Engineering Commons^™

Determining The Limitations Of Class F Fly Ash Compared To Class G Cement In Hydrocarbon Wells Application, Youssef Helmy

Theses and Dissertations

Cement is a material commonly used in multiple applications in different industries. Among the industries that uses cement is the oil and gas industry. API (American Petroleum Institute) Class G cement that is the most incorporated form of cement used in the cementation of oil and gas wells to provide several forms of protection and stabilization for the casings. However, Class G cement is contested in terms of efficiency, costs, and environmental awareness against Class F fly ash geopolymers by researchers. This research aims to explore the potential limitations that fly ash geopolymer might have for its use in the …

Reducing Carbon Emissions With Returned Concrete, John M. Maxwell Jr.

Construction Management

The concrete industry is one of the most energy-intensive sectors of construction. Specifically, the cement production aspect is the most energy intensive, and produces the most carbon emissions. Concrete, a material ubiquitous with nearly every facet of construction; certain types of structures are composed of nearly all concrete. Production of cement is one of the biggest contributors to emissions within the industry. There have been initiatives to reduce or offset emissions from this process, through things like carbon capture, and the purchase of carbon or emissions credits. The objective of this paper was to investigate a new method of carbon …

Spatially Resolved Elastic Modulus Of Magnesium Silicate Hydrate: A Cementitious Material, Arif Syed

Material Science and Engineering Theses

Magnesium-based cements such as magnesium silicate hydrate (MSH) have drawn interest as an environmentally friendly substitute for ordinary Portland cement because of their potential for reduced carbon footprint. The precise determination of these materials' elastic moduli is important to better assess their mechanical performance. Atomic force microscopy (AFM) is an effective tool for precise and spatially resolved quantification of nanomechanical characteristics of materials, including thin films. In this study, elastic modulus maps of MSH grown on single crystal mica surfaces were obtained using amplitude modulation-frequency modulation AFM. The effects of the Mg:Si ratio and morphology on the elastic modulus of …

Production Of Ground Granulated Blast-Furnace Slag Cement: Energy And Carbon Reduction Efficiency Of Cement-Grinding System, Kuan-Hung Lin, Chung-Chia Yang

Journal of Marine Science and Technology

This study used clinker, ground granulated blast-furnace slag (GGBS), and gypsum in a cement-grinding system to produce GGBS cement (GCE). Gypsum was used as the alkaline activator to modify the surface area of GCE and increase its compressive strength. The results revealed that the use of the gypsum activator and the modification of the surface area of GCE effectively increased the formerly inadequate compressive strength of GCE (GGBS > 60%) in the early stage. In addition, energy consumption data were obtained during the production of GCE and Portland cement (PCE) by the cement-grinding system. The calculations concerning the production proportions indicated …

Indirect Tensile Strength Of Clayey Soils Treated With Cement Or Lime, Melissa Adams Cowley

Theses and Dissertations

The objectives of this research were to evaluate the sensitivity of indirect tensile strength (ITS) test results to stabilizer type, stabilizer concentration, and curing time for multiple clayey soils with varying plasticity indices (PIs), identify cases in which an ITS of 30 psi can be obtained, and create a general linear model that predicts ITS. The scope of work included laboratory testing of three clayey soils sampled from Monticello, Utah; Bloomington, Indiana; and San Antonio, Texas. Each soil was tested using two stabilizers, cement or lime, at three concentrations, and two replicate samples were prepared for each combination. ITS testing …

Pbm And Dem Simulations Of Large-Scale Closed-Circuit Continuous Ball Mill Of Cement Clinker, Nontawat Muanpaopong

Dissertations

Cement milling is known to be inefficient and energy-intensive. Thus, even small improvements in cement milling's performance could significantly reduce operation costs. This dissertation aims to develop a simulation tool for dry milling and generate a fundamental process understanding, which enables process optimization. To this end, a true unsteady-state simulator (TUSSIM) for continuous dry milling is developed and applied to model various processes: (a) open circuit continuous mills, (b) closed-circuit continuous mills, and (c) vertical roller mills. TUSSIM is based on the solution of the cell-based population balance model (PBM) for continuous milling, which consists of a set of differential …

