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Full-Text Articles in Engineering

A New Data Driven Long-Term Solar Yield Analysis Model Of Photovoltaic Power Plants, Biplob Ray, Rakibuzzaman Shah, Md Rabiul Islam, Syed Islam Jan 2020

A New Data Driven Long-Term Solar Yield Analysis Model Of Photovoltaic Power Plants, Biplob Ray, Rakibuzzaman Shah, Md Rabiul Islam, Syed Islam

Faculty of Engineering and Information Sciences - Papers: Part B

Historical data offers a wealth of knowledge to the users. However, often restrictively mammoth that the information cannot be fully extracted, synthesized, and analyzed efficiently for an application such as the forecasting of variable generator outputs. Moreover, the accuracy of the prediction method is vital. Therefore, a trade-off between accuracy and efficacy is required for the data-driven energy forecasting method. It has been identified that the hybrid approach may outperform the individual technique in minimizing the error while challenging to synthesize. A hybrid deep learning-based method is proposed for the output prediction of the solar photovoltaic systems (i.e. proposed PV …


Model Predictive Control For A New Magnetic Linked Multilevel Inverter To Integrate Solar Photovoltaic Systems With The Power Grids, A M. Mahfuz-Ur-Rahman, Md Rabiul Islam, Kashem M. Muttaqi, Danny Sutanto Jan 2020

Model Predictive Control For A New Magnetic Linked Multilevel Inverter To Integrate Solar Photovoltaic Systems With The Power Grids, A M. Mahfuz-Ur-Rahman, Md Rabiul Islam, Kashem M. Muttaqi, Danny Sutanto

Faculty of Engineering and Information Sciences - Papers: Part B

The multilevel inverters are becoming increasingly popular for use in the grid integration of wind and photovoltaic (PV) power plants due to their higher voltage handling capability and the better output power quality. There are several types of multilevel inverters that have been proposed in the literature; among them the active neutral point clamp (ANPC) multilevel inverters have been drawing significant attention specially for solving the problems with other multilevel inverters. However, with the increase of number of levels, the ANPC requires more electronic switches and flying capacitors, by which the complexity and the cost increases. In this paper, an …


A Novel Empirical Heat Transfer Model For A Solar Thermal Storage Process Using Phase Change Materials, Yu Bie, Ming Li, Fei Chen, Grzegorz Krolczyk, Lin Yang, Zhixiong Li, Weihua Li Jan 2019

A Novel Empirical Heat Transfer Model For A Solar Thermal Storage Process Using Phase Change Materials, Yu Bie, Ming Li, Fei Chen, Grzegorz Krolczyk, Lin Yang, Zhixiong Li, Weihua Li

Faculty of Engineering and Information Sciences - Papers: Part B

Numerical and experimental analyses are often used to evaluate the solar thermal system with latent heat thermal energy storage (LHTES). However, the relationship between the numerical simulation and actual heat transfer process is still unclear. This work compares the simulated average temperature of two different phase change materials (PCMs) with experimental result at different operation conditions for the purpose of developing a temperature correction model. A novel empirical heat transfer model is then established to improve the simulation accuracy of PCM-based solar thermal systems. The contributions of this work include that (1) the system performance could be evaluated by the …


Ultrasonic Spray Deposition Of Tio2 Electron Transport Layers For Reproducible And High Efficiency Hybrid Perovskite Solar Cells, Jingsong Sun, Alexander Pascoe, Steffen Meyer, Qijie Wu, Enrico Della Gaspera, Sonia Raga, Tian Zhang, Andrew Nattestad, Udo Bach, Yi-Bing Cheng, Jacek Jasieniak Jan 2019

Ultrasonic Spray Deposition Of Tio2 Electron Transport Layers For Reproducible And High Efficiency Hybrid Perovskite Solar Cells, Jingsong Sun, Alexander Pascoe, Steffen Meyer, Qijie Wu, Enrico Della Gaspera, Sonia Raga, Tian Zhang, Andrew Nattestad, Udo Bach, Yi-Bing Cheng, Jacek Jasieniak

