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Full-Text Articles in Engineering
Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton
Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton
Gordon Wallace
Aqueous dispersions of reduced graphene oxide (rGO) and multi walled carbon nanotubes (MWCNT) were fabricated through a modified chemical reduction method. The significant advantage of the method developed here is the omission of any stabilising compound or organic solvent to obtain stable rGO-MWCNT dispersions. Significantly biological entities, in this case the enzyme glucose oxidase (GOx), can be successfully incorporated into the dispersion. These dispersions were characterised using XPS, SEM, zeta potential and particle size measurements which showed that the dispersion stability is not sacrificed with the addition of GOx, and significantly, the electrical properties of the rGO and MWCNTs are …
Flexible Cellulose Based Polypyrrole-Multiwalled Carbon Nanotube Films For Bio-Compatible Zinc Batteries Activated By Simulated Body Fluids, Sha Li, Zai Ping Guo, Cai Yun Wang, Gordon G. Wallace, Hua-Kun Liu
Flexible Cellulose Based Polypyrrole-Multiwalled Carbon Nanotube Films For Bio-Compatible Zinc Batteries Activated By Simulated Body Fluids, Sha Li, Zai Ping Guo, Cai Yun Wang, Gordon G. Wallace, Hua-Kun Liu
Gordon Wallace
This work aims to develop biocompatible non-toxic materials for implantable bio-electronic cells. Polypyrrole (PPy)–carbon nanotube (CNT) composites with varied ratios of PPy to CNTs were chemically synthesized and used as cathodes with the support of cellulose paper. Zinc foil was used as the anode material due to its non-toxicity and moderate dissolution rate in aqueous solutions. Simulated body fluids (SBFs) with various protein concentrations were applied as electrolytes in this battery system. The PPy–CNT|Zn cell is capable of being discharged up to 24.5 hours at a current density of 60 μA cm−2 in a protein free SBF. The batteries have …
Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace
Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace
Gordon Wallace
This paper reports on a facile synthesis method for reduced graphene oxide (rGO)/multi-walled carbon nanotubes (MWNTs) nanocomposites. The initial step involves the use of graphene oxide to disperse the MWNTs, with subsequent reduction of the resultant graphene oxide/MWNTs composites using l-ascorbic acid (LAA) as a mild reductant. Reduction by LAA preserves the interaction between the rGO sheets and MWNTs. The dispersion-containing rGO/MWNTs composites was characterized and electrophoretically deposited anodically onto glassy carbon electrodes to form high surface area films for capacitance testing. Pseudo capacitance peaks were observed in the rGO/MWNTs composite electrodes, resulting in superior performance with capacitance values up …
Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen
Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen
Gordon Wallace
By controlling the SWNT-rGO electrode composition and thickness to attain the appropriate porosity and tortuosity, the electroactive surface area is maximized while rapid diffusion of the electrolyte through the electrode is maintained. This leads to an increase in exchange current density between the electrode and electrolyte which results in enhanced thermocell performance.
Carbon Nanotube Network Modified Carbon Fibre Paper For Li Ion Batteries, Jun Chen, Jiazhao Wang, Andrew I. Minett, Yong Liu, Carol M. Lynam, Hua-Kun Liu, G G. Wallace
Carbon Nanotube Network Modified Carbon Fibre Paper For Li Ion Batteries, Jun Chen, Jiazhao Wang, Andrew I. Minett, Yong Liu, Carol M. Lynam, Hua-Kun Liu, G G. Wallace
Gordon Wallace
Here we report on the direct deposition of large quantities of highly porous carbon nanotube networks onto a carbon fibre paper support; subsequently utilised as the anode in a Li-ion battery application showing improved long-term performance and chemical stability with a significant fully reversible capacity of 546mAh/g.
