Engineering Commons^™

Minerva 2007, The Honors College

Minerva

This issue of Minerva includes an article on the hiring of first-ever full-time Honors faculty members, Mimi Killinger and Mark Haggerty; an article on Honors alumna Molly Barker '00; and a reflection by former Honors Program Director Sam Schuman.

Fatigue Performance Of High-Temperature Deep-Rolled Metallic Materials, P Juijerm, I Altenberger

Journal of Metals, Materials and Minerals

High-temperature deep rolling was developed from conventional deep rolling (deep rolling at room temperature) and performed on various metallic materials, such as austenitic stainless steel AISI 304, normalized plain carbon steel SAE 1045, aluminium alloys (non-precipitation-hardenable AA5083 and precipitation-hardenable AA6110). The fatigue performance of high-temperature deep-rolled specimens was investigated using stress-controlled fatigue tests and compared with the conventionally deep-rolled condition. It was found that high-temperature deep rolling effectively enhances the fatigue performance of steels. However, for aluminium alloys, the beneficial effects of high-temperature deep rolling are not pronounced due to the different strengthening mechanisms in aluminium alloys.

Om Study Of Effect Of Hip And Heat Treatments On Microstructural Restoration In Cast Nickel Based Superalloy, In-738, O Wangyao, W Homkrajai, V Krongtong, N Panich, G Lothongkum

Journal of Metals, Materials and Minerals

The present work aims at studying and searching for the most suitable and practicable repairing condition for microstructural restoration, which could provide the desired microstructural characteristics by rejuvenation method of hot isostatic pressing (HIP), followed by 12 heat treatment conditions for long-term serviced gas turbine blades made of cast nickel base superalloy grade IN-738 operated by Electricity Generating Authority of Thailand (EGAT). During heat treatment process, coarse carbides and overexposed coarse gamma prime precipitates, which had formed previously during service, would dissolve into the matrix during solution treatment. Then specimens were processed through a series of precipitation aging, which re-precipitated …

The Microgeometry Parameters Of Uncoated And Zinc-Coated Cold Rolled Steel Strips, J Bidulská, T Kvačkaj, V Bodák, R Bidulský

Journal of Metals, Materials and Minerals

The microgeometry of surface is arithmetically expressed by the arithmetical mean deviation of the profile, Ra and peak count, Pc. Roughening of working rolls was achieved by using the technology EDT (Electric Discharge Texturing) and SBT (Shot Blast Texturing). The paper shows the relationship between the basic microgeometry parameters and the adjustment technology of working rolls. Zinc-coated cold rolled steel strips, uncoated cold rolled steel strips and the Ra, Pc parameters were measured using the tangent profilometer "Hommel Tester T1000". Measurements of Ra and Pc showed the scatter for SBT and EDT rolls, respectively. EDT can provide a considerably greater …

Prediction Of Tensile Strength For Sandwich Injection Molded Short-Glass-Fiber Reinforced Thermoplastics, S Patcharaphun, G Mennig

Journal of Metals, Materials and Minerals

This present paper provides a modified rule-of-mixtures relationship which allows for the calculation of ultimate tensile strength (UTS) as a function of the area fraction between skin and core layers. The effects of fiber length and fiber orientation within the skin and core layers on the tensile strength of conventional and sandwich injection molded short-glass-fiber reinforced polypropylene have been studied in detail. The present theory is then applied to existing experimental results and the agreement is found to be satisfactory

Zn Coatings For Temporary Protection Applied By Peening Technology, J Brezinnová

Journal of Metals, Materials and Minerals

This paper presents actual investigation results of an experiment that aimed at verifying the possibility of applying zinc on steel surface by peening technology using zinc-coated cut wire. A suitable method for obtained zinc layers and evaluation of their corrosion resistance was determined. Accelerated laboratory tests with presence of SO2 and long term working tests in atmospheric conditions were used. Creation of incoherent zinc coatings was established on the bases of metallographic and spectral analysis. The process of cold zinc by peening may serve as temporary anticorrosion protection of steel surface.