Australian Institute for Innovative Materials - Papers

The fabrication of high efficiency perovskite solar cells at larger scales will rely on the optimized deposition conditions of every layer using scalable methodologies. Most current perovskite devices that employ the archetypal TiO2 hole blocking layer utilise a simple air-brush approach. This approach is not scalable as it results in significant layer inhomogeneity across larger devices areas. To overcome this inherent limitation, in this work we use ultrasonic spray deposition as an alternative approach for the TiO2 deposition. Focusing on identical reaction chemistries as for air-brush, namely bis(isopropoxide)-bis(acetylacetonate) titanium (IV) based solutions, we find that under optimized conditions smooth TiO2 …


Formulation Of A Model Predictive Control Algorithm To Enhance The Performance Of A Latent Heat Solar Thermal System, Gianluca Serale, Massimo Fiorentini, Alfonso Capozzoli, Paul Cooper, Marco Perino Jan 2018

Formulation Of A Model Predictive Control Algorithm To Enhance The Performance Of A Latent Heat Solar Thermal System, Gianluca Serale, Massimo Fiorentini, Alfonso Capozzoli, Paul Cooper, Marco Perino

Faculty of Engineering and Information Sciences - Papers: Part B

Model predictive control has proved to be a promising control strategy for improving the operational performance of multi-source thermal energy generation systems with the aim of maximising the exploitation of on-site renewable resources. This paper presents the formulation and implementation of a model predictive control strategy for the management of a latent heat thermal energy storage unit coupled with a solar thermal collector and a backup electric heater. The system uses an innovative Phase Change Material slurry for both the heat transfer fluid and storage media. The formulation of a model predictive controller of such a closed-loop solar system is …


Economic Operation Optimization Of Battery Energy Storage Systems In A Solar Rich Microgrid, Herath Pathiranage Asanga Priyankara Jayawardana, Massimo Fiorentini, Duane A. Robinson, Ashish P. Agalgaonkar Jan 2018

Economic Operation Optimization Of Battery Energy Storage Systems In A Solar Rich Microgrid, Herath Pathiranage Asanga Priyankara Jayawardana, Massimo Fiorentini, Duane A. Robinson, Ashish P. Agalgaonkar

Faculty of Engineering and Information Sciences - Papers: Part B

The increasing trend of connecting local distributed generation units to the grid has unlocked new economic opportunities for owners. This is supported by the ongoing development of energy storage technologies, especially battery based systems. In practice, battery storage systems typically operate based on control algorithms where tariff structures and future generation and load profiles are not taken into account. This paper investigates the results of a case study for a microgrid using a proposed optimization model which minimizes cost by considering an import/export tariff structure. The effect of changing time resolution related to variations in demand and generation is examined, …


Development Of Microencapsulated Phase Change Material For Solar Thermal Energy Storage, Weiguang Su, Jo Darkwa, Georgios Kokogiannakis Jan 2017

Development Of Microencapsulated Phase Change Material For Solar Thermal Energy Storage, Weiguang Su, Jo Darkwa, Georgios Kokogiannakis

Faculty of Engineering and Information Sciences - Papers: Part A

In this paper a novel microencapsulated phase change material (MF-3) has been developed and tested for solar assisted hot water storage systems. Even though the morphology of the sample was affected by the type of emulsifier used for fabrication it recorded the highest energy storage capacity of 126 kJ/kg with encapsulation efficiency of 97.4% as compared with other developed samples. For the purpose of assessing its thermal effectiveness it was theoretically evaluated in a compacted fixed bed TES unit and found to be capable of achieving a higher energy storage density as well as relatively smaller physical storage size than …


Performance Simulation Of A Ground Source Heat Pump System Integrated With Solar Photovoltaic Thermal Collectors For Residential Application, Lei Xia, Zhenjun Ma, Georgios Kokogiannakis Jan 2017

Performance Simulation Of A Ground Source Heat Pump System Integrated With Solar Photovoltaic Thermal Collectors For Residential Application, Lei Xia, Zhenjun Ma, Georgios Kokogiannakis

Faculty of Engineering and Information Sciences - Papers: Part B

This paper presents the simulation and performance evaluation of a ground source heat pump (GSHP) system integrated with water-based solar photovoltaic thermal (PVT) collectors for residential buildings. A dynamic simulation system is developed using TRNSYS and used to facilitate the performance evaluation of the system. A 20-year life-time performance simulation is performed under three operation scenarios with different sizes of the PVT collectors. The results showed that the performance of the system is highly dependent on the size of the PVT collectors. Furthermore, an economic analysis is carried out to determine the optimum size of the PVT collectors for the …