Polyaniline And Polyaniline-Carbon Nanotube Composite Fibres As Battery Materials In Ionic Liquid Electrolyte, Caiyun Y. Wang, Vahid Mottaghitalab, Chee O. Too, Geoffrey M. Spinks, G G. Wallace
Polyaniline And Polyaniline-Carbon Nanotube Composite Fibres As Battery Materials In Ionic Liquid Electrolyte, Caiyun Y. Wang, Vahid Mottaghitalab, Chee O. Too, Geoffrey M. Spinks, G G. Wallace
Gordon Wallace
New battery materials are presented that consist of either a solid polyaniline (PANi) fibre or the same fibre containing carbon nanotubes (CNTs). An ionic liquid ethylmethyl imidazolium bis(trifluoromethanesulfonyl) amide (EMI.TFSA) is used as electrolyte. The electrochemical properties of PANi and PANi/CNT fibres are investigated by means of cyclic voltammetry, a.c. impedance and galvanostatic charge–discharge techniques. A PANi fibre with a CNT content of 0.25 wt.% exhibits a discharge capacity of 12.1 mAh g−1.
Carbon Nanotube Electroactive Polymer Materials: Opportunities And Challenges, Liangti Qu, Qiang Peng, Liming Dai, Geoffrey M. Spinks, G G. Wallace, Ray H. Baughman
Carbon Nanotube Electroactive Polymer Materials: Opportunities And Challenges, Liangti Qu, Qiang Peng, Liming Dai, Geoffrey M. Spinks, G G. Wallace, Ray H. Baughman
Gordon Wallace
Carbon nanotubes (CNTs) with macroscopically ordered structures (e.g., aligned or patterned mats, fibers, and sheets) and associated large surface areas have proven promising as new CNT electroactive polymer materials (CNT-EAPs) for the development of advanced chemical and biological sensors. The functionalization of CNTs with many biological species to gain specific surface characteristics and to facilitate electron transfer to and from them for chemical- and bio-sensing applications is an area of intense research activity. Mechanical actuation generated by CNT-EAPs is another exciting electroactive function provided by these versatile materials. Controlled mechanical deformation for actuation has been demonstrated in CNT mats, fibers, …
The Development And Characterisation Of Polyaniline-Single Walled Carbon Nanotube Composites Fibres Using 2-Acrylamido-2 Methyl-1-Propane Sulfonic Acid (Ampsa) Through One Step Wet Spinning Process, Vahid Mottaghitalab, Geoffrey M. Spinks, Gordon G. Wallace
The Development And Characterisation Of Polyaniline-Single Walled Carbon Nanotube Composites Fibres Using 2-Acrylamido-2 Methyl-1-Propane Sulfonic Acid (Ampsa) Through One Step Wet Spinning Process, Vahid Mottaghitalab, Geoffrey M. Spinks, Gordon G. Wallace
Gordon Wallace
High strength, flexible and conductive polyaniline (PANi)–carbon nanotube (SWNT) composite fibres have been produced using wet spinning. The use of dichloroacetic acid (DCAA) containing 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPSA) has been shown to act as an excellent dispersing medium for carbon nanotubes and for dissolution of polyaniline. The viscosity of DCAA–AMPSA solution undergoes a transition from Newtonian to non-Newtonian viscoelastic behaviour upon addition of carbon nanotubes. The ultimate tensile strength and elastic modulus of PANi–AMPSA fibres were increased by 50 and 120%, respectively, upon addition of 0.76% (w/w) carbon nanotubes. The elongation at break decreased from 11 to 4% upon addition …
Carbon Nanotube/Graphene Nanocomposite As Efficient Counter Electrodes In Dye-Sensitized Solar Cells, Josef Velten, Attila J. Mozer, Dan Li, David Officer, G G. Wallace, Ray Baughman, A Zakhidov
Carbon Nanotube/Graphene Nanocomposite As Efficient Counter Electrodes In Dye-Sensitized Solar Cells, Josef Velten, Attila J. Mozer, Dan Li, David Officer, G G. Wallace, Ray Baughman, A Zakhidov
Gordon Wallace
We demonstrated the replacement of the Pt catalyst normally used in the counter electrode of a dye-sensitized solar cell (DSSC) by a nanocomposite of dry spun carbon multi-walled nanotube (MWNT) sheets with graphene flakes (Gr-F). The effectiveness of this counter electrode on the reduction of the triiodide in the iodide/triiodide redox (I−/I− 3 ) redox reaction was studied in parallel with the use of the dry spun carbon MWNT sheets alone and graphene flakes used independent of each other. This nanocomposite deposited onto fluorinated tin-oxide-coated glass showed improved catalytic behavior and power conversion efficiency (7.55%) beyond the use of the …