Microscopy, Bruce A. Lamping, Thomas J. O'Keefe Dec 1976

Evaluation Of Zinc Sulfate Electrolytes By Cyclic Voltammetry And Electron Microscopy, Bruce A. Lamping, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

A cyclic voltammetric technique has been developed for approximating the quantities of active chemical species present in zinc sulfate electrolytes. The experimental apparatus consisted of a Pyrex "H" cell, an aluminum cathode encased in a Teflon holder, a carbon anode and a mercurous sulfate reference electrode. Voltammograms were obtained using industrial, purified neutral leach solution (Cominco Ltd., Trail, BC) acidified to give a final concentration of 0.77 M Zn++ and 1 M H2SO4. The polarization curves were then evaluated and used as reference standards to compare with results obtained when various organic and inorganic additions were made. The deposit morphologies …


Intermetallic Reactions In Vacuum-Deposited Nickel And Gold Films On (111) Silicon Single Crystals, K. H. Yoon, Gordon Lewis, L. L. Levenson Apr 1976

Intermetallic Reactions In Vacuum-Deposited Nickel And Gold Films On (111) Silicon Single Crystals, K. H. Yoon, Gordon Lewis, L. L. Levenson

Materials Science and Engineering Faculty Research & Creative Works

Pure nickel and gold thin films were vacuum-deposited on (111) silicon single crystals. When Ni/Au/Si or Au/Ni/Si samples were heated to about 550° in situ, hexagonal or deformed hexagonal shaped crystallites were formed on the silicon substrates. The composition of these crystallites was determined by using x-ray diffraction, scanning electron microscopy and scanning Auger microprobe methods. The crystallites were identified as NiSi2. The crystal-lites on the (111) silicon plane parallel to the surface appeared as regular hexagons while the inclined crystal-lites resembled trapezia. The results of Auger spectra and in-depth composition profiles for Ni, Au, and Si showed that the …


Void-Strengthening In Aluminum And Its Nature, P. G. Manusmare, Hollis P. Leighly Jan 1976

Void-Strengthening In Aluminum And Its Nature, P. G. Manusmare, Hollis P. Leighly

Materials Science and Engineering Faculty Research & Creative Works

Temperature and strain rate dependence of yield strength were used to analyze the nature of aluminum strengthened by the formation of voids. Aluminum rods 99.999% pure were quenched and heat treated to form voids with an approximate density of 1013-1014 voids/cm3. Voids in selected samples were observed by electron microscopy. The yield strength of the void strengthened samples was measured at various temperatures from 77 to 593 K and at two strain rates, 3.33 x 10-2/s and 1.67 x 10-3/s. Tests at room temperature and at 77 K were made at various strain rates. The similarity of Coulomb's approach to …


The Martensite Transformation, Manfred Wuttig, Tetsuro Suzuki Jan 1976

The Martensite Transformation, Manfred Wuttig, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.


On The Effects Of Antimony And Glue On Zinc Electrocrystallization Behaviour, D. J. Robinson, Thomas J. O'Keefe Jan 1976

On The Effects Of Antimony And Glue On Zinc Electrocrystallization Behaviour, D. J. Robinson, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

An investigation has been made to determine the effects that additions of glue and antimony have on the electrowinning of zinc from acid sulphate solutions. In particular, the zinc crystal growth and cathode current efficiencies were studied in an attempt to establish a correlation between morphology and the nature of the additives. Operating conditions of 55 A ft-2* and 35°C were used for most of the experiments with electrolyte concentrations of approximately 55 gl-1 zinc and 150 gl-1 H2SO4. Additional runs were made at 40,75 and 100 Aft-2 at 30,40 and 50°C in order to verify certain trends. Primarily by …


A Suboptimal Control Law To Improve The Transient Stability Of Power Systems, Aditya Kumar, Earl F. Richards Jan 1976

A Suboptimal Control Law To Improve The Transient Stability Of Power Systems, Aditya Kumar, Earl F. Richards

Materials Science and Engineering Faculty Research & Creative Works

The application of optimal control theory to damp the electromechanical oscillations associated with the transient conditions in power systems has been given little attention. A suboptimal control law which minimizes the sum of the performance indices of the two linear systems given by a piecewise linear model of a power system improves the transient stability better than the usual "optimal" control law obtained from a linearized model. Further, the suboptimal control law presented in this paper assures stability of the system for all disturbances resulting in rotor oscillations of magnitudes less than a preselected limit. Copyright © 1976 by The …


Interpretation Of Some Of The Basic Features Of Field-Ion Image Projections From A Hemispherical To A Planar Surface Using Moire Patterns, P. D. Ownby, Robert M. Doerr, Walter Bollmann Jan 1976

Interpretation Of Some Of The Basic Features Of Field-Ion Image Projections From A Hemispherical To A Planar Surface Using Moire Patterns, P. D. Ownby, Robert M. Doerr, Walter Bollmann

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.


The Effect Of Receiver Pressure On The Observed Flow Pattern In The Hydrostatic Extrusion Of Bimetal Rods, Ronald A. Kohser Jan 1976

The Effect Of Receiver Pressure On The Observed Flow Pattern In The Hydrostatic Extrusion Of Bimetal Rods, Ronald A. Kohser

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.