Development Of A Dynamic Model For A Hybrid Photovoltaic Thermal Collector - Solar Air Heater With Fins, Wenke Fan, Georgios Kokogiannakis, Zhenjun Ma, Paul Cooper Jan 2017

Development Of A Dynamic Model For A Hybrid Photovoltaic Thermal Collector - Solar Air Heater With Fins, Wenke Fan, Georgios Kokogiannakis, Zhenjun Ma, Paul Cooper

Faculty of Engineering and Information Sciences - Papers: Part A

A dynamic model for a hybrid Photovoltaic Thermal Collector-Solar Air Heater (PVT-SAH) with longitudinal fins was developed to enable assessment of the potential of the system to provide high temperature outlet air (60-90 °C) under dynamic boundary conditions. The model description includes the method for discretising the system into a number of control volumes, the energy balance equations for each control volume and the implementation of the numerical solution. Model validation has been successfully undertaken by using empirical verification of model predictions with an experimental facility and by comparing the model outputs with the reference data from the literature. The …


Team Uow Solar Decathlon House: Refurbishment Demonstration, Zhenjun Ma, Rui Yan, Massimo Fiorentini, Paul Cooper Jan 2016

Team Uow Solar Decathlon House: Refurbishment Demonstration, Zhenjun Ma, Rui Yan, Massimo Fiorentini, Paul Cooper

Faculty of Engineering and Information Sciences - Papers: Part A

This paper describes a practical demonstration of how to refurbish a typical Australian timber framed fibro house to become a net-zero energy, Solar Decathlon (SD) home. The Team UOW Illawarra Flame House was entered in the SD China 2013 competition and was eventually the overall winner of the competition. The house refurbishment method was illustrated initially through architectural changes to the design of the nominal original house in order to improve functionality, daylighting and natural ventilation. Energy simulations for the original house and the house with the architectural refurbishment were then carried out to determine the thermal envelope retrofit targets …


A High Energy Density Solar Rechargeable Redox Battery, Mohammad Ali Mahmoudzadeh, Ashwin R. Usgaocar, Joseph Giorgio, David L. Officer, Gordon G. Wallace, John D. W Madden Jan 2016

A High Energy Density Solar Rechargeable Redox Battery, Mohammad Ali Mahmoudzadeh, Ashwin R. Usgaocar, Joseph Giorgio, David L. Officer, Gordon G. Wallace, John D. W Madden

Australian Institute for Innovative Materials - Papers

An integrated solar energy conversion and storage system is presented using a dye sensitized electrode in a redox battery structure. A stable discharge voltage is shown with high areal energy storage capacity of 180 W h cm-2 by choosing iodide/polysulfide as the pair of active materials matched with permeable porous electrodes. The solar rechargeable battery system offers a higher round-trip efficiency and potential cost savings on fabrication compared to individual devices.


Effective Utilization Of Available Pev Battery Capacity For Mitigation Of Solar Pv Impact And Grid Support With Integrated V2g Functionality, Md Jan E Alam, Kashem M. Muttaqi, Danny Sutanto Jan 2016

Effective Utilization Of Available Pev Battery Capacity For Mitigation Of Solar Pv Impact And Grid Support With Integrated V2g Functionality, Md Jan E Alam, Kashem M. Muttaqi, Danny Sutanto

Faculty of Engineering and Information Sciences - Papers: Part A

Utilizing battery storage devices in plug-in electric vehicles (PEVs) for grid support using vehicle-to-grid (V2G) concept is gaining popularity. With appropriate control strategies, the PEV batteries and associated power electronics can be exploited for solar photovoltaic (PV) impact mitigation and grid support. However, as the PEV batteries have limited capacity and the capacity usage is also constrained by transportation requirements, an intelligent strategy is necessary for an effective utilization of the available capacity for V2G applications. In this paper, a strategy for an effective utilization of PEV battery capacity for solar PV impact mitigation and grid support is proposed. A …


Ambient Synthesis Of One-/Two-Dimensional Cuagse Ternary Nanotubes As Counter Electrodes Of Quantum-Dot-Sensitized Solar Cells, Xin Qi Chen, Yang Bai, Zhen Li, Lian Zhou Wang, S X. Dou Jan 2016

