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Full-Text Articles in Engineering
Iron Phosphate Glass For The Immobilization Of Dehalogenated Salt Waste, Matthew Aaron Page
Iron Phosphate Glass For The Immobilization Of Dehalogenated Salt Waste, Matthew Aaron Page
All Theses
Electrochemical reprocessing can be used to recycle presently stored nuclear fuel and consists of dissolving that used fuel in molten salt and the waste produced from these processes is a small amount of a high-level salt waste. Vitrification has been selected as the primary means of safely disposing high and low level radioactive waste. This is due to glass’ ability to incorporate many elements within its matrix, and it is chemically durable with the addition of network formers and other glass forming chemicals. With over 90,000 tonnes of nuclear waste in the United States, the avoidance of additional steps required …
Investigation Into Mechanisms And Mitigation Of Alkali-Silica Reaction In Sustainable Portland Cement Concrete Containing Recycled Glass Materials, Kaveh Afshinnia
Investigation Into Mechanisms And Mitigation Of Alkali-Silica Reaction In Sustainable Portland Cement Concrete Containing Recycled Glass Materials, Kaveh Afshinnia
All Dissertations
A significant portion of recycled glass from municipal waste streams is not found to be suitable for reuse as cullet in the production of new glass containers, and as a result it is disposed in landfills. One of the appropriate ways to reduce the disposal of waste glass in landfills is by using it in portland cement concrete as an aggregate material and/or supplementary cementitious material to replace portion of portland cement. The high silica content of the soda glass (approximately 70%) can potentially behave as a pozzolanic material when finely ground, which may enhance the mechanical and durability properties …
Designing Optical Properties In Infrared Glass, Benn Gleason
Designing Optical Properties In Infrared Glass, Benn Gleason
All Dissertations
Chalcogenide glasses (ChGs) are well-known for their attractive optical properties, such as high refractive index and transparency in across infrared wavelengths. ChGs also possess the ability to compositionally tune properties such as the refractive index, the thermo-optic coefficient, and other non-optical properties. Chalcogenide glasses with compositionally tailored physical and optical properties will provide optical designers with new materials necessary to create novel infrared imaging systems requiring new or expanded functionality. This dissertation has evaluated the relationship between glass composition, the resulting atomic structure, and resulting optical and thermo-optical properties, with specific focus on the infrared refractive index and the thermo-optic …
Elaboration And Optimization Of Tellurite-Based Materials For Raman Gain Application, Guillaume Guery
Elaboration And Optimization Of Tellurite-Based Materials For Raman Gain Application, Guillaume Guery
All Dissertations
Tellurite-based oxide glasses have been investigated as promising materials for Raman gain applications, due to their good linear and nonlinear optical properties and their wide transparency windows in the near- and midwave infrared spectral region. Furthermore, their interesting thermal properties, i.e. low glass transition temperature and ability to be drawn into optical fibers, make tellurite-based glasses excellent candidates for optical fiber amplifiers. The estimation of the strength and spectral distribution of Raman gain in materials is commonly approximated from the spontaneous Raman scattering cross-section measurement. For development of tellurite-based glasses as Raman amplifiers, understanding the relationship between glass structure, vibrational …
Optimization Of Processing Parameters For As2se3 Glass For Low Loss, High Strength Fibers, Baptiste Giroire
Optimization Of Processing Parameters For As2se3 Glass For Low Loss, High Strength Fibers, Baptiste Giroire
All Theses
Chalcogenide glasses have been widely studied due to their extraordinary transparency in the infrared (IR) region from 0.5 to 20 μm. This transparency combined with excellent thermo-mechanical properties, makes them ideal candidate for infrared optics including IR fiber optic applications. However, such non-oxide glasses generally exhibit low mechanical strength, as compared to their oxide counterpart, which are based on covalently bonded metal-oxygen species. In addition to mechanical robustness, low optical loss (hence low impurity content) is required for most IR optical materials, including the one in this study, amorphous arsenic tri-selenide, As2Se3. In this effort, As2Se3 glass was investigated and …
Nanoparticles In Solution-Derived Chalcogenide Glass Films, Spencer Novak
Nanoparticles In Solution-Derived Chalcogenide Glass Films, Spencer Novak
All Theses
The results in this thesis are from our efforts to modify the optical properties of solution-derived chalcogenide glass films by the incorporation of nanomaterials. First, the composition Ge23Sb7S70 was selected as the appropriate glass matrix for testing because solution-derived films of this composition have been well-studied in our group. Additionally, this composition was found to be less sensitive to certain processing parameters than As2S3, another well-studied, candidate chalcogenide glass composition, making Ge23Sb7S70 more suitable for the addition of nanomaterials. Optimization of film process parameters was performed to obtain high-quality films appropriate for doping with nanomaterials. This consisted of determining the …
Characterization And Optimization Of Solution-Derived Chalcogenide Glass Thin Films, Jacklyn Wilkinson
Characterization And Optimization Of Solution-Derived Chalcogenide Glass Thin Films, Jacklyn Wilkinson
All Theses
Chalcogenide glasses have many unique properties that allow them to be used in a variety of optical applications. Infrared transparency allows them to be used in sensors for molecules that have 'fingerprints' in the 2-25 μm range. By producing amorphous thin films of these materials, they can be incorporated into chemical sensors as planar waveguides and resonators. The goal of this work was to fabricate and characterize solution-derived chalcogenide thin films for use in chemical sensors with a source wavelength between 3-3.5 μm.
