Engineering Commons^™

Characterization And Utilization Of Alkali-Activated Concrete For Sustainable Infrastructures, Eslam Gomaa

Doctoral Dissertations

“This study has investigated the feasibility of using locally available fly ashes (FAs) to synthesize alkali-activated concrete (AAC) for different structural and repair applications. Using AAC made of 100% FA reduces global CO2 emissions, saves energy, and decreases raw material consumption during the production process of ordinary Portland cement. Class C FAs, sourced from Labadie, Jeffery City, Kansas City, Thomas Hill, and Sikeston power plants in the state of Missouri, were used to synthesize the AAC. Sodium silicate (SS), Na2SiO3, and sodium hydroxide (SH), NaOH were used as the alkali activators. Slag, crumb rubber, and air-entraining admixture were used as …

Design Of Magnesium Phosphate Cement Based Composite For High Performance Bipolar Plate Of Fuel Cells, Wenbin Hao, Hongyan Ma, Zeyu Lu, Guoxing Sun, Zongjin Li

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

In this work, we report a comprehensive study on a magnesium phosphate cement (MPC) based composite as the construction material for high performance bipolar plates of fuel cells. MPC with partial replacement of fly ash was employed as the binding matrix. Some carbon-based materials, such as graphite, carbon black, carbon fiber, and multi-walled carbon nanotubes were used to construct the conductive phase. A simple hot-press process was applied to produce the composite. The formula and the structure of the composite was modified and adjusted to optimize the properties of the composite to meet the US DOE 2015 technical targets, including …

Effects Of High Volume Fly Ash And Powder Activators On Plastic And Hardened Concrete Properties, Drew Alexander Davis

Masters Theses

This study was performed to examine the effects of high volumes of Class C fly ash modified by powder activators upon the plastic and hardened properties of concrete. In a companion study, five Missouri area cements and five Class C fly ashes were examined for incompatibilities, with the most and least reactive combinations being scaled up to full scale concrete testing. Two baseline concrete mixtures were examined, the only difference in mixtures being the sources of portland cement and fly ash. Fly ash replacement was examined at 50% and 70% replacement (by total cementitious mass). Three powder activators were used …

Effects Of High Volumes Of Fly Ash On Cement Paste, Karl Wehking Beckemeier

Masters Theses

"The study of high-volume fly ash (HVFA) concrete mixtures has become popular due to the significant environmental and economic benefits which the material may provide. By including fly ash at 50 percent or greater replacement levels, substantial benefits could be obtained. However, the inclusion of fly ash can have negative effects, including incompatibilities between constituents of a mixture. As the fly ash replacement level increases, the degree and likelihood of these problems increases.

In this study, paste mixtures were made, as part of a larger HVFA concrete study, in order to determine the degree to which varying levels of fly …