Engineering Commons^™

Engineering Metal-Ligand Interface For Selective Electrochemical Carbon Dioxide Reduction, Yuxin Fang

LSU Doctoral Dissertations

Unsustainable exploitation of fossil fuel and its massive greenhouse gas emission necessitates the development in alternative energy sources. Chemical fuels (CH₃OH or C₂H₅OH) outperform other choices, such as batteries for their high energy densities, which is key to portability. Electrochemical reduction of CO₂is capable of producing a wide range of valuable fuels (Syngas, formic acid, methane and methanol, etc.). Converting CO₂into carbon-based fuels further closes the carbon neutral cycle, which contributes to the effort in reducing global CO₂emission. Integration of organic ligands with transition metals shows great potential …