Engineering Commons^™

Effects Of Pyrolysis Heating Rate On Intrinsic Reactivities Of Coal Chars, Thomas K. Gale, Calvin H. Bartholomew, Thomas H. Fletcher

Faculty Publications

The main objective of this work was to determine the effects of pyrolysis heating rate on intrinsic O₂ reactivity of coal chars. Relationships of intrinsic reactivity to other pyrolysis conditions and char physical and chemical structure were also investigated, and empirical correlations were obtained. Two different entrained flow reactors (a flat flame methane/air burner and a drop tube reactor) were used to prepare chars under a variety of different pyrolysis conditions at maximum particle temperatures and heating rates of 840-1627 K and 10⁴ to 2x10⁵ K/s, respectively. Intrinsic reactivities of a lignite and two bituminous coal chars …