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Articles 1 - 21 of 21
Full-Text Articles in Engineering
Statistical Modeling And Optimization Of Process Parameters For 2, 4-Dichlorophenoxyacetic Acid Removal By Using Ac/Pdmaema Hydrogel Adsorbent: Comparison Of Different Rsm Designs And Ann Training Methods, Irvan Dahlan, Emilia Eizleen Md Azhar, Siti Roshayu Hassan, Hamidi Abdul Aziz, Yung-Tse Hung
Statistical Modeling And Optimization Of Process Parameters For 2, 4-Dichlorophenoxyacetic Acid Removal By Using Ac/Pdmaema Hydrogel Adsorbent: Comparison Of Different Rsm Designs And Ann Training Methods, Irvan Dahlan, Emilia Eizleen Md Azhar, Siti Roshayu Hassan, Hamidi Abdul Aziz, Yung-Tse Hung
Civil and Environmental Engineering Faculty Publications
In this study, the response surface methodology (RSM) and artificial neural network (ANN) were employed to study the adsorption process of 2,4-dichlorophenoxyacetic acid (2,4-D) by using modified hydrogel, i.e., activated carbon poly(dimethylaminoethyl methacrylate) (AC/PDMAEMA hydrogel). The effect of pH, the initial concentration of 2,4-D and the activated carbon content on the removal of 2,4-D and adsorption capacity were investigated through the face-centered composite design (FCCD), optimal design and two-level factorial design. The response surface plot suggested that higher removal of 2,4-D and adsorption capacity could be achieved at the higher initial concentration of 2,4-D and lower pH and activated carbon …
Comparison Of Dye Wastewater Treatment Methods: A Review., Bukola M. Adesanmi, Yung-Tse Hung, Howard Paul, Christopher Huhnke
Comparison Of Dye Wastewater Treatment Methods: A Review., Bukola M. Adesanmi, Yung-Tse Hung, Howard Paul, Christopher Huhnke
Civil and Environmental Engineering Faculty Publications
Wastewater is produced by numerous dyes producing and dye consuming industries in their process activities especially the textile industry. These effluents become toxic and harmful to the living things and the environment if not properly treated before being discharged to the environment. In recent decades dye wastewater has been becomes a growing water pollution problem because it is one of the most difficult to treat. To put an end to this problem, viable, efficient, and sustainable method of treatment of dye wastewater and color removal needs to be established. Several research papers have been done over the years on various …
Synthetic Wastewater Treatment Using Agro-Based Adsorbents, Saisantosh Vamshi Harsha Madiraju, Yung-Tse Hung, Howard Paul
Synthetic Wastewater Treatment Using Agro-Based Adsorbents, Saisantosh Vamshi Harsha Madiraju, Yung-Tse Hung, Howard Paul
Civil and Environmental Engineering Faculty Publications
This study was undertaken to determine the treatment a binary mixture of dye wastewater (containing Naphthol Green B) and the sugar industry wastewater for removal of color. The specific treatment in the current research consists of adsorption using low-cost adsorbents and microfiltration using Whatman-41 microfilters. Considerations of this treatment process are to take the samples using batch adsorption and avoid coagulation with further dilution. Numerous runs are made, with the ideal waste samples prepared in the laboratory. As a 1st step in the study, different dye concentrations are considered using different concentrations of sugar wastewater. Samples are treated with 3 …
Treatment Of Combined Acid Black 48 And Coffee Wastewater By Low-Cost Adsorbents, Yung-Tse Hung
Treatment Of Combined Acid Black 48 And Coffee Wastewater By Low-Cost Adsorbents, Yung-Tse Hung
Civil and Environmental Engineering Faculty Publications
© 2020, Kaunas University of Technology. All rights reserved. Removal of synthetic dyes from wastewater is essential both from the environmental and human health point of view. A small concentration of synthetic dyes can reduce water transparency and consequently influence photosynthesis and alter aquatic ecosystems. Acid black 48 is an Azo dye that falls under the category of synthetic dyes used in the textile industry. With dyes, coffee wastewater has high chemical oxygen demand (COD) that can affect dissolved oxygen (DO) in surface waters. A mixture of wastes in surface waters creates a need to investigate the efficiency of existing …
Color Removal From Combined Dye And Fruit Nectar Wastewater Using Adsorption And Microfiltration, Oluwatobiloba A. Akinwande
Color Removal From Combined Dye And Fruit Nectar Wastewater Using Adsorption And Microfiltration, Oluwatobiloba A. Akinwande
ETD Archive
Pollution of the waterways is a great challenge of the 21st century. Textile effluents contain compounds which have the capacity to cause more harm when ingested. There are many dye removal technologies like coagulation, photo oxidation which help to remove color from dye wastewater. The use of adsorption to remove color from dye wastewater has been used for many centuries. Activated carbon can efficiently remove color from dye wastewater but it is very expensive and so different researches have been conducted to get the adsorption capacity of different forms of adsorbents. These adsorbents can be gotten from agricultural waste, biomass, …
Color Removal And Treatment Of Dye And Sugar Waste Water Using Low Cost Adsorbents, Saisantosh Vamshi Harsha Madiraju
Color Removal And Treatment Of Dye And Sugar Waste Water Using Low Cost Adsorbents, Saisantosh Vamshi Harsha Madiraju
ETD Archive