Ambient Synthesis Of One-/Two-Dimensional Cuagse Ternary Nanotubes As Counter Electrodes Of Quantum-Dot-Sensitized Solar Cells, Xin Qi Chen, Yang Bai, Zhen Li, Lian Zhou Wang, S X. Dou

Australian Institute for Innovative Materials - Papers

2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. One-/two-dimensional ternary CuAgSe nanotubes (NTs) were successfully prepared from copper selenide (Cu2-xSe) NTs at room temperature within a short reaction time by the facile cation-exchange approach. Cation exchange leads to the transformation of the crystal structure from cubic into orthorhombic and/or tetragonal with good retention of morphology. The exchange reactions are spontaneous owing to large negative changes of the Gibbs free energy. The effects of parameters such as reaction time, precursor source, and precursor ratio on the exchange reaction were investigated. The resultant CuAgSe NTs were explored as counter electrodes (CEs) of …


A Bi-Layer Tio2 Photoanode For Highly Durable, Flexible Dye-Sensitized Solar Cells, Jianjian Lin, Yong Peng, Alexander Pascoe, Fuzhi Huang, Yi-Bing Cheng, Yoon-Uk Heo, Andrew Nattestad, Wanchul Seung, Sung Kyun Kim, Hoon Joon Yoon, Sang Woo Kim, Yusuke Yamauchi, S X. Dou, Jung Ho Kim Jan 2015

A Bi-Layer Tio2 Photoanode For Highly Durable, Flexible Dye-Sensitized Solar Cells, Jianjian Lin, Yong Peng, Alexander Pascoe, Fuzhi Huang, Yi-Bing Cheng, Yoon-Uk Heo, Andrew Nattestad, Wanchul Seung, Sung Kyun Kim, Hoon Joon Yoon, Sang Woo Kim, Yusuke Yamauchi, S X. Dou, Jung Ho Kim

Australian Institute for Innovative Materials - Papers

Low-temperature processing of dye-sensitized solar cells (DSCs) [B. Oregan, M. Grätzel, Nature, 1991, 353, 737] is crucial to enable their commercialization with low-cost plastic substrates. Much of the previous work in this area has focused on mechanical compression of premade particles on plastic substrates; however, many reported that this technique did not yield sufficient interconnections for high charge carrier transport. Herein, we present bi-layer photoanodes that incorporate microstructured TiO2 sea-urchin-like assemblies, composed of high-aspect-ratio single crystalline nanoribbons, i.e., two-dimensional subunits, which were deposited onto a nanoparticle layer (commercial P25), with a 5.6% conversion efficiency realized. We demonstrate that …


Enhanced Electron Lifetime Of Cdse/Cds Quantum Dot (Qd) Sensitized Solar Cells Using Znse Core-Shell Structure With Efficient Regeneration Of Quantum Dots, Rasin K. Ahmed, Long Zhao, Attila J. Mozer, Geoffrey D. Will, John M. Bell, Hongxia Wang Jan 2015

Enhanced Electron Lifetime Of Cdse/Cds Quantum Dot (Qd) Sensitized Solar Cells Using Znse Core-Shell Structure With Efficient Regeneration Of Quantum Dots, Rasin K. Ahmed, Long Zhao, Attila J. Mozer, Geoffrey D. Will, John M. Bell, Hongxia Wang

Australian Institute for Innovative Materials - Papers

Research on development of efficient passivation materials for high performance and stable quantum dot sensitized solar cells (QDSCs) is highly important. While ZnS is one of the most widely used passivation material in QDSCs, an alternative material based on ZnSe which was deposited on CdS/CdSe/TiO2 photoanode to form a semi-core/shell structure has been found to be more efficient in terms of reducing electron recombination in QDSCs in this work. It has been found that the solar cell efficiency was improved from 1.86% for ZnSe0 (without coating) to 3.99% using 2 layers of ZnSe coating (ZnSe2) deposited by successive ionic …


An Intermediate Band Dye-Sensitised Solar Cell Using Triplet-Triplet Annihilation, Catherine Simpson, Tracey M. Clarke, Rowan W. Macqueen, Yuen Yap Cheng, Adam J. Trevitt, Attila J. Mozer, Pawel W. Wagner, Timothy W. Schmidt, Andrew Nattestad Jan 2015

