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Full-Text Articles in Engineering
Transport Processes In Random Arrays Of Cylinders. I. Thermal Conduction, Ashok S. Sangani, C. Yao
Transport Processes In Random Arrays Of Cylinders. I. Thermal Conduction, Ashok S. Sangani, C. Yao
Ashok S. Sangani
A numerical method is developed that takes into account the many particle interactions in a rigorous manner to determine the effective thermal conductivity of Km of a composite medium consisting of parallel circular cylinders of thermal conductivity ak suspended in a matrix of conductivity k. Numerical results for Km are presented for a wide rane of a and o, the area fraction of the cylinders, after averaging over several computer-generated random arrays of cylinders. The results obtained via this exact method are compared with those of various approximate analystical methods to assess their utility in predicting Km.
Transport Processes In Random Arrays Of Cylinders. I. Thermal Conduction, Ashok S. Sangani, C. Yao
Transport Processes In Random Arrays Of Cylinders. I. Thermal Conduction, Ashok S. Sangani, C. Yao
Biomedical and Chemical Engineering - All Scholarship
A numerical method is developed that takes into account the many particle interactions in a rigorous manner to determine the effective thermal conductivity of Km of a composite medium consisting of parallel circular cylinders of thermal conductivity ak suspended in a matrix of conductivity k. Numerical results for Km are presented for a wide rane of a and o, the area fraction of the cylinders, after averaging over several computer-generated random arrays of cylinders. The results obtained via this exact method are compared with those of various approximate analystical methods to assess their utility in predicting Km.
A Two-Dimensional Mathematical Model Of A Porous Lead Dioxide Electrode In A Lead-Acid Cell, E. C. Dimpault-Darcy, T. V. Nguyen, Ralph E. White
A Two-Dimensional Mathematical Model Of A Porous Lead Dioxide Electrode In A Lead-Acid Cell, E. C. Dimpault-Darcy, T. V. Nguyen, Ralph E. White
Faculty Publications
A two-dimensional mathematical model is presented for a lead dioxide electrode in a lead-acid cell. It is used to simulate the time dependent behavior of the electrode during discharge. The model contains six dependent variables: the concentration of the acid electrolyte, the porosity, the electrical potentials of the solid and solution phases, and the two directional components of the current density in the electrolyte. The effect of the electrode grid was included by varying the conductivity of the solid. Parameters such as electrode conductivity, electrode dimensions, and temperature are investigated to understand their effects on electrode discharge performance.
A Mathematical Model For Predicting Cyclic Voltammograms Of Electronically Conductive Polypyrrole, Taewhan Yeu, Trung V. Nguyen, Ralph E. White
A Mathematical Model For Predicting Cyclic Voltammograms Of Electronically Conductive Polypyrrole, Taewhan Yeu, Trung V. Nguyen, Ralph E. White
Faculty Publications
Polypyrrole is an attractive polymer for use as a high energy density secondary battery because of its potential as an inexpensive, lightweight, and noncorrosive electrode material. A mathematical model to simulate cyclic voltammograms for polypyrrole is presented here. The model is for a conductive porous electrode film on a rotating disk electrode (RDE) and is used to predict the spatial and time dependence of concentration, overpotential, and stored charge profiles within a polypyrrole film. The model includes both faradaic and capacitive charge components in the total current density expression.
A Mathematical Model For The Electrodeposition Of Alloys On A Rotating Disk Electrode, Shiuan Chen, Ken-Ming Yin, Ralph E. White
A Mathematical Model For The Electrodeposition Of Alloys On A Rotating Disk Electrode, Shiuan Chen, Ken-Ming Yin, Ralph E. White
Faculty Publications
A general multiple electrode reaction model for electrodeposition of alloys on a rotating disk electrode is presented. Included in the model are mass transport equations with the effect of ionic migration, Butler-Volmer kinetic rate expressions, and the mole fractions of the individual components in the solid state. The model shows that the effect of ionic migration is important and that plating variables such as applied potential, pH, and bulk concentration can be included. Two examples (Ni-P and Ru-Ni-P) are used to illustrate the predictions of the model.
Electrodeposition Of Copper-Nickel Alloys From Citrate Solutions On A Rotating Disk Electrode, Ramona Y. Ying, Patrick K. Ng, Z. Mao, Ralph E. White
Electrodeposition Of Copper-Nickel Alloys From Citrate Solutions On A Rotating Disk Electrode, Ramona Y. Ying, Patrick K. Ng, Z. Mao, Ralph E. White
Faculty Publications
A mathematical model is developed to simulate the electrodeposition of Cu-Ni alloy from citrate solutions onto a rotating disk electrode under potentiostatic control. The model includes the influence of diffusion, ionic migration, forced convection, and homogeneous equilibria. The three major electrochemical reactions treated in the model are copper deposition, nickel deposition, and hydrogen evolution. Using experimental parameters when available, the model was fitted and tested against experimentally-obtained results for different bath compositions and operating conditions. The model agreed reasonably well with the experimental results particularly in the codeposition region, –1.0 to –1.2V vs. SCE, where hydrogen evolution is not the …