Engineering Commons^™

Tools And Strategies For The Patterning Of Bioactive Molecules And Macromolecules, Daniel J. Valles

Dissertations, Theses, and Capstone Projects

Hypersurface Photolithography (HP) is a printing method for fabricating structures and patterns composed of soft materials bound to solid surfaces and with ~1 micrometer resolution in the x, y, and z dimensions. This platform leverages benign, low intensity light to perform photochemical surface reactions with spatial and temporal control of irradiation, and, as a result, is particularly useful for patterning delicate organic and biological material. In particular, surface- initiated controlled radical polymerizations can be leveraged to create arbitrary polymer and block- copolymer brush patterns. Chapter 1 will review the advances in instrumentation architectures from our group that have made these …

Molecular Dynamics Simulations Of Self-Assemblies In Nature And Nanotechnology, Phu Khanh Tang

Dissertations, Theses, and Capstone Projects

Nature usually divides complex systems into smaller building blocks specializing in a few tasks since one entity cannot achieve everything. Therefore, self-assembly is a robust tool exploited by Nature to build hierarchical systems that accomplish unique functions. The cell membrane distinguishes itself as an example of Nature’s self-assembly, defining and protecting the cell. By mimicking Nature’s designs using synthetically designed self-assemblies, researchers with advanced nanotechnological comprehension can manipulate these synthetic self-assemblies to improve many aspects of modern medicine and materials science. Understanding the competing underlying molecular interactions in self-assembly is always of interest to the academic scientific community and industry. …

Space Opens Its Doors To Unexpected Players, One Of Them Paraguay, Macarena Carrizosa

Capstones

Paraguay successfully sent its first native satellite into orbit in 2021, proving how essential and accessible the industry has become, even for developing countries. This article looks at how knowledge and technology transfer programs combined with a lower cost of entry helped Paraguay reach its first major milestone in the space industry, having its own satellite.

The Impact Of User Control And Transparency In App Design On Privacy Concerns And Behavior Of Mobile App Users, Arwa Alawajy

Dissertations, Theses, and Capstone Projects

Mobile apps have unprecedented access to sensitive personal information. The increasing commodification of mobile-user data motivates us to explore the vital role of app developers in protecting users’ privacy. This dissertation examines the privacy of mobile app users from the perspective of HCI. According to Communication Privacy Management (CPM) theory, people believe they own their personal information and have the right to control how or with whom they share this information. In practice, individuals manage their privacy system and the boundaries between the public and private domain. Users make privacy disclosure decisions according to their individual characteristics and the perceptions …

Efficient Protocols For Multi-Party Computation, Tahereh Jafarikhah

Dissertations, Theses, and Capstone Projects

Secure Multi-Party Computation (MPC) allows a group of parties to compute a join function on their inputs without revealing any information beyond the result of the computation. We demonstrate secure function evaluation protocols for branching programs, where the communication complexity is linear in the size of the inputs, and polynomial in the security parameter. Our result is based on the circular security of the Paillier's encryption scheme. Our work followed the breakthrough results by Boyle et al. [9; 11]. They presented a Homomorphic Secret Sharing scheme which allows the non-interactive computation of Branching Programs over shares of the secret inputs. …

Applying Deep Learning On Financial Sentiment Analysis, Cuiyuan Wang

Dissertations, Theses, and Capstone Projects

Portfolio Investment has always been appealing to investors and researchers. In the past, people tend to use historical trading information of the securities to predict the return or manage the portfolio. Nowadays, the literature has been proved that the market sentiment could predict asset prices. Specifically, it has been shown that the stock market movement is related to financial news and social media events. Thus, it becomes necessary to extract the sentiment of the financial news. We explicitly introduce the application of dictionary methods, traditional machine learning models and deep learning models on text classification. The experiment results show that …

The Legacy Of Car-Share And Light-Rail Transit For Mobility And Accessibility Improvements In Economically Marginalized Neighborhoods In The New York Metro Area, Kyeongsu Kim