This study was undertaken to determine the treatment of wastewater from dye and sugar industry for removal of color. This specific treatment consists of adsorption using low cost adsorbents and micro filtration using whatman-41 micro filters. Considerations of this treatment process is to take the samples using batch adsorption and avoid coagulation with further dilution. Numerous runs were made with the ideal waste samples prepared in the laboratory. As a first step in the study different dyes were considered using different concentrations of sugar wastewater. Samples were treated with three different low-cost adsorbents. These treated samples using low cost adsorbents …
Color Removal Of Dye And Milk Wastewater Using Peanut Hull By The Process Of Adsorption, Venkatesh Kummarakuntla
Color Removal Of Dye And Milk Wastewater Using Peanut Hull By The Process Of Adsorption, Venkatesh Kummarakuntla
ETD Archive
Dairy industry is one of the major industries from which organic wastewater is produced and released into the water bodies. Textile industries also generate considerable amount of dye wastewater that effect the water quality standards. Various treatment techniques are adopted to treat the wastewater. Adsorption is one of the low-cost treatment processes to treat the textile and milk wastewater. This thesis focuses on the treatment of combined dye and milk wastewater using the process of adsorption. The treatment process is carried out by using three different types of low cost adsorbents Peanut-hull, Banana peel and Activated carbon. The effectiveness of …
Treatment Of Dye Wastewater Using Dehydrated Peanut Hull, Nikitha Shamirpet
Treatment Of Dye Wastewater Using Dehydrated Peanut Hull, Nikitha Shamirpet
ETD Archive
The release of dye waste water into environment causes harm to aquatic life when they reach drains or other water sources. They pollute the soil and causes change in cycles of plant and animal life through bio-accumulation and nutrient cycle. Dyes which form residue or precipitate causes mutations or changes in the DNA of living organisms in and around the area of release of the dye into atmosphere. In this thesis, several runs were attempted to treat the synthetically prepared dye waste water using dehydrated peanut hull. The initial dye waste water samples were all collected and checked for absorbance, …
Effect Of History On The Binary Adsorption Equilibria Of Aluminium Terephthalate (Mil-53(Al)), Ufuoma Israel Kara
Effect Of History On The Binary Adsorption Equilibria Of Aluminium Terephthalate (Mil-53(Al)), Ufuoma Israel Kara
ETD Archive
Metal organic frameworks (MOFs) are highly porous solids with potential applications in a wide range of fields including gas separations and catalysis. Most of porous solids used in these applications such as zeolites and activated carbon usually have rigid structures. In contrast, a number of metal-organic frameworks (MOFs) exhibit structural transformation in response to external stimuli. Such materials show promise for applications such as sensors, actuators and adsorptive separations. Several thermodynamic formalisms were proposed in literature to explain this phenomenon, often known as gate-opening or “breathing” of the MOF material. In this study, the adsorptive behavior of MIL-53(Al), a MOF …
Adsorption And Microfiltration Processes To Treat Dye And Coffee Wastewater., Abhiram Siva Prasad Pamula
Adsorption And Microfiltration Processes To Treat Dye And Coffee Wastewater., Abhiram Siva Prasad Pamula
ETD Archive
Wastewater from coffee processing industry creates high biological and chemical oxygen demand in the surface water. In addition to coffee wastewater from coffee industry, dyes from textile industry enter surface water affecting water quality in terms of transmissivity of light. Adsorption is an economical wastewater treatment process to remove color from dye and coffee wastewater. In the current thesis, adsorption using low-cost adsorbents like peanut hull and onion peel are used to treat combined dye and coffee wastewater. Three representative dyes including acid black 48, disperse yellow 3, crystal violet certified with processed coffee is used in preparing batch adsorption …
Pure And Binary Adsorption Equilibrium Of Nitrogen And Oxygen In Lilsx Zeolite, Himabindu Gandra
Pure And Binary Adsorption Equilibrium Of Nitrogen And Oxygen In Lilsx Zeolite, Himabindu Gandra
ETD Archive
Chemical products are made by combination of processes that includes synthesis, separation and purification. Separation processes comprises a large portion in these industries and are considered to be critical as most of the applications in chemical industries involves mixtures. Traditional separation methods such as distillation, evaporation, drying etc., requires high energy. For example, air separation to produce nitrogen and oxygen was previously practiced by cryogenic distillation that involves high pressure units and large energy requirement. On other hand, adsorption processes utilize less energy resources and is unique among separation methods. The phase separation is achieved by the existence of a …
Evaluation Of Mass Transfer Rate In Column Of Small Lilsx Particles, Mihikumar S. Patel
Evaluation Of Mass Transfer Rate In Column Of Small Lilsx Particles, Mihikumar S. Patel
ETD Archive
Air separation using zeolite based adsorption processes is a widely-studied topic. Proper process modeling is a key requirement to simulate the process. Conventional process modeling for air separation is designed for large scale adsorption processes using a long cycle time. However, advanced technology now permits to use of a short cycle time using small particles, which significantly reduces the size of the process.