Strength And Durability Of Plastic Clays Treated With Cement Or Lime, Tyler D. Mickelson

Theses and Dissertations

The objective of this research was to compare the efficacy of portland cement to that of lime for improving the strength and durability of plastic clays. The scope of work associated with this research involved laboratory strength and durability testing of three plastic clays treated with portland cement or lime. To ensure a broad application of the work, the clays were obtained from three different regions of the United States, specifically from project sites near Bloomington, Indiana; San Antonio, Texas; and Monticello, Utah. Laboratory testing included evaluation of selected properties of the three clays in the untreated condition and in …

Thermoelectric Properties Of Cement Composite Analogues From First Principles Calculations, Esther Orisakwe, Conrad S.N. Johnston, Ruchita Jani, Xiaolo Liu, Lorenzo Stella, Jorge Kohanoff's, Niall Holmes Dr., Brian Norton, Ming Qu, Hongxi Yin, Kazuaki Yazawa

Articles

Buildings are responsible for a considerable fraction of the energy wasted globally every year, and as a result, excess carbon emissions. While heat is lost directly in colder months and climates, resulting in increased heating loads, in hot climates cooling and ventilation is required. One avenue towards improving the energy efficiency of buildings is to integrate thermoelectric devices and materials within the fabric of the building to exploit the temperature gradient between the inside and outside to do useful work. Cement-based materials are ubiquitous in modern buildings and present an interesting opportunity to be functionalized. We present a systematic investigation …

Transient Nonlinear Vibration Characterization Of Building Materials In Sequential Impact Scale Experiments, James Bittner, John S. Popovics

Michigan Tech Publications

Characterizing standard building materials such as concrete is challenging primarily because of the broad range of constituent component sizes within the material itself. Concrete, the most ubiquitous building material, contains critical components that span at least three orders of magnitude of physical size. This work introduces a nondestructive sequential impact test to extract transient nonlinear vibration behaviors that provide statistically significant holistic characterization of a heterogeneous building material, neat cement paste, on a centimeter scale sample. The sensitivity of the single impact vibration combined with the repeatability of the new sequential apparatus enables the extraction of statistically distinct transient nonlinear …

Comparing The Measured And Thermodynamically Predicted Afm Phases In A Hydrating Cement, Niall Holmes Dr., Mark Russell, Geoff Davis, Mark Tyrer

Articles

In hydrating Portland cements, more than one of the AFm family of calcium aluminates may exist. Depending on the amount of carbonate and sulfate present in the cement, the most common phase to precipitate is monosulfate, monocarbonate and/or hemicarbonate. It has been reported in the literature that hemicarbonate often appears in measurements such as XRD but not predicted to form/equilibrate in thermodynamic models. With the ongoing use of commercial cements such as CEM I and CEM II containing more and more limestone, it is important to understand which hydrate solids physically precipitate and numerically predict over time. Using 27 cement …

Employing Discrete Solid Phases To Represent C-S-H Solid Solutions In The Cemdata07 Thermodynamic Database To Model Cement Hydration Using The Phreeqc Geochemical Software, Niall Holmes Dr., Mark Tyrer, Denis Kelliher

Articles

This paper presents a cement hydration model over time using the cemdata07 thermodynamic database and a series of derived discrete solid phases (DSPs) to represent calcium silicate hydrate (C-S-H) as a binary solid solution with two end-members. C-S-H in cement is amorphous and poorly crystalline with a range of molar Ca/Si ratios from 0.6 to 1.7. It displays strongly incongruent dissolution behaviour, where the release of calcium into solution is several orders of magnitude greater than silicon. It is, therefore, important that any cement hydration model provides a credible account of this behaviour. C-S-H has been described in the cemdata07 …

Review Of Fly-Ash As A Supplementary Cementitious Material, Nikki Shaji, Niall Holmes Dr., Mark Tyrer