Dissertations, Theses, and Capstone Projects

This dissertation explores the value of the car-share program and a new light rail system with respect to their impact on mobility and accessibility improvements in economically and transportation access-wise marginalized neighborhoods in NYC and its adjacent communities. It consists of three main essays that took deep dives into how each new service or system altered mobility or accessibility for those in need. The first essay (Chapter 2) investigates car-share vehicle utilization rates of the Zipcar across NYC. It assesses the utilization rates by vehicle type, service location, time period, and weekday usage compared to weekend activity. With a multivariate …

Blockchain-Based Architecture For Secured Cyberattack Signatures And Features Distribution, Oluwaseyi J. Ajayi

Dissertations and Theses

One effective way of detecting malicious traffic in computer networks is intrusion detection systems (IDS). Despite the increased accuracy of IDSs, distributed or coordinated attacks can still go undetected because of the single vantage point of the IDSs. Due to this reason, there is a need for attack characteristics' exchange among different IDS nodes. Another reason for IDS coordination is that a zero-day attack (an attack without a known signature) experienced in organizations located in different regions is not the same. Collaborative efforts of the participating IDS nodes can stop more attack threats if IDS nodes exchange these attack characteristics …

When The Brain Plays A Game: Neural Responses To Visual Dynamics During Naturalistic Visual Tasks, Jason Ki

Dissertations and Theses

Many day-to-day tasks involve processing of complex visual information in a continuous stream. While much of our knowledge on visual processing has been established from reductionist approaches in lab-controlled settings, very little is known about the processing of complex dynamic stimuli experienced in everyday scenarios. Traditional investigations employ event-related paradigms that involve presentation of simple stimuli at select locations in visual space and discrete moments in time. In contrast, visual stimuli in real-life are highly dynamic, spatially-heterogeneous, and semantically rich. Moreover, traditional experiments impose unnatural task constraints (e.g., inhibited saccades), thus, it is unclear whether theories developed under the reductionist …

Molecular-Level Understanding Of Ionic & Electronic Charge Storage Mechanisms In Rechargeable Aluminum Batteries Using Sold-State Nmr, Ankur Lahanu Jadhav

Dissertations and Theses

Rechargeable aluminum-ion batteries are safe and low-cost alternatives to traditional lithium-ion batteries due to the high volumetric capacity (8040 mAh/cm³) of aluminum. However, very few electrode materials have shown reversible aluminum ion intercalation. Intercalation Al³⁺ ions in these structures leads to poor capacity retention, mainly due to slow solid-state diffusion of the highly charged tri-valent aluminum ions within these crystalline structures. In 2015, aluminum ions were shown to reversibly intercalate/de-intercalate into the Chevrel Mo₆S₈ phase, though the intercalation mechanism is not well understood. Alternatively, molecular chloroaluminate ions within the ionic liquid electrolyte have also …

Analyzing Freight Congestion And Transportation Performance Measures Using The National Performance Management Research Data Set (Npmrds), Yaxin Zhang

Dissertations and Theses

Traffic congestion is common in urban areas. It results in loss of productivity, increased risk of passenger safety, increased fuel consumption, environment pollution, etc. Improving performance measurement is a tool to improve traffic flow and capacity planning.

The main data source in this research is the National Performance Management Research Data Set (NPMRDS) for 2018. NPMRDS is a form of commercial GPS probe data, obtained from vehicles with on-board probe technologies. This dataset is licensed by the Federal Highway Administration and is made available to State Departments of Transportation (DOTs) and Metropolitan Planning Organizations (MPOs) for the purpose of federally …

Restoration Of Bone Material And Microstructural Properties After Long-Term Remodeling Suppression, Abigail A. Coffman