Traditional process models were mostly developed for large particles (dp > 1.5 mm). Typically, it is safely assumed that intra particle diffusion controls the rate of the process while axial dispersion has a much smaller effect. This is …
Pure And Binary Adsorption Of Methane And Nitrogen On Silicalite, Prahar S. Vaidya
Pure And Binary Adsorption Of Methane And Nitrogen On Silicalite, Prahar S. Vaidya
ETD Archive
Separation processes comprise a large portion of the activity in the chemical and petrochemical industries. For the chemical, petroleum refining, and materials processing industries as a group, separation processes are considered to be critical. Almost all the applications of chemical industries involves mixtures, so innovation in separation technology not only enhances productivity and global competitiveness of U.S. industries, but is also critical for achieving the industrial energy and waste reduction goals. Traditionally, air separation to produce nitrogen and oxygen and to separate nitrogen from methane was practiced by cryogenic distillation, which involved expensive high pressure units and large requirement of …
A Psa Process For An Oxygen Concentrator, Aaron A. Moran
A Psa Process For An Oxygen Concentrator, Aaron A. Moran
ETD Archive
Oxygen is used in a variety of chemical processes and for medical purposes throughout the world. Pressure swing adsorption (PSA) has become a viable alternative to cryogenic distillation for the separation of oxygen from air with the development of advanced adsorbents like zeolites. PSA processes are inherently complex because it is a dynamic process. Efficient operation of a PSA process is necessary in order to utilize the capacity of the adsorbent as much as possible and reduce the power requirements of the process.In this thesis, a novel zeolite adsorbent was utilized in a PSA process for oxygen generation with the …
Pure Component Adsorption Of Methane, Ethylene, Propylene And Carbon Dioxide In Silicalite, Qianqian Zhou
Pure Component Adsorption Of Methane, Ethylene, Propylene And Carbon Dioxide In Silicalite, Qianqian Zhou
ETD Archive
Adsorption isotherms are measured for pure methane, ethylene, propylene and carbon dioxide in silicalite. Isotherm data are collected using a volumetric method at three different temperatures of 10C, 35C and 65C at pressure up to 100psi. The Virial equation and Langmuir equation have been applied to represent excess amount adsorbed in each pure component system. The binary adsorption equilibrium for various mixtures are predicted from the pure component adsorption data, using the Ideal Adsorption Solution Theory (IAST)
The Effectiveness Of Silica Sand In Semi-Aerobic Stabilized Landfill Leachate Treatment, Ezlina Othman, Mohd Suffian Yusoff, Hamidi Abdul Aziz, Mohd Nordin Adlan, Mohammed J.K. Bashir, Yung Tse Hung
The Effectiveness Of Silica Sand In Semi-Aerobic Stabilized Landfill Leachate Treatment, Ezlina Othman, Mohd Suffian Yusoff, Hamidi Abdul Aziz, Mohd Nordin Adlan, Mohammed J.K. Bashir, Yung Tse Hung
Civil and Environmental Engineering Faculty Publications
© 2010 by the authors. This study examines the suitability of natural silica sand as a low-cost adsorbent for the removal of ammoniacal nitrogen and heavy metals, particularly iron and zinc, from semi-aerobic stabilized landfill leachate. Leachate samples were collected from the Pulau Burung landfill site (PBLS) in Penang, Malaysia. The above-mentioned contaminants are highlighted in this study because of their unsafe concentrations at PBLS. The effects of shaking time, settling time, and silica sand dosage on the study parameter removal efficiencies were investigated to predict the performance of the process. The adsorptions of ammoniacal nitrogen, iron, and zinc were …
Doug Ruthven And Jorg Karger: Their Individual And Collective Contributions To The Field Of Zeolite Science And Engineering, Dhananjai B. Shah
Doug Ruthven And Jorg Karger: Their Individual And Collective Contributions To The Field Of Zeolite Science And Engineering, Dhananjai B. Shah
Chemical & Biomedical Engineering Faculty Publications