Conference papers

This paper presents a review of fly-ash as a Supplementary Cementitious Material (SCM) in concrete in terms of its effects on hydration and durability. The climate change agenda has focused the cement and concrete industry on using low embodied CO2 materials and much effort has been made on incorporating industrial by-products into cement as SCMs. With worldwide cement production (circa 4 billion tonnes) currently accounting for approximately 8% of global CO2 emissions and 7% of industry energy use, the use of suitable SCMs to partially replace cement in concrete is extremely important. However, while coal-fired power stations are in the …

Deriving Discrete Solid Phases From Csh-3t And Cshq End-Members To Model Cement Hydration In Phreeqc, Niall Holmes Dr., Colin Walker, Mark Tyrer, Denis Kelliher

Conference papers

This paper presents a cement hydration model over time using the CEMDATA thermodynamic database and a series of discrete solid phases (DSP) to represent calcium silicate hydrate (C-S-H) as a ternary (CSH-3T) and quaternary (CSHQ) solid solution. C-S-H in cement is amorphous and poorly crystalline with a range of molar Ca/Si ratios = 0.6-1.7 and displays strongly incongruent dissolution behaviour where the release of calcium into solution is several orders of magnitude greater than silicon. It is therefore important that any cement hydration model provides a credible account of this behaviour. C-S-H has been described in the CEMDATA thermodynamic database …

Reactions In The Microannulus Of A Wellbore System With Produced Water From The Permian Basin, Ernesto J. Perea

Civil Engineering ETDs

The objective of this study is to determine the effect of the products from steel corrosion and cement dissolution after reaction with produced water (PW) on the permeability of a wellbore microannulus. The wellbore microannulus is the interface between wellbore cement and steel casing and is often identified as a leakage pathway in wellbore systems. The need to better understand the impact of PW on well integrity aids in the assessment of environmental impacts of energy production. Static batch reactors were used to expose a cement – steel microannulus to two PW solutions, a simulated PW, and a field sampled …

Sustainable Concrete And Its Current Stance In The Construction Industry, Morgan Hailey Gawle

Construction Management

Concrete is currently the second most consumed resource used in the world and the production of this material, mainly the production of cement, contributes to a little over 8% of carbon dioxide emissions globally. The concept of sustainable concrete is rapidly surfacing within the construction industry as environmental issues and concerns like global warming and climate change continue to worsen. Scientists have been and continue to consistently conduct studies to test if sustainable concrete is a possible solution to reducing carbon dioxide and greenhouse gas emissions that come straight from the construction industry. But some construction companies have concerns that …

Using Metal-Organic Frameworks (Mof) To Reduce The Carbon Footprint Of Concrete, Mona Ibrahim El-Hallak

Theses

The production of concrete by the construction industry has a massive impact on the environment. The process of manufacturing its main component, cement, releases a considerable amount of anthropogenic carbon dioxide. This thesis is concerned with the production of sustainable and eco-friendly concrete that integrates metal-organic frameworks (MOF) to capture and offset the CO₂ emissions emitted during the production of cement. The main objective is to synthesize a MOF capable of capturing CO₂ in concrete through accelerated carbonation curing and to assess its impact on concrete performance. Different parameters were examined, including the MOF content, initial curing duration, …

The Impact Of Material And Environmental Properties On The Ettringite - Metaettringite Thermochemical Reaction, Aaron Strand

Dissertations

The use of energy is an essential need for people, with demand constantly increasing due to an increasing population and an increase in living and comfort standards. Since 1965, world energy consumption has quadrupled. During peak utilization, the strain on the grid infrastructure can be immense. As energy demand fluctuates during different times of the day and year, the energy production needs to scale accordingly This creates inefficiencies within the system such as over building generation capacity or losses from start up or ramping up production. This can be alleviated through load leveling where excess energy generated during low demand …

Viscosity Modifying Agents: Key Components Of Advanced Cement-Based Materials With Adapted Rheology, Hela Bessaies-Bey, Kamal Khayat, Marta Palacios, Wolfram Schmidt, Nicolas Roussel

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Viscosity modifying agents (VMAs) are essential ingredients for the production of flowable cement-based materials. This paper presents an overview of commonly used VMAs and attempts to shed some light on the underlying physics at the origin of their mechanisms of action. The main molecular parameters of VMA controlling the rheological properties of the cement pore solution are highlighted. As the mechanisms of action of VMAs in cement-based materials are closely related to their affinity with the surface of cement particles, the adsorption of the main VMA types is discussed. The effect of VMAs on flow properties and stability of cement-based …