Dissertations and Theses

Anti-resorptive drugs, principally bisphosphonates (BPs), are the mainstay of osteoporosis treatment. They work by inhibiting bone resorption/remodeling, thus preventing bone loss. However, long-term suppression of bone resorption adversely affects bone tissue mechanical properties, even while conserving bone mass. Lack of remodeling leads to accumulation of fatigue-induced microdamage, altered matrix mineralization and reduction in normal bone tissue heterogeneity, causing impaired strength and fracture toughness. The most severe consequence to patients, while rare, is Atypical Femur Fractures (i.e., complete fatigue fractures of the femoral shaft). To counteract the effects of long-term remodeling suppression, a temporary break in BP treatment (a "drug holiday) …

Development Of A Biaxial Testing System For Research Of Soft Tissue Biomechanics Using Laboratory Models, Tariq Shameen

Dissertations and Theses

The rupture of the cap tissue layer of a fibroatheroma in human coronary vessels is considered the key event leading to the formation of a thrombus and myocardial infarction, resulting in more than half a million deaths in the US every year. In this study, we are interested in investigating the biomechanics of different elastomer materials that can be used as laboratory models to replicate coronary arteries’ ultimate tensile stress (0.2 - 2.08 MPa). To this end, we developed a biomechanical testing system that allows us to characterize the material properties of small samples with high accuracy and precision. We …

Investigating The Effect Of Electrolyte Concentration And Charging Protocol On Materials Utilization In Rechargeable Zinc Manganese Dioxide Batteries, Snehal H. Kolhekar

Dissertations and Theses

Achieving a highly cyclable, high energy density battery with MnO₂ cathodes encounters many obstacles. Chief among these is the inability of the widely-used γ-MnO₂ polymorph to retain its structural integrity when cycled to near full one-electron discharge capacity, which is about 280mAh/g for commercially available electrolytic manganese dioxide (EMD). In this one-electron range, discharge occurs by proton insertion producing Mn⁺³ which then reverts to γ-MnO₂ on charging. In the first part of the thesis, we investigate the root cause of failure of MnO₂ cathodes under deep cycling in the one-electron discharge range and establish a …

Osteocyte Activity And Skeletal Muscle Relative Gene Expression Profiling After Short-Term Muscle Paralysis, Michelle Gelbs

Dissertations and Theses

Mechanical loading is essential for maintaining bone tissue. Reduced mechanical loading has been shown to have a negative effect on bone, and can result in the development of disuse osteoporosis. Disuse models of muscle inactivity and immobilization, like the Botox model used in this study, result in changes in the bone microarchitecture, the mechanisms behind which are not fully understood. In a previous four-week Botox disuse study, skeletally mature 20- week-old rats experienced degradation of intracortical bone, increased vascular porosity, and decreased osteocyte lacunar density in the tibiae. The focus of this study was to explicate a potential source of …

A New Mathematical Theory For The Dynamics Of Large Tumor Populations, A Potential Mechanism For Cancer Dormancy & Recurrence And Experimental Observation Of Melanoma Progression In Zebrafish, Adeyinka A. Lesi

Dissertations and Theses

Cancer, a family of over a hundred disease varieties, results in 600,000 deaths in the U.S. alone. Yet, improvements in imaging technology to detect disease earlier, pharmaceutical developments to shrink or eliminate tumors, and modeling of biological interactions to guide treatment have prevented millions of deaths. Cancer patients with initially similar disease can experience vastly different outcomes, including sustained recovery, refractory disease or, remarkably, recurrence years after apparently successful treatment. The current understanding of such recurrences is that they depend on the random occurrence of critical mutations. Clearly, these biological changes appear to be sufficient for recurrence, but are they …

Coordinated Control For Dc Energy Hubs Involving Ders, Evs, And Subway Systems, Rohama Ahmad

Dissertations and Theses

No abstract provided.