An Intermediate Band Dye-Sensitised Solar Cell Using Triplet-Triplet Annihilation, Catherine Simpson, Tracey M. Clarke, Rowan W. Macqueen, Yuen Yap Cheng, Adam J. Trevitt, Attila J. Mozer, Pawel W. Wagner, Timothy W. Schmidt, Andrew Nattestad

Australian Institute for Innovative Materials - Papers

A new mechanism of charge photogeneration is demonstrated for the first time, based on organic molecular structures. This intermediate band approach, integrated into a dye-sensitised solar cell configuration is shown to generate charges upon illumination with low energy photons. Specifically 610 nm photoexcitation of Pt porphyrins, through a series of energy transfer steps and triplet-triplet annihilation, excites a higher energy absorption onset molecule, which is then capable of charge injection into TiO2. Transient absorption measurements reveal further detail of the processes involved.


Community Energy Storage For Neutral Voltage Rise Mitigation In Four-Wire Multigrounded Lv Feeders With Unbalanced Solar Pv Allocation, Md Jan E Alam, Kashem M. Muttaqi, Danny Sutanto Jan 2015

Community Energy Storage For Neutral Voltage Rise Mitigation In Four-Wire Multigrounded Lv Feeders With Unbalanced Solar Pv Allocation, Md Jan E Alam, Kashem M. Muttaqi, Danny Sutanto

Faculty of Engineering and Information Sciences - Papers: Part A

The traditional neutral voltage problem in low-voltage (LV) four-wire multigrounded distribution networks can be aggravated due to an unbalanced allocation of one-phase photovoltaic (PV) units. Inherent limitations restrict the performance of the traditional strategies to mitigate the combined effect of load and PV unbalance. To overcome the shortcoming of traditional approaches, a new dynamic mitigation approach using community energy storage (CES) is proposed in this paper. A power balancing algorithm is developed to perform the balancing operation while minimizing power drawn from the CES. A charge/discharge control strategy is developed that will continuously balance and dynamically adjust the power exchange …


Absorption Enhancement In Double-Sided Nanocone Hole Arrays For Solar Cells, Xu Zhang, Yanguang Yu, Jiangtao Xi, Yile Wang, Xiao-Hong Sun Jan 2015

Absorption Enhancement In Double-Sided Nanocone Hole Arrays For Solar Cells, Xu Zhang, Yanguang Yu, Jiangtao Xi, Yile Wang, Xiao-Hong Sun

Faculty of Engineering and Information Sciences - Papers: Part A

Enhancing light absorption in thin-film silicon solar cells is important for improving light harvesting efficiency and reducing manufacture cost. In this paper, we introduce a double-sided nanocone hole (NCH) array structure for solar cells by extending a model suggested by Wang et al (2012 Nano Lett. 12 1616). The top-sided NCH structure is mainly used for increasing the antireflection of incident light, and the bottom-sided NCH structure for enhancing light trapping in the near-infrared spectrum. The theoretical analysis is performed on the proposed structure, from which the optimal geometric parameters of the structure are determined. The performance analysis shows that …


Using Solar Photovoltaic Thermal Collectors In Phase Change Materials Enhanced Buildings For Thermal Performance Management, Zhenjun Ma, Wenye Lin, Mohammed I. Sohel Jan 2015

Using Solar Photovoltaic Thermal Collectors In Phase Change Materials Enhanced Buildings For Thermal Performance Management, Zhenjun Ma, Wenye Lin, Mohammed I. Sohel

Faculty of Engineering and Information Sciences - Papers: Part A

This paper presents the investigation of using air-based solar photovoltaic thermal (PVT) collectors in phase change materials (PCMs) enhanced buildings for effective thermal management. PVT collectors are used to generate electricity and provide low grade heating energy to buildings for winter space heating. PCMs are either integrated into building walls to increase the local thermal mass or used as a temporary centralized thermal storage to store the low grade thermal energy derived from the PVT collectors. The thermal performance of buildings due to the integration of the PVT collectors and PCMs is tested and evaluated through computer simulations. It is …


