Engineering Commons^™

Ultra-Thin Coating And Three-Dimensional Electrode Structures To Boosted Thick Electrode Lithium-Ion Battery Performance, Jie Li, Yan Gao, Xinhua Liang, Jonghyun Park

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper reports a multiscale controlled three‐dimensional (3D) electrode structure to boost the battery performance for thick electrode batteries with LiMn_1.5Ni_0.5O₄ as cathode material, which exhibits a high areal capacity (3.5 mAh/cm²) along with a high specific capacity (130 mAh/g). This excellent battery performance is achieved by a new concept of cell electrode fabrication, which simultaneously controls the electrode structure in a multiscale manner to address the key challenges of the material. Particles with ultrathin conformal coating layers are prepared through atomic layer deposition followed by a nanoscale‐controlled, thermal diffusion doping. The particles …