The structural and optical properties of the parent bulk glass were characterized and used as reference for …
Multi-Length Scale Modeling Of The High-Pressure, Large-Strain, High-Strain-Rate Response Of Soda-Lime Glass, William Bell
Multi-Length Scale Modeling Of The High-Pressure, Large-Strain, High-Strain-Rate Response Of Soda-Lime Glass, William Bell
All Dissertations
Development of new transparent armor systems is essential for the protection of the current and future US armed forces, especially in light of the recent military operations The Operation Iraqi Freedom in Iraq and The Operation Enduring Freedom in Afghanistan. These conflicts have introduced a new military theater without a well-defined battle front and new types of threats (e.g. improvised explosive devices, IEDs). Development and modeling of new transparent armor systems for use in numerous applications from vehicle windows to face shields is a current area of thrust aimed at addressing the shortcomings of existing systems in order to better …
Stress Relaxation Of Glass Using A Parallel Plate Viscometer, Guy-Marie Vallet
Stress Relaxation Of Glass Using A Parallel Plate Viscometer, Guy-Marie Vallet
All Theses
Currently, grinding and polishing is the traditional method for manufacturing optical glass lenses. However, for a few years now, precision glass molding has gained importance for its flexibility in manufacturing aspheric lenses. With this new method, glass viscoelasticity and more specifically stress relaxation are important phenomena in the glass transition region to control the molding process and to predict the final lens shape.
The goal of this research is to extract stress relaxation parameters in shear of Pyrex¨ glass by using a Parallel Plate Viscometer (PPV). The PPV machine was originally created to measure the viscosity of glass solid cylinders …
Identifying The Optimum Process Parameters Of Precision Glass Molding For Aspherical Lenses, Waqas Iqbal
Identifying The Optimum Process Parameters Of Precision Glass Molding For Aspherical Lenses, Waqas Iqbal
All Theses
The purpose of this research is to determine the optimum process parameters for the Precision Glass Molding (PGM) Process using Manufacturing Design, Design of Experiments and Metrology (for measuring the geometry of lenses). First, a custom machine is designed and manufactured which can carry out Precision Glass Lens Molding Experiments. This machine is then modified to improve temperature, position and force control. A literature review is performed to obtain data for process parameters that have been used in previous PGM studies. The collected data is then used in Design of Experiments to create twenty seven experiments that determine the optimum …
Development, Parameterization And Validation Of Dynamic Material Models For Soil And Transparent Armor Glass, Bhaskar Pandurangan
Development, Parameterization And Validation Of Dynamic Material Models For Soil And Transparent Armor Glass, Bhaskar Pandurangan
All Dissertations
Despite the signing of several mine ban treaties in the 1990's, it is widely recognized that there is a landmine crisis. The following are some of the main aspects of this crisis: (a) Millions of unexploded landmines remain deployed all over the world; (b) Thousands of civilians are killed or maimed every year by unintended detonations of the mines; (c) The cost of medical treatment of landmine injuries runs into the millions; (d) the ability of the international community to provide the humanitarian relief in terms of medical services, safe drinking water and food, etc., is greatly hampered by landmine …