Microstructure And Mechanical Properties Of En Aw 6082 Aluminium Alloy Prepared By Equal-Channel Angular Pressing, M Fujda, T Kvačkaj

Journal of Metals, Materials and Minerals

The mechanical properties and microstructure of EN AW 6082 aluminium alloy subjected to severe plastic deformation (SPD) and natural ageing are compared with those of extruded and artificially aged state (initial state) and quenched state of alloy after solution annealing. Quenched state of alloy was deformed at room temperature by equal channel angular pressing (ECAP) following route C up to three passes. Polyedric microstructure of quenched state was considerably changed by SPD. Deformation bands with different amount of deformation were observed in microstructure of ECAPed state, which indicated non-uniform deformation across the cross-section of ECAPed specimen. Ultimate tensile strength (UTS) …

Experimental Methods Of Assessment Of Pvd Coatings Properties, M Hagarová

Journal of Metals, Materials and Minerals

The paper investigates the properties of thin coatings deposited by Physical Vapour Deposition (PVD) technology. This is a modern technology of depositing thin coatings onto the surface of machine parts. Technological procedures of deposition of thin coatings undergo constant improvement. At the same time, new types of coatings are developed. These developments necessitate evaluation of structure, composition and properties of the coatings. The basic methods of determination of properties of thin coatings include determination of their thickness and hardness, structure and chemical analysis, adhesioncohesion and tribological properties.

Finite Element Analysis Study On Effect Of Indenter Tip Radius To Nanoindentation Behavior And Coatings Properties, N Panich, P Wangyao, S Surinphong, Y K. Tan, Y Sun

Journal of Metals, Materials and Minerals

This paper mainly focuses on the study of factors that affect the nanoindentation process and the determination of mechanical properties of coating film using computational finite element (FE) analysis. Attempts have been made in order to show the effect of indenter tip radius on the nanoindentation process of both hard and soft coating systems. It has been proved that larger load is required to reach a specific penetration depth when the indenter tip radius increases. Besides, the change in tip radius led to a more severe effect on hard coating system compared to soft coating system. Furthermore, pile- up and …

Ferroelectric Glass-Ceramic Sintering Aid For Lead Titanate Ceramics, P Sooksaen, I M. Reaney, D C. Sinclair

Journal of Metals, Materials and Minerals

Silicate-based glass that devitrifies on heating to form ferroelectric lead titanate has been developed. The potential for use as sintering aid in PbO-based electroceramics has been evaluated by studying the densification of PbTiO3 (PT) with increasing wt% addition of glass powder. As the wt% glass content increased, the density increased, the maximum and room temperature relative permittivity decreased and there was also a decrease in Tc and the c/a ratio. The decrease in Tc is believed to be due to increased clamping from neighbouring grains as the density of the PT increases. The decrease in maximum and room temperature relative …

Primary Analysis Of Effective Permeability Of The Flame In Burning Natural Gas, R Jaroslav, R Magdalena

Journal of Metals, Materials and Minerals

This paper presents a method of analysis of effective permeability of the flame in burning natural gas. In order to conduct a complex analysis, it is necessary to determine this parameter as a special case of the process of quasi-plasma nature for the purpose of investigating the options for application of suitable industrial methods applied in similar cases. We observed the synergy of solenoid parameters of the plasma part of the flame with ceramic materials without any special additional customization of the measurement device. The processed results of measurement demonstrate additional requirements necessary for measurement technology. The method was applied …

Surface Modification Of Microfluidic Devices, P Kumlangdudsana, S T. Dubas, L Dubas

Journal of Metals, Materials and Minerals

Microfluidic is a multidisciplinary which encompasses the fields of physics, chemistry, nanotechnology, engineering, and biotechnology. It has been developed extensively for many applications such as handling biological entities such as DNA separation, immunoassay, cell sorting, biosensors, and enzymatic assays due to the potential offered by miniaturizing, high throughput of analysis, low cost of fabrication, multiplex functionality and portability. The surface modification of microfluidic devices has also been a major focus in research to help to enhance their efficiency. There is a variety of surface modification methods and in this paper we reviews and presents an overview of the surface modification …

Bs News

Building Services Engineering

No abstract provided.

Sold Downstream: Free Speech, Fair Use, And Anti-Circumvention Law, R. Terry Parker

The University of New Hampshire Law Review

[Excerpt] “Here’s a hypo. Living in Asia, I purchased a shameful amount of music and movies, all legit purchases through reputable stores, HMV and Tower Records, but little of which will get reissued. I wanted to preserve my collection but software in the discs prevented me from ripping backup copies to my computer. Lacking the technological savvy to get around this software myself, I purchased and used a product to help me circumvent these controls. Discuss.