Development Of Light Actuated Chemical Delivery Platform On A 2-D Array Of Micropore Structure, Hojjat Rostami Azmand, Hojjat Rostami Azmand

Dissertations and Theses

Localized chemical delivery plays an essential role in the fundamental information transfers within biological systems. Thus, the ability to mimic the natural chemical signal modulation would provide significant contributions to understand the functional signaling pathway of biological cells and develop new prosthetic devices for neurological disorders. In this paper, we demonstrate a light-controlled hydrogel platform that can be used for localized chemical delivery in a high spatial resolution. By utilizing the photothermal behavior of graphene-hydrogel composites confined within micron-sized fluidic channels, patterned light illumination creates the parallel and independent actuation of chemical release in a group of fluidic ports. The …

Structural Robustness Of Long-Span Cable-Supported Bridges, Qian Chen

Dissertations and Theses

As a critical part of the current infrastructure system, long-span bridges are directly exposed to adverse environments, such as floods, scours, hurricanes, etc., and dynamic loads such as earthquakes and vehicular impacts. Additionally, recent long-span cable-supported collapse examples show that many bridges suffered progressive collapse when local damage occurred, and they are highly vulnerable to severe damages in the event of a localized failure. However, the traditional design approaches are unable to provide explicit measures of residual safety of bridges, especially after an abnormal event. Currently available redundancy and robustness evaluation approaches, which were developed mainly for short-span bridges, are …

Molecular To Macroscopic Understanding Of Chloroaluminate Anion Intercalation In Rechargeable Aluminum-Graphite Batteries, Jeffrey Xu

Dissertations and Theses

Today’s global energy challenges pose an urgent need to electrify transportation and better store intermittent renewable energy sources (e.g., solar and wind energy). For such large-scale battery applications, aluminum batteries are a promising “beyond lithium-ion” technology due to the high volumetric capacity, earth abundance, low-cost, and inherent safety of aluminum metal. However, there are very few compatible positive electrode materials that exhibit high energy density and cycling stability, in part due to the challenges of electrochemically intercalating highly charged Al³⁺ cations. Recently, graphite has been demonstrated as a promising positive electrode material in non-aqueous rechargeable aluminum batteries, which store …

Understanding The Effect Of Climate And Hydrometeorological Extremes On Natural And Human-Induced Hydrosystems, Jeongwoo Hwang

Dissertations and Theses

The contemporary hydrosystems of the United States involve a complex combination of natural and modified basins in the presence of changing climate and anthropogenic impacts. An enhanced understanding of the interdependence between climate forcings, human-induced interventions, and water balance in both natural and modified basins are essential for developing reliable and resilient hydrosystems and for better water resources management. In response, this dissertation focuses on investigating the hydroclimatology of natural and modified basins across the contiguous United States. It has three research objectives: (1) to explain flow alterations due to anthropogenic activities, especially dam operations, in modified basins and understand …

Control Hierarchies For Critical Infrastructures In Smart Grid Using Reinforcement Learning And Metaheuristic Optimization, Oindrilla Dutta

Dissertations and Theses

The objective of this work is to develop robust control framework for interdependent smart grid infrastructures comprising two critical infrastructures: 1) power distribution networks that are characterized by high penetration of distributed energy resources (DERs), and 2) DC-rail transportation systems in congested urban areas. The rising integration of DERs into the power grid is causing a paradigm shift in the power distribution network. Consequently, new control challenges for efficient and robust operation of the power grid have surfaced. For instance, the intermittency of renewable energy resources necessitates coordinated control of power flows, voltage regulators, and protection device settings of the …

Voltage Security Optimization For Power Transmission Systems, Tamer Ibrahim

Dissertations and Theses

This project proposes an optimization approach for day-ahead reactive power planning to ensure voltage security in transmission networks. The problem is formulated as a voltage-secure multi-period optimal reactive power dispatch (MP-ORPD) problem. The optimization approach searches for optimal set-points of dynamic and static reactive power (var) resources. Specifically, the output includes set-points for switching shunts, transformer taps, and voltage magnitudes at the regulated buses. The primary goal is to maximize the dynamic reactive power reserve of the system, by minimizing the reactive power supplied by synchronous generators. The secondary goal is to minimize changes in the settings of switching shunts …

On The Improvements Of Boundary-Layer Representation For High Resolution Weather Forecasting In Costal-Urban Environments, David Melecio-Vazquez