Prof. Doug Ruthven and Prof. Jörg Kärger are two giants in the field of zeolite science and engineering. Over their academic careers encompassing almost forty years each, they have contributed significantly to the advancement of fundamental understanding of adsorption and diffusion in zeolites as well as their industrial applications. The author, in the beginning of his academic career, had an opportunity to spend two years as a post-doctoral fellow in Prof. Ruthven’s laboratory at the University of New Brunswick (1975–1977). This experience actually motivated me to spend my academic career in working in the field of zeolite adsorption and …
Equilibrium Studies And Kinetics Mechanism For The Removal Of Basic And Reactive Dyes In Both Single And Binary Systems Using Edta Modified Rice Husk, Siew-Teng Ong, Weng-Nam Lee, Pei-Sin Keng, Yung-Tse Hung, Sie-Tiong Ha
Equilibrium Studies And Kinetics Mechanism For The Removal Of Basic And Reactive Dyes In Both Single And Binary Systems Using Edta Modified Rice Husk, Siew-Teng Ong, Weng-Nam Lee, Pei-Sin Keng, Yung-Tse Hung, Sie-Tiong Ha
Civil and Environmental Engineering Faculty Publications
The potential of using ethylenediamine tetraacetic acid modified rice husk (ERH) to remove different types of dyes, namely basic and reactive dyes were studied. Sorption characteristic of ERH showed that it was pH dependent. The kinetics of sorption for both dyes was rapid within the first 60 min regardless of its initial concentration. Using the pseudo-second order kinetics model, the predicted uptakes of Methylene Blue (MB) and Reactive Orange 16 (RO16) agreed closely with experimental values obtained. Three isotherm models were used to fit with equilibrium data, namely Langmuir, Freundlich and BET models. It was found that the equilibrium fitted …
Tartaric Acid Modified Rice Hull As A Sorbent For Methylene Blue Removal, Siew Teng Ong, Pei Sin Keng, Ai Wen Chong, Siew Ling Lee, Yung Tse Hung
Tartaric Acid Modified Rice Hull As A Sorbent For Methylene Blue Removal, Siew Teng Ong, Pei Sin Keng, Ai Wen Chong, Siew Ling Lee, Yung Tse Hung
Civil and Environmental Engineering Faculty Publications
Problem statement: Improper dye discharge from various industries such as textile, paper, cosmetic and plastics into receiving streams can be one of the sources towards water pollution. The release of these effluents not only causes various disruptions in the ecosystems, but also poses hazard effect as most of the dyes are highly toxic, mutagenic and carcinogenic in nature. Approach: To prepare an inexpensive and efficient sorbent by chemically modifying rice hull for the removal of Methylene Blue (MB) which is predominantly used in coloring acrylic fiber. Batch experiments were carried out for the removal of MB from aqueous solution by …
Adsorption Of Lactic Acid From Fermentation Broth And Aqueous Solutions On Zeolite Molecular Sieves, Isam H. Aljundi, Joanne M. Belovich, Orhan Talu
Adsorption Of Lactic Acid From Fermentation Broth And Aqueous Solutions On Zeolite Molecular Sieves, Isam H. Aljundi, Joanne M. Belovich, Orhan Talu
Chemical & Biomedical Engineering Faculty Publications
The recovery of lactic acid from fermentation broth and aqueous solutions was studied by adsorption on Silicalite molecular sieves. Batch experiments were used to measure the adsorption isotherms of the lactic acid on Silicalite. A linear correlation was found for both solutions. Silicalite showed a higher adsorptive capacity in the case of the aqueous solution than that of the fermentation broth. Henry’s constants were estimated as Formula Not Shown and Formula Not Shown for the aqueous and broth solutions, respectively. The effect of temperature on adsorption was also studied in batch mode. Henry’s constant dependency on …
Activity Coefficients Of Adsorbed Mixtures, Orhan Talu, Jianmin Li, Alan L. Myers
Activity Coefficients Of Adsorbed Mixtures, Orhan Talu, Jianmin Li, Alan L. Myers
Chemical & Biomedical Engineering Faculty Publications
Experimental and simulated data for adsorption of gas mixtures on energetically heterogeneous surfaces like activated carbon and zeolites exhibit negative deviations from ideality. The deviations are large in some cases, with activity coefficients at infinite dilution equal to 0.1 or less. Similar molecules form ideal mixtures, but molecules of different size or polarity are nonideal. Equations for bulk liquid mixtures (Wilson, Margules, etc.) do not apply to isobars for adsorbed mixtures. A two-constant equation for activity coefficients as a function of composition and spreading pressure is in good agreement with theory, simulation, and experiment.