Courts agree that copying the music and movies here is infringement but that fair use may provide a defense. However, courts do not agree …

Electrochemical Oxidization Of Herring Sperm Dna And Its Interaction With Histone, Juan Xu, Gui-Ping Huang, Hong Li, Wei Zhu

Journal of Electrochemistry

The voltammetric behavior of herring sperm DNA at glassy carbon electrode and its interaction with histone have been investigated by using cyclic voltammetry,differential pulse voltammetry,and fluorescence measurement.In the potential range of 0.20 V to 1.25 V,it is found that an irreversible oxidative peak is exhibited in acid solution,but in the neutral or alkaline solution two oxidative peaks are observed.Oxidative peak potential values show a negative shift with increasing pH via a slope of-57 mV·pH-1 and a linear relation with DNA concentration in the range of 0.45 to 8.20 mmol·L-1.In the presence of histone,the oxidative peak current of DNA and the …

Eiectro-Oxidation Of Methanol On Pdnio/C Catalyst In Alkaline Medium, Mei-Li Wang, Lin Sang, Cheng-De Huang

Journal of Electrochemistry

The electro-oxidation of methanol in alkaline electrolyte at in-house synthesized PdNiO/C and Pd/C catalysts and the effect of heat treatment on the structure and performance of catalysts were studied by cyclic voltammetry,chronoamperometry,chronopotentiometry and X-ray diffraction methods.It is shown that when the reduction temperature is 70℃ and the ratio between Pd and Ni is 8∶2,The PdNiO/C catalyst presents a highest activity for methanol electrooxidation.Calcining can increase the particle size and crystallinity of catalysts,but decrease the dispersion and activity of catalysts, too.Besides,the NiO is disengaged from Pd lattice by heat-treatment.The optimal PdNiO/C catalyst shows higher catalytic activity and much better poisoning resistance …

Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong

Journal of Electrochemistry

Corrosion behavior of carbon steel in methyldiethanolamine(MDEA) solution was investigated by Electrochemical Impedance Spectroscopy(EIS).The results were showed that the corrosion rate of carbon steel in solution containing dissolved oxygen is higher than that in solution removed of dissolved oxygen before cathodic activation.They were reversed after cathodic activation.The corrosion rate is increased at first and then decreased when the concentration of MDEA is increased in the blank solutions.In the simulated solutions containing quantities of!heat-stable salts(HSS),the corrosion rate is decreased monotonously with increase of the MDEA concentration.As anodic polarization potential is increased,the EIS of carbon steel in HSS simulated solution showed characteristics …

Electrochemical Behavior Of Zinc Alloy Anode In Ca(Oh)_2 Solutions Of Different Ph, Peng-Ying Ren, Ji-Quan He

Journal of Electrochemistry

The polarization curves of zinc alloy anodes in Ca(OH)2 solutions have been measured by potentiodynamic method,and the composition of corrosion products were examined by X-ray-diffraction(XRD).The experimental results indicated that not only the electrochemical behavior of zinc alloy anodes were absolutely different in every alkaline solutions,but also many electrochemical parameters were determined,such as zero current potential(E0),the density of corrosion current(icorr),passive current density(ip),breakdown potential(Eb),and so on.There were three zero current potential when zinc alloy anodes in some Ca(OH)2 solutions which made passive state unstable.The graphs of E-pH about zinc alloy anodes dipped in different Ca(OH)2 solutions were drawn,and compared with the potential-pH …

Study On The Corrosion Of Chlorine Condenser By Electrochemical Method, Bin Xiang, Wen Chen, Wen-Zhang Huang, Shao-Hua Xing, Sheng-Tao Zhang

Journal of Electrochemistry

Corrosion of condenser is very seriously in chlorine-alkali industry,which could lead to fatal disaster.The most commonly used material in low pressure condenser includes steel of 16MnR,10#,and welding rod of J507.Electrochemical analysis of the three materials in 29.9%(by mass) calcium chloride(CaCl2) solution was carried out.The corrosion current density icorr and impedance parameters of the three materials in 29.9% CaCl2 solution were estimated separately.The result showed that in the tripartite phase regions where the 10# seamless tube and 16MnR armor plate were jointed by welding,the weld was firstly eroded and suggested that the chlorine condenser should be examined and repaired every year.