Using Phreeqc To Model Cement Hydration, Niall Holmes Dr., Mark Tyrer, Roger P. West Prof, Aaron Lowe, Denis Kelliher

Articles

This paper presents the steps involved in undertaking an analysis of hydrating cements with different levels of limestone powder using the PHREEQC geochemical software with the Notepad++ editor. The analysis begins with determining which solid phases are thermodynamically predicted to precipitate and form using the oxide compositions of commercial CEM I and CEM II/A-L cements. When the phases are known, PHREEQC is programmed to provide predictions of the phase dissolution and phase assemblage over time (here, 1000 days of hydration) as well as the pore solution chemistry. Thermodynamics has been successfully applied to the field of cement hydration to predict …

Application Of Biochar As Beneficial Additive In Concrete, Temirlan Barissov

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Biochar is a high-carbon solid material produced via thermal decomposition of organic biomass in a low-oxygen environment. Characterized with high water retention properties and high alkalinity, biochar is generally used for soil amendment and fertilization purposes. This study is intended to explore the feasibility of using biochar as a beneficial additive of the most used manmade material, concrete. Literature review revealed several studies where biochar was successfully implemented as an additive in concrete. The beneficial influence of biochar on the mechanical characteristics of concrete is based on nucleation and densification effects. However, the internal microstructure, porosity and chemical composition of …

Recycling Of Fiber Polymer Matrix Composites In Cementitious Materials, Edward Patton Clark

Electronic Theses and Dissertations

Recycling options for fiber polymer matrix composite waste materials are limited because they typically cannot be reused, reprocessed for down-cycling, and are generally environmentally unfriendly. The utility industry, specifically electrical distribution, has been increasingly using hybrid carbon, glass fiber, and epoxy resin composite rods for high-voltage (HV) conductor transmission lines. The high-voltage conductor core (HVCC) used in the transmission line can have an optimal in-service-life of roughly several decades, in which the material is then retired to a waste landfill. Currently, there is limited research and recycling methodology for these hybrid composite rods. In this research, powder carbon fiber, glass …

Methods And Tools Of Cement Production Process (Comparative Analysis), Potential Of Uzbekistan In This Area, Khudaykulov Umid, S Turgunbayev

Technical science and innovation

the article describes the history of cement use, its initial appearance, cement composition and its physicochemical structure and properties, types of cement and classifications of cement. Cement production processes, technological methods used in production, advantages and disadvantages of the methods and technological stages of the production process by the drying method of cement production are covered. A study of the cement industry and processes in the country was conducted, which summarized the most priority methods and processes of cement production based on the natural resources, climate and potential of Uzbekistan.

Hydration, Shrinkage, Cracking, And Mechanical Properties Of Cementitious Materials With Lignocellulosic Biomass Wastes., Aofei Guo

Electronic Theses and Dissertations

The disposal of lignocellulosic biomass wastes imposes a huge economic and environmental burden on this society. Recycling lignocellulosic biomass wastes and applying them to cementitious materials provides a sustainable and value-added way for both agriculture and concrete industries. To comprehensively identify the effect of lignocellulosic biomass wastes at different scales on cementitious materials, the hydration, shrinkage, cracking, and mechanical properties of cementitious materials with lignocellulosic biomass wastes were studied. Given the three different forms (powders, chips, and fibers) of lignocellulosic biomass wastes in this study, the research was implemented in three stages. In the first stage, hemp powders were collected …

Colloidal Silica: Cement Enhancing Admixture Product Evaluation, Lieska Halsey, David Hansen

Nebraska Department of Transportation: Research Reports

As Class F- fly ash (F-ash) becomes scarce, PCC engineers will look to other supplemental cementitious materials (SCM) to replace F-ash and its ASR mitigating properties. Colloidal silica (CS), or nano-silica, has been shown to mitigate ASR at certain replacement levels; however, CS cannot be a full replacement of F-ash. Engineers at the Nebraska Department of Transportation (NDOT) learned of CS from a presentation given by Intelligent Concrete, Inc. at the 2019 Nebraska Concrete Professionals Association Conference and decided to investigate the potential use of CS in NDOT concrete mix designs.