A Versatile Binder-Free Tio2 Paste For Dye-Sensitized Solar Cells, Jeremy H. Yune, Inna Karatchevtseva, P Evans, Klaudia K. Wagner, Matthew J. Griffith, David L. Officer, Gerry Triani Jan 2015

A Versatile Binder-Free Tio2 Paste For Dye-Sensitized Solar Cells, Jeremy H. Yune, Inna Karatchevtseva, P Evans, Klaudia K. Wagner, Matthew J. Griffith, David L. Officer, Gerry Triani

Australian Institute for Innovative Materials - Papers

In this study, binder-free TiO2 colloidal pastes have been prepared using a variety of heterocyclic bases with diverse characteristics to produce robust photoanodes for dye-sensitized solar cells (DSSC) from a single cast film thickness of 5 micron. The influence of the base on the electrode structure and film morphology, including its electron donor characteristics are investigated after low temperature thermal treatment and high temperature sintering. The results show that quinoline in the TiO2 paste is retained within the electrode structure in comparison to piperidine and pyridine after a short thermal treatment of 150 °C for 15 minutes. The …


Enhanced Electron Lifetimes In Dye-Sensitized Solar Cells Using A Di-Chromophoric Porphyrin: The Utility Of Inter-Molecular Forces, Long Zhao, Pawel W. Wagner, Holly Van Der Salm, Keith C. Gordon, Shogo Mori, Attila J. Mozer Jan 2015

Enhanced Electron Lifetimes In Dye-Sensitized Solar Cells Using A Di-Chromophoric Porphyrin: The Utility Of Inter-Molecular Forces, Long Zhao, Pawel W. Wagner, Holly Van Der Salm, Keith C. Gordon, Shogo Mori, Attila J. Mozer

Australian Institute for Innovative Materials - Papers

Electron lifetimes in dye-sensitized solar cells employing a porphyrin dye, an organic dye, a 1:1 mixture of the two dyes and a di-chromophoric dye design consisting of the two dyes using a non-conjugated linker were measured, suggesting that the dispersion force of the organic dyes has a significant detrimental effect on the electron lifetime and that the di-chromophoric design can be utilized to control the effect of the dispersion force.


Increased Upconversion Performance For Thin Film Solar Cells: A Trimolecular Composition, Yuen Yap Cheng, Andrew Nattestad, Tim F. Schulze, Rowan W. Macqueen, Burkhard Fückel, Klaus Lips, Gordon G. Wallace, Tony Khoury, Maxwell J. Crossley, Timothy W. Schmidt Jan 2015

Increased Upconversion Performance For Thin Film Solar Cells: A Trimolecular Composition, Yuen Yap Cheng, Andrew Nattestad, Tim F. Schulze, Rowan W. Macqueen, Burkhard Fückel, Klaus Lips, Gordon G. Wallace, Tony Khoury, Maxwell J. Crossley, Timothy W. Schmidt

Australian Institute for Innovative Materials - Papers

Photochemical upconversion based on triplet-triplet annihilation (TTA-UC) is employed to enhance the short-circuit currents generated by two varieties of thin-film solar cells, a hydrogenated amorphous silicon (a-Si:H) solar cell and a dye-sensitized solar cell (DSC). TTA-UC is exploited to harvest transmitted sub-bandgap photons, combine their energies and re-radiate upconverted photons back towards the solar cells. In the present study we employ a dual-emitter TTA-UC system which allows for significantly improved UC quantum yields as compared to the previously used single-emitter TTA systems. In doing so we achieve record photo-current enhancement values for both the a-Si:H device and the DSC, surpassing …


Mesoporous Hierarchical Anatase For Dye-Sensitized Solar Cells Achieving Over 10% Conversion Efficiency, Jianjian Lin, Yoon-Uk Heo, Andrew Nattestad, Yusuke Yamauchi, S X. Dou, Jung Ho Kim Jan 2015

Mesoporous Hierarchical Anatase For Dye-Sensitized Solar Cells Achieving Over 10% Conversion Efficiency, Jianjian Lin, Yoon-Uk Heo, Andrew Nattestad, Yusuke Yamauchi, S X. Dou, Jung Ho Kim

