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Full-Text Articles in Engineering

Selected Chemoautotrophic Processes In Wastewater Treatment: Low Temperature Nitrification Inhibition By An Azo Dye And Biofiltration For Odor Control Of Hydrogen Sulfide, Ronald W. Martin Jr. Jan 2003

Selected Chemoautotrophic Processes In Wastewater Treatment: Low Temperature Nitrification Inhibition By An Azo Dye And Biofiltration For Odor Control Of Hydrogen Sulfide, Ronald W. Martin Jr.

Dissertations, Master's Theses and Master's Reports - Open

Biochemical processes by chemoautotrophs such as nitrifiers and sulfide and iron oxidizers are used extensively in wastewater treatment. The research described in this dissertation involved the study of two selected biological processes utilized in wastewater treatment mediated by chemoautotrophic bacteria: nitrification (biological removal of ammonia and nitrogen) and hydrogen sulfide (H2S) removal from odorous air using biofiltration.

A municipal wastewater treatment plant (WWTP) receiving industrial dyeing discharge containing the azo dye, acid black 1 (AB1) failed to meet discharge limits, especially during the winter. Dyeing discharge mixed with domestic sewage was fed to sequencing batch reactors at 22oC and 7oC. …


Reaction Control In Quiescent Systems Of Free-Radical Retrograde-Precipitation Polymerization, Vijaya Raghavan Tirumala Jan 2003

Reaction Control In Quiescent Systems Of Free-Radical Retrograde-Precipitation Polymerization, Vijaya Raghavan Tirumala

Dissertations, Master's Theses and Master's Reports - Open

Free-radical retrograde-precipitation polymerization, FRRPP in short, is a novel polymerization process discovered by Dr. Gerard Caneba in the late 1980s. The current study is aimed at gaining a better understanding of the reaction mechanism of the FRRPP and its thermodynamically-driven features that are predominant in controlling the chain reaction.

A previously developed mathematical model to represent free radical polymerization kinetics was used to simulate a classic bulk polymerization system from the literature. Unlike other existing models, such a sparse-matrix-based representation allows one to explicitly accommodate the chain length dependent kinetic parameters.

Extrapolating from the past results, mixing was experimentally shown …