Engineering Commons^™

Chemically Modified Cellulosic Materials As Multi-Functional Agents In Polymer Composites, Jinlong Zhang

LSU Doctoral Dissertations

Comparative flame retardancy of micro wood fiber plastic composites (WPCs) with fire retardants (1,2-bis(pentabromophenyl) ethane, metal hydroxides and nanoclay) was studied. The fire additives (1,2-bis(pentabromophenyl) ethane as well as magnesium hydroxide) obviously enhanced the fire retarding properties of WPCs. Especially, 1,2-bis(pentabromophenyl) ethane significantly reduced the total heat release as well as heat release rate. In addition, a synergistic effect of 1,2-bis(pentabromophenyl) and nanoclay was achieved for the enhanced fire retarding performance of WPCs.

A copolymer of cellulose nanocrystals (CNCs) and poly(N-vinylcaprolactam) (PVCL) (PVCL-g-CNCs) for use as thermally-responsive polymers with low critical solution temperatures (LCSTs) was synthesized via atom transfer radical …

Healing-On-Demand Polymer Composites Based On Shape Memory Polyurethane Fibers And Polymeric Artificial Muscles, Pengfei Zhang

LSU Doctoral Dissertations

In this dissertation, the healing-on-demand polymer composites based on shape memory polyurethane fibers and artificial muscles are investigated, for understanding and developing a novel healing-on-demand composite so that it would be used for industrial applications that could heal structural-length scale damage and leaking autonomously, repeatedly, efficiently, timely, and molecularly. Firstly, the structural relaxation behavior of shape memory polyurethane (SMPU) fiber was studied by theoretical analysis and experimental test. Then, a self-healing composite based on cold-drawn short SMPU fiber was prepared and tested for evaluating its crack-healing performance. After that, polymer artificial muscle based healing-on-demand composite was developed and characterized. Based …