Electrochemical Behavor Of Zinc-Indium Alloy Electrodes In Concentrated Alkaline Solution, Zhi-Lin Wang, Xiao-Ge Zhang, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

The electrochemical behavior of zinc-indium alloy electrodes in 35%KOH solutions has been investigated by electrochemical methods including the potentiodynamic polarization and discharge measurements under constant current density.The results indicate that the anodic current density and passive current density increase after the indium addition.The discharge measurement shows that the addition of indium shortens the time to passive state for the Zn alloy compared to pure zinc at a large discharge conditions,that is the addition of indium may enhance the electrochemical activity of Zn alloy electrodes.It is found that the anodic dissolution of zinc-indium alloy electrodes in the concentrated KOH solution occurs …

Preparation And Properties Of High Capacity Lifepo_4, Jun Li, Gui-Tang Lai, Hui-Min Huang, Da-Guang Li, Xin-De Xia

Journal of Electrochemistry

Carbon-doped LiFePO4/C and pure phase LiFePO4 cathode materials were prepared by liquid-state precipitation reaction.The results of XRD,SEM,elemental analysis,FTIR and A.C.impedance tests show that the samples have had olivine structure and a 3.4V discharge platform.The tapped density of LiFePO4/C sample could reach 1.46g/cm3,the initiate discharge capacity is 144.6mAh/g at 0.1C,which remained capacity is 93.2% after 20 cycles.The first discharge capacity is 133.5mAh/g at 1C and the capacity decreased 8.76% after 20 cycles.

Research Of 2,2′-Dipyridine On Electroless Copper Plating Using Sodium Hypophosphite As Reductant, Bin Yang, Fang-Zu Yang, Ling Huang, Shu-Kai Xu, Guang-Hua Yao, Shao-Min Zhou

Journal of Electrochemistry

In the bath of the electroless copper plating using sodium hypophosphite as reductant,the effects of 2,2′-dipyridine on the deposition rate,anodic oxidation of sodium hypophosphite,cathodic reduction of copper ions,surface morphologies,structure and the existing status of the deposit components were examined.The results showed that,2,2′-dipyridine hindered the electroless deposition.Experiments of liner sweep voltammetry(LSV) indicated that,as the addition of 2,2′-dipyridine to the electrolyte,the oxidation peak potential of sodium hypophosphite shifted to a more negative value but the peak current decreased;the reducing peak potential of copper ions moved to a more negative value whereas the peak current increased.Scanning electron microscope(SEM)、energy dispersive spectroscopy(EDS)、X-ray diffraction(XRD) and X-ray …

Electrochemical Behavior And Determination Of Luteolin At A Glassy Carbon Electrode, Ai-Lin Liu, Shao-Bo Zhang, Xiao-Sha Wu, Li-Ping Li, Yang-Yuan Cao, Li-Ying Huang, Xin-Hua Lin

Journal of Electrochemistry

The electrochemical behavior of luteolin was studied by voltammetry at a glassy carbon electrode in phosphate buffer solution.The results exhibited that the well-defined redox peak of luteolin is observed and the electrode process is adsorption-controlled.The charge transfer coefficient(α) was calculated as 0.66 in phosphate buffer solution(pH 4.0).The relationships between oxidation peak current and the concentration of luteolin are linear in the range of 1.0×10-8 ～ 5.0×10-6 mol·L-1 by differential pulse voltammetric method.The detection limit had been estimated as 1.0×10-8 molL-1.This method can be used for the determination of luteolin with satisfactory results.

Selection Of Additions In The Process Of Electrochemical Synthesizing Of K_2feo_4, Wei-Hua Yang, Dong-Qin Bi, Yan Zhou, Hong-Hui Wang, Xin-Ren Lan

Journal of Electrochemistry

Some of different additions including KIO4 was added to the anodic electrolyte for electrochemical synthesizing of K2FeO4,the effects of these additions on current yield were investigated.XRD and SEM were used to characterize the structure and image of K2FeO4.The results show that KIO4 is a preferable addition.When the mass dosage of KIO4 is 0.02%,electrolysis time is 1 h,the current yield is enhanced by 31.6% and the corresponding purity of the product is improved by 3.85 %.