Dissertations and Theses

As large urban centers around the world become more densely populated, the global conversion from natural to man-made land surfaces will only increase. These land-use changes affect the urban surface energy budget which in turn changes the structure of the planetary boundary layer (PBL) above. With current high-performance computing systems, meteorological and built environment information can be better utilized to quantify the anthropogenic effects of these modifications. Although these systems have improved forecasting near-surface weather conditions, a comprehensive approach to represent urban impacts on the PBL is still limited. Improved PBL representation can lead to better weather and climate forecasts, …

Development Of An Injectable Methylcellulose Hydrogel System For Nucleus Pulposus Repair And Regeneration, Nada A. Haq-Siddiqi

Dissertations and Theses

Low back pain is the most common cause of disability in the world and is often caused by degeneration or injury of the intervertebral disc (IVD). The IVD is a complex, fibrocartilaginous tissue that allows for the wide range of spinal mobility. Disc degeneration is a progressive condition believed to begin in the central, gelatinous nucleus pulposus (NP) region of the tissue, for which there are few preventative therapies. Current therapeutic strategies include pain management and exercise, or surgical intervention such as spinal fusion, none of which address the underlying cause of degeneration. With an increasingly aging population, the socioeconomic …

The Diffuse Bounce Back Lattice Boltzmann Method And Its Applications On The Study Of Fluid-Particle Interactions, Geng Liu

Dissertations and Theses

Fluid-structure interaction is very broadly seen and widely used in many industrial, engineering and environmental processes. The lattice Boltzmann method has been preferred for simulating particulate flows due to its advantages of easy implementation, micro- and mesoscopic physical insights and parallel algorithm. Both sharp and diffuse boundary treatments are studied to recover curved and moving boundaries on structured orthogonal grids for the lattice Boltzmann method. These methods can describe curved boundaries more accurately and more smoothly than the naive staircase approximation. However, to improve the order of velocity accuracy and to reduce the fluctuation of force, either interpolation or additional …

Alternate Load Paths And Retrofits For Long-Span Truss Bridges Under Sudden Member Loss And Blast Loads, Huihui Li

Dissertations and Theses

In current bridge design practices, due to the existence of alternate load paths (ALPs), continued stability and progressive collapse-resistance of long-span bridges following the initialed loss of a critical member can be attributed to “redundancy”. However, “redundancy”, also indicated as the post member failure behavior of long-span bridges is not well understood and is not explicitly considered, especially for long-span truss bridges. As one of the most famous collapse events that took place recently, collapse of the I-35W truss bridge has demonstrated the vulnerabilities of long-span truss bridges, and their societal and economic consequences under the abnormal events, such as …

Transition To Turbulence And Relaminarization Of Pulsatile Pipe Flows, Joan Gomez

Dissertations and Theses

The instability and transition to turbulence and its evolution in pulsatile pipe flows involving both, reverse and no-reverse flows, is the primary focus of this experimental work. A piston driven by a programable DC servo motor was used to set up a water flow system and provide the pulsation characteristics. Time-resolved particle image velocimetry data were acquired in a refractive index matching setup by using a continuous wave laser and a high-frame-rate digital camera. The position of the piston was continuously recorded by a laser proximity sensor. Different experiments were carried out with Reynolds numbers in the range of 535 …

Adsorption Kinetics And Phase Behavior Of Particles Adsorbed At An Interface, Shaghayegh Darjani

Dissertations and Theses

The ability to predict the adsorption dynamic, phase behavior, and surface pressure of a monolayer of adsorbed particles in two-dimensional systems are key aspects of many current research areas. Examples include phase transitions in amphiphilic monolayers, emulsion stability due to particle adsorption at interfaces, and melting at an interface.

In this thesis, a new approach for deriving the equation of state for a two-dimensional lattice gas is proposed, based on arguments similar to those used in the derivation of the Langmuir-Szyszkowski equation of state for localized adsorption. This work aims to predict the adsorption kinetics and phase behavior of a …