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USF Tampa Graduate Theses and Dissertations

2012

Thermoelectric

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Synthesis And Physical Properties Of Group 14 Intermetallic Clathrates, Stevce Stefanoski Jan 2012

Synthesis And Physical Properties Of Group 14 Intermetallic Clathrates, Stevce Stefanoski

USF Tampa Graduate Theses and Dissertations

The search of materials relevant for thermoelectric and magnetocaloric applications, as well as materials that interact with light, is an important aspect of the materials science. Such materials can be used for solid-state power generation and refrigeration, as light sources, detectors, or controllers. Intermetallic clathrates have long been of interest for the materials science research. The promise these materials hold for useful applications ranges from thermoelectrics to photovoltaics and optoelectronics to potentially ultra-hard materials and magnetic cooling applications. Their unique physical properties are intimately related to their intriguing structural properties. Thus a fundamental understanding of the chemistry and physics of …


Growth And Characterization Of Functional Nanoparticulate Films By A Microwave Plasma-Assisted Spray Deposition Process, Ted Wangensteen Jan 2012

Growth And Characterization Of Functional Nanoparticulate Films By A Microwave Plasma-Assisted Spray Deposition Process, Ted Wangensteen

USF Tampa Graduate Theses and Dissertations

Nanoparticle and nanoparticulate films have been grown by a unique approach combining a microwave and nebulized droplets where the concentration and thus the resulting particle size can be controlled. The goal of such a scalable approach was to achieve it with the least number of steps, and without using expensive high purity chemicals or the precautions necessary to work with such chemicals. This approach was developed as a result of first using a laser unsuccessfully to achieve the desired films and particles. Some problems with the laser approach for growing desired films were solved by substituting the higher energy microwave …