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Brominated Carbon Materials As Positive Electrodes For Nonaqueous Secondary Lithium-Bromine Batteries, Benjamin Beau Peterson

LSU Doctoral Dissertations

Secondary lithium-bromine (Li-Br₂) batteries have theoretical potentials near 4.1 V vs Li/Li⁺ and capacities more than 2 times greater than conventional Li-ion batteries. Herein, secondary, non-aqueous Li-Br₂ half-cell batteries are reported using a Li metal anode, carbon-coated glass fiber separator, non-aqueous Li-based electrolytes with and without the addition of lithium bromine (LiBr) salt, and positive electrodes consisting of either chemically brominated non-graphitic carbon or carbon derived from the carbonization of metal-organic frameworks (MOFs) with LiBr embedded into the micro- and mesopores of the carbon matrix. The separator is effective in mitigating the transport of Br_{2 …}