Australian Institute for Innovative Materials - Papers

Interest in both one-dimensional and hierarchical architectures of metal oxide semiconductors has intensified within the field of materials science over recent years. Herein, a new mesoporous anatase TiO2 architecture that combines these two concepts, as it is composed of individual, high-aspect-ratio, nanoribbon-like components, was synthesized via a facile hydrothermal method without any surfactant or template. An 8.3% solar-to-electric conversion efficiency was obtained when these structures were used in photoanodes for dye-sensitized solar cells, which are superior to commercial state-of-the-art TiO2 (6.6%), due to enhanced dye loading and efficient light scattering. To further improve the light scattering effect, a …


N719- And D149-Sensitized 3d Hierarchical Rutile Tio2 Solar Cells - A Comparative Study, Jianjian Lin, Yoon-Uk Heo, Andrew Nattestad, Mohammed Shahabuddin, Yusuke Yamauchi, Jung Ho Kim Jan 2015

N719- And D149-Sensitized 3d Hierarchical Rutile Tio2 Solar Cells - A Comparative Study, Jianjian Lin, Yoon-Uk Heo, Andrew Nattestad, Mohammed Shahabuddin, Yusuke Yamauchi, Jung Ho Kim

Australian Institute for Innovative Materials - Papers

Poor dye loading on rutile TiO2 is one of the chief reasons for lower solar-to-electric conversion efficiency (η) in dye-sensitized solar cells (DSCs), compared to their anatase based counterparts. Previously, we showed that similar light harvesting for both rutile and anatase was realized by using a metal-free organic indoline dye, D149 [Sci. Rep., 2014, 4, 5769]. This was in contrast to the bulk of previous studies, which employed ruthenium based N719, leading to significant differences in light harvesting. To date, there has been no report directly comparing N719 and D149 for rutile based DSCs. In this work, three-dimensional hierarchical …


Boosting The Efficiency Of Quantum Dot Sensitized Solar Cells Up To 7.11% Through Simultaneous Engineering Of Photocathode And Photoanode, Yang Bai, Chao Han, Xinqi Chen, Hua Yu, Xu Zong, Zhen Li, Lianzhou Wang Jan 2015

Boosting The Efficiency Of Quantum Dot Sensitized Solar Cells Up To 7.11% Through Simultaneous Engineering Of Photocathode And Photoanode, Yang Bai, Chao Han, Xinqi Chen, Hua Yu, Xu Zong, Zhen Li, Lianzhou Wang

Australian Institute for Innovative Materials - Papers

We demonstrate a new strategy of boosting the efficiency of quantum dot sensitized solar cells (QDSSCs) by engineering the photocathode and photoanode simultaneously. Nanostructured photocathodes based on non-stoichiometric Cu2-xSe electrocatalysts were developed via a simple and scalable approach for CdS/CdSe QDs co-sensitized solar cells. Compared to Cu2S CE, remarkably improved photovoltaic performance was achieved for QDSSCs with Cu2-xSe CEs. The superior catalytic activity and electrical conductivity of Cu2-xSe CEs were verified by the electrochemical impedance spectra and Tafel-polarization measurements. To maximize the efficiency enhancement, the photoanodes were optimized by introducing a pillared …


Trap-Assisted Transport And Non-Uniform Charge Distribution In Sulphur-Rich Pbs Colloidal Quantum Dot-Based Solar Cells With Selective Contacts, Victor Malgras, Guanran Zhang, Andrew Nattestad, Tracey M. Clarke, Attila J. Mozer, Yusuke Yamauchi, Jung Ho Kim Jan 2015

Trap-Assisted Transport And Non-Uniform Charge Distribution In Sulphur-Rich Pbs Colloidal Quantum Dot-Based Solar Cells With Selective Contacts, Victor Malgras, Guanran Zhang, Andrew Nattestad, Tracey M. Clarke, Attila J. Mozer, Yusuke Yamauchi, Jung Ho Kim

Australian Institute for Innovative Materials - Papers

This study reports evidences of dispersive transport in planar PbS colloidal quantum dots heterojunction-based devices as well as the effect of incorporating a MoO3 hole selective layer on the charge extraction behavior. Steady state and transient characterization techniques are employed to determine the complex recombination processes involved in such devices. The addition of a selective contact drastically improves the device efficiency up to 3.15 % (especially through the photocurrent and series resistance) and extends the overall charge lifetime by suppressing the main first-order recombination pathway observed in device without MoO3. The lifetime and mobility calculated for our sulphur-rich PbS-based devices …


An Approach For Online Assessment Of Rooftop Solar Pv Impacts On Low-Voltage Distribution Networks, Md Jan-E- Alam, Kashem Muttaqi, Darmawan Sutanto Jan 2014

An Approach For Online Assessment Of Rooftop Solar Pv Impacts On Low-Voltage Distribution Networks, Md Jan-E- Alam, Kashem Muttaqi, Darmawan Sutanto

Faculty of Engineering and Information Sciences - Papers: Part A

Assumption-based offline analysis tools may not be able to provide sufficient and accurate information for the corrective decision making to mitigate solar photovoltaic (PV) impacts in the future distribution grids. This is mainly due to the increasing penetration level of intermittent power generation resources and also the fluctuating behavior of consumer demand. Online assessment tools can assist to manage PV impacts and aid to mitigate those on a real-time basis. This paper proposes an approach for online assessment of rooftop PV impacts on low-voltage (LV) networks using real-time network data. A variable-width sliding window will be used to provide the …


A Novel Approach For Ramp-Rate Control Of Solar Pv Using Energy Storage To Mitigate Output Fluctuations Caused By Cloud Passing, M J. E Alam, K M. Muttaqi, D Sutanto Jan 2014

A Novel Approach For Ramp-Rate Control Of Solar Pv Using Energy Storage To Mitigate Output Fluctuations Caused By Cloud Passing, M J. E Alam, K M. Muttaqi, D Sutanto

Faculty of Engineering and Information Sciences - Papers: Part A

The variability of solar irradiance with a high ramp-rate, caused by cloud passing, can create fluctuation in the PV output. In a weak distribution grid with a high PV penetration, this can create significant voltage fluctuations. Energy storage devices are used to smooth out the fluctuation using traditional moving average control. However, moving average does not control the ramp-rate directly; rather the ramp-rate depends on previous values of PV output. This paper proposes a strategy where the ramp-rate of PV panel output is used to control the PV inverter ramp-rate to a desired level by deploying energy storage (which can …


Solar Pv And Battery Storage Integration Using A New Configuration Of A Three-Level Npc Inverter With Advanced Control Strategy, Hamid Teymour Ghasemabadi, Danny Soetanto, Kashem M. Muttaqi, Philip Ciufo Jan 2014

Solar Pv And Battery Storage Integration Using A New Configuration Of A Three-Level Npc Inverter With Advanced Control Strategy, Hamid Teymour Ghasemabadi, Danny Soetanto, Kashem M. Muttaqi, Philip Ciufo

Faculty of Engineering and Information Sciences - Papers: Part A

In this paper, a novel configuration of a three-level neutral-point-clamped (NPC) inverter that can integrate solar photovoltaic (PV) with battery storage in a grid-connected system is proposed. The strength of the proposed topology lies in a novel, extended unbalance three-level vector modulation technique that can generate the correct ac voltage under unbalanced dc voltage conditions. This paper presents the design philosophy of the proposed configuration and the theoretical framework of the proposed modulation technique. A new control algorithm for the proposed system is also presented in order to control the power delivery between the solar PV, battery, and grid, which …


Highly Connected Hierarchical Textured Tio2 Spheres As Photoanodes For Dye-Sensitized Solar Cells, Jianjian Lin, Andrew Nattestad, Hua Yu, Yang Bai, Lianzhou Wang, S X. Dou, Jung Ho Kim Jan 2014

Highly Connected Hierarchical Textured Tio2 Spheres As Photoanodes For Dye-Sensitized Solar Cells, Jianjian Lin, Andrew Nattestad, Hua Yu, Yang Bai, Lianzhou Wang, S X. Dou, Jung Ho Kim

Australian Institute for Innovative Materials - Papers

We present a new type of microstructured TiO2 sea urchin-like assembly, composed of high aspect-ratio nanosheets. We also demonstrate the applicability of these structures as photoanodes in dye-sensitized solar cells, with 9.0% conversion efficiency realized, a considerable improvement over the commercial Dyesol paste (8.2%) under the same conditions. We reveal that this new TiO2 nanostructure is beneficial to enhanced dye loading and efficient light scattering. In particular, the interpenetrating individual sheets of the spheres result in more intimate interparticle connections and provide efficient electron transfer pathways.