Preparation And Investigations On The Tio2nanotube Arrays For Cathodic Protection Of 316l Stainless Steel, Jing Li, Hong Yun, Chang-Jian Lin

Journal of Electrochemistry

A highly ordered TiO2nanotube layer was fabricated by potentiostatic anodization of pure titanium in fluorinated electrolyte solutions.The structure and composition of the as-prepared TiO2 nanotubes were characterized by SEM and XRD.The TiO2 nanotubes show a stronger absorption in the ultraviolet(UV) light range.The performances of photogenerated cathodic protection and the photoelectrochemical response for the TiO2 nanotube layers under illumination and dark conditions were evaluated through the electrochemical measurements.It is found that the open-circuit potentials of 316 SS coupled with the TiO2 nanotubes layers shift negatively under UV light irradiation(λ<380nm).It is indicated that the TiO2 nanotubes arrays are able to function effectively a photogenerated cathodic protection for metals under light illumination and keep the cathodic protection for a long time under dark conditions.

Ion-Implanting Modification Of Layered Manganese Dioxide And Its Electrochemical Performance, He-Ning Huang, Dong-Ping Lv, Xing-Kang Huang, Qi-Wei Zhang, Yong Yang

Journal of Electrochemistry

Layered MnO2(δ-MnO2) was prepared by thermal decomposition of potassium permanganate.Ti was ion-implanted into such δ-MnO2 by physical techniques,forming a composite(δ-MnO2-Ti).These materials were characterized by XRD,SEM,XPS techniques and their electrochemical proprieties were investigated.The results showed that the layered structure of δ-MnO2 did not been destroyed after Ti ion implantation,and the implanted Ti element was mainly Ti4+ as indicated by XPS.Both of the first and the highest discharge specific capacities of the ion-implanted layered MnO2(δ-MnO2-Ti),compared to those of δ-MnO2,were improved significantly.

Determination Of Malathion Based On Carbon Nanotubes Modified Electrode Incorporating Acetylcholinesterase, Lu Zhang, Yao-Dong Zhang, Hong-Lan Qi

Journal of Electrochemistry

A biosensor for determination of organophosphorus pesticide based on the acetylcholinesterase and multi-wall carbon nanotubes modified electrode is fabricated.Under the optimal conditions,the chronoamperometric current at +0.70V(vs.SCE) increased linearly with the concentration of malathion in the range from 6.0×10-10 to 6.0×10-9 mol·L-1 with a detection limit of 1.0×10-10 mol·L-1.The recoveries of malathion in lake water is 97% to 105% determinated by this method.

Reverse Link Cdma System Capacity Evaluation For Stratospheric Platform Mobile Communications, Iskandar Iskandar

Makara Journal of Technology

We propose an analysis of reverse link CDMA multispot beam stratospheric platforms (SPF) in this paper. The SPF is currently proposed as a novel wireless technology for the development of the next generation fixed and mobile communications. The geometry of this technology is different from that of the terrestrial but rather similar to the satellite based cellular system. However, evaluation on the CDMA system capacity of this technology has not been much reported. This paper addresses all possible multiple access interference analyses including the effects of channel fading and shadowing in order to evaluate the system capacity. Single SPF and …

The Potency Of Fire And Explosion Hazard On Premium Oil Storage Tank At Depot X 2007, Fatma Lestari, Warid Nurdiansyah

Makara Journal of Technology

The Potency of Fire and Explosion Hazard on Premium Oil Storage Tank at Depot X 2007. Premium oil storage tanks have fire and explosion risk because Premium oil is flammable liquid. Because of that, fire and explosion risk assessment on Premium oil storage tank at Depot X is needed as foundation to fire and explosion risk management, and comply with regulations. Method of this research is Dow’s Fire and Explosion Index. This research indicate that F&EI value for Premium oil storage tank is 118,82. Based on that F&EI value, level of risk at Premium oil storage tank is intermediate risk.

Limiting Maximum Drag Reduction Asymptote For The Moment Coefficient Of An Enclosed Rotating Disk With Fine Spiral Grooves, Budiarso Budiarso, Keizo Watanabe, Satoshi Ogata

Makara Journal of Technology

In this study, the limiting maximum drag reduction asymptote for the moment coefficient of an enclosed rotating disk with fine spiral grooves in turbulent flow region were obtained analytically. Analysis which were based on an assumption for a simple parabolic velocity distribution of turbulent pipe flow to represent relative tangential velocity, was carried out using momentum integral equations of the boundary layer. For a certain K- parameter the moment coefficient results agree well with experimental results for maximum drag reduction in an enclosed rotating disk with fine spiral grooves and drag reduction ratio approximately was 15 %. Additionally, the experimental …