Effects Of Accelerated Carbonation Curing On Co2 Sequestration And On The Compressive Strength Of Concrete Masonry Units, Barry Gilroy, Leon Black, David Thompson, Ronan Hogan, Niall Holmes

Conference papers

The global consumption of Portland cement has risen to over 4 billion tonnes per annum. Its manufacture is energy and carbon intensive and approximately 900 kg of CO2 is emitted into the atmosphere for each tonne of Portland cement produced. The International Energy Agency (IEA) roadmap sets out a goal to reduce emissions due to cement production to 18 % below 2006 levels by 2050. Concrete has the potential to re-absorb CO2 by the process of carbonation, where it reacts with CaO in the concrete to form calcium carbonate. Accelerated carbonation curing (ACC) is a technique for curing fresh concrete …

The Effects Of Shrinkage Reducing Admixtures On Shrinkage And Strength Properties Of Cement Mortar Lining Mixes, Raed Ashour

Theses - ALL

Cement mortar lining plays an essential role in protecting water supply networks. It protects the internal surface of water pipelines from corrosion and prevents the development of red-water problems in water supply networks. While several factors can cause damage to cement mortar lining, shrinkage cracks are considered one of the main sources of lining failure. Shrinkage cracks are hard to control and can significantly shorten the service life of cement mortar lining applications. Thereafter, the service life of steel pipes can be shortened due to corrosion, which in turn affects the quality of the supplied water.

This thesis describes the …

Flexural Load Capacity Of Heat-Treated Concrete Mixed With Recycled Glass Aggregate And Glass Pozzolan, Enrique Gonzalez Tapia

Civil Engineering Theses

This research focuses on determining the effects of adding glass aggregate and glass pozzolan to concrete that has been exposed to high temperatures. Previous work, based on finding the recommended proportions of recycled components for optimum results, was done to analyze the effects of adding recycled glass components to concrete. Based on those studies, a replacement ratio of 30% glass aggregates and 20% glass pozzolan was used in this project. The compressive strength of concrete has been extensively studied and has been shown to increase in strength when glass components are used in their correct proportions. Less research has been …

Investigating The Experimental Process For Partial Replacement Of Cement With Sugarcane Bagasse In The Construction Industry, Amany G. Micheal Prof., Rania Moussa, Nadin Dawoud

Centre for Advanced Materials

In the last few decades there has been speedily increasing in the agriculture and industrial wastes. This causes many environmental issues and raises the potential to contaminate the natural resources of living such as water, air and soil. Recently, the amount of organic waste produced daily has been rising, while it is poorly managed. It is either burned or disposed improperly, which effect negatively the environment and public health. On the other hand, during the cement production process many wastes, and pollutants are generated which have major negative impacts on the environment. Cement is considered as a substantial constituent of …

Application Of Internal Curing To Improve Concrete Bridge Deck Performance, Arman Abdigaliyev, Yong-Rak Kim, Jiong Hu

Nebraska Department of Transportation: Research Reports

Due to the relatively high cement content and low water-to-cement ratio (w/c) used, bridge deck concrete is prone to premature cracking. Internal curing has been found to greatly reduce the chance of premature cracking as well as concrete deterioration. This research project was intended to develop internally cured bridge deck concrete based on a local mix design in Nebraska. Four different lightweight fine aggregate (LWFA) as internal curing agents were evaluated, and their effects on fresh, mechanical, durability, and shrinkage properties of concrete were studied. To identify the most effective LWFA dosage for shrinkage reduction, different replacement rates of sand …

Prospects For The Development Of Mortgage Works In Underground Mines, T.U. Khudoyarov, I.Yu Sodiko

Gorniy vestnik Uzbekistana

This article presents analyzes of international experience in the application of laying works and their prospects in the development of deposits with a complex geome- chanical situation. Various options for the composition of the filling